U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications     

HAN Ke  YANG Xingke  CHAO Huixi  HE Hujun  RUAN Shiqi  GAO Yunfeng  ZHANG Weisheng  ZHU Wei  JIN Gang 《《地质学报》英文版》2021,95(2):500-516

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.  相似文献   

Geochronology, Fluid Inclusions and Isotopic Characteristics of the Dongjun Pb-Zn-Ag Deposit, Inner Mongolia, NE China     

XIE Wei  WEN Shouqin  ZHANG Guangliang  TANG Tieqiao 《《地质学报》英文版》2021,95(5):1611-1633

The Dongjun Pb-Zn-Ag deposit in the northern part of the Great Xing’an Range (NE China) consists of quartz-sulfide vein-type and breccia-type mineralization, related to granite porphyry. Hydrothermal alteration is well-developed and includes potassic-silicic-sericitic alteration, phyllic alteration and propylitic alteration. Three stages of mineralization are recognized on the basis of field evidence and petrographic observation, demarcated by assemblages of quartz-pyrite-arsenopyrite (early stage), quartz-polymetallic sulfide (intermediate stage) and quartz-carbonate-pyrite (late stage). Zircon LA-ICP-MS U-Pb dating indicates that the granite porphyry was emplaced at 146.7 ± 1.2 Ma (Late Jurassic). Microthermometry and laser Raman spectroscopy shows that ore minerals were deposited in conditions of intermediate temperatures (175–359°C), low salinity (0.5–9.3 wt% NaCl eqv.) and low density (0.60–0.91 g/cm3). Ore-forming fluids were derived largely from magmatic hydrothermal processes, with late-stage addition of meteoric water, belonging to a H2O-NaCl-CO2 ± CH4 system. The δ34SV-CDT values range from 0.75‰ to 4.70‰. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values of the ore minerals are in the ranges of 18.240–18.371, 15.542–15.570, and 38.100–38.178, respectively. Data for the S and Pb isotopic systems indicate that the ore-forming metals and sulfur were derived from Mesozoic magma. Based on the geological characteristics and geochemical signatures documented in this study, we conclude that the Dongjun deposit is a mesothermal magmatic hydrothermal vein-type Pb-Zn-Ag deposit controlled by fractures and related to granite porphyry, in response to Late Jurassic tectonic–magmatic–hydrothermal activity. We further conclude that fluid immiscibility, fluid mixing and fluid-rock interactions were the dominant mechanisms for deposition of the ore-forming materials.  相似文献   

Genesis of Geothermal Fluid in Typical Geothermal Fields in Western Sichuan,China     

ZHAO Jiayi  WANG Guiling  ZHANG Cuiyun  XING Linxiao  LI Man  ZHANG Wei 《《地质学报》英文版》2021,95(3):873-882

The hydrogeochemical characteristics of geothermal fluids can reveal the genesis of geothermal systems and act as important references for developing and using geothermal resources.This study presents hydrogeochemical processes and thermal cycle mechanisms of typical geothermal fields in Western Sichuan.Based on the geological conditions in Western Sichuan,29 hot springs in three geothermal fields in the Batang and Litang areas were selected for hydrochemical and isotopic (δD andδ~(18)O) analyses.Furthermore,the temperature of the thermal reservoir was calculated and the upflow cooling process of the hot springs was analyzed.Most of the subterranean hot waters in Batang and Litang are of the HCO_3-Na hydrochemical type.The ion variation in Batang is primarily affected by water-rock interactions.There is a strong positive correlation between Na~+,B~-,and Cl~-in Litang,suggesting that they have the same material source.The Na~+and metaboric acid content is relatively high,which indicates that the groundwater runoff in both areas is relatively long-lasting,with reduced flow velocity;moreover,the metasilicic acid content is relatively high,which supports this conclusion.Both hydrogen and oxygen isotopes plot near the atmospheric precipitation line,indicating that groundwater recharge is functionally obtained from precipitation.The calculated thermal storage temperatures in Batang and Litang were 88–199°C and 96–154°C,respectively.The proportion of cold water mixing in Batang was 64%–67%,while that in Litang was 60%–68%.According to the calculated results,the initial thermal cycle depth of the Batang area (4540–4780 m) was greater than that of the Litang area (3150–3960 m).The enthalpy of the deep parental geothermal fluid in Batang was 1550 J/g with a Cl~-concentration of 37 mg/L,while that in Litang was 2100 J/g with a Cl~-concentration of 48 mg/L.  相似文献   

商丹断裂带(河南段)构造变形特征及其找矿意义          下载免费PDF全文

薛艳  韩天成  陶威  易志强  马洪勇  黄向东 《地质找矿论丛》2021,36(3):257-264

商丹断裂带是一条多期次活动的大型断裂带,区域上也是大型金属矿的赋存带,对金属矿产具有重要的控制作用。文章以商丹断裂带(河南段)为研究对象,在基于孔沟至寨根一带构造剖面的宏观特征和显微构造特征解析的基础上,对研究区控矿构造和机理提出了新的认识。综合研究表明,商丹断裂带(河南段)具多期活动特征,整体呈现"正花状构造"样式。分析方解石机械双晶、矿物动态重结晶及变质矿物组合等显微构造显示,断裂带以韧性变形为主,两侧地层以韧性和脆性变形叠加为特征。区内变质变形温度以绿片岩相、中低温为主,局部可达角闪岩相。早期的韧性剪切活动控制本区金矿的总体控矿界面,晚期的构造活动形成的韧-脆性破碎带对先期形成的矿床进行改造、富集、最终定位,主断裂两侧的次级韧-脆性构造带是未来寻找金矿的有利部位。  相似文献   

珠江口盆地阳江东凹古近系构造特征与勘探潜力     

梁卫  彭光荣  朱定伟  吴静  杜晓东  蔡国富  汪晓萌  何金海  李三忠  索艳慧 《大地构造与成矿学》2021,45(1):168-178

阳江东凹是近年来珠江口盆地(东部)的热点探区,过去四十余年受限于钻井数量与地震资料品质和覆盖范围,缺少对古近系的研究。随着勘探程度的提高,走向深层古近系是珠江口盆地油气勘探的必然趋势。本文在覆盖全区的高品质三维地震资料基础上,结合新近钻井和测井资料,系统解剖阳江东凹的构造特征及其对沉积充填的控制,并探讨古近系的勘探潜力。阳江东凹发育5个次级洼陷,古近纪控洼断裂频繁转换,断裂活动、岩浆底侵导致的隆升差异性控制了各次洼三级层序的展布、厚度和沉积充填。东部恩平20洼、恩平21西洼和恩平21东洼控洼断裂活动强度整体较强,文昌组以半深湖相和辫状河三角洲沉积为主,烃源条件和储盖组合良好,特别是恩平21东洼的缓坡带,是阳江东凹古近系勘探的有利区带。  相似文献   

珠江口盆地中中新世SQ14.8层序-沉积演化及其地质意义     

陈维涛  孙珍  何敏  张琴  王文勇  王绪诚  徐少华 《大地构造与成矿学》2021,45(5):875-891

中中新世,位于南海北部陆缘的珠江口盆地发生了构造、沉积和古气候格局的骤然变迁,而对古珠江沉积体系层序、沉积的研究为重塑该变革提供了良好契机.本文利用珠江口盆地三维地震和钻井资料,选取中中新世SQ14.8三级层序开展了系统的层序地层和沉积解剖,通过厘定关键层序、体系域界面,建立了高精度区域四分体系域格架,并在此基础上重建陆架-陆坡区主要沉积体系的宏观展布特征和演化过程.研究发现,SQ14.8三级层序记录了珠江口盆地新近纪以来最大规模的一次相对海平面下降,引发沉积滨线跨越陆架长距离迁移到陆架坡折,发育了从低位到强制海退完整的体系域单元.古珠江三角洲作为陆架区主要的沉积体系,在相对海平面升降旋回的驱动下,其发育位置从内陆架到陆架边缘的迁移过程中,发育主控因素也由河流作用为主逐渐变为河流和海洋水动力共同控制.强制海退体系域的识别及沉积展布研究为预测深水储层提供了依据,该时期发育的陆架边缘三角洲下方陆坡区是寻找富砂重力流储集体的有利地区,而陆架边缘三角洲侧翼砂质沉积较少,下方的扇体以泥质扇为主.综合分析认为中中新世变冷事件是造成13.8 Ma相对海平面强烈下降的主要原因,在珠江口盆地促成SQ14.8层序典型强制海退体系域及陆架边缘三角洲的发育,进一步证明该事件是一次全球性的气候事件,其响应不仅可以在大洋钻孔获取的O同位素中找到证据,在边缘海盆的沉积记录中也有明显反映.  相似文献   

辽东地区古元古代变基性岩床的成因和构造意义     

胡国辉  张琪琪  王伟  张拴宏  李建锋 《大地构造与成矿学》2021,45(5):1023-1043

辽东地区胶-辽-吉造山带发育大量的变基性岩墙/床,这些岩墙/床对研究造山带古元古代构造演化过程具有重要意义.本文通过对辽东地区辽河群中的变基性岩床进行岩石学、岩石地球化学和锆石LA-ICP-MS U-Pb年代学研究,探讨其成因和形成的构造背景,有助于深入认识胶-辽-吉造山带古元古代地质演化过程.辽东地区变基性岩床顺层侵入于辽河群大石桥组大理岩中,发生角闪岩相变质作用,岩石类型以斜长角闪岩和石榴斜长角闪岩为主,主要矿物为角闪石和斜长石,其他矿物有石榴子石、石英、黑云母、磁铁矿和黄铁矿等.变基性岩床样品的锆石具特征的环带结构和较低的Th/U值(0.01～0.34),指示锆石为变质成因,4个样品的锆石LA-ICP-MS U-Pb定年结果(1854±11 Ma、1846±12 Ma、1847±9 Ma和1848±7 Ma)表明基性岩床发生变质作用的时间为～1.85 Ga,与华北克拉通最终碰撞拼合的时间一致.根据基性岩床与胶-辽-吉造山带其他地区～2.1 Ga的基性岩具有相似的野外产状、岩石学和地球化学特征,推断其侵位时代可能为～2.1 Ga.基性岩床样品的SiO2含量为47.07％～52.18％,K2O+Na2O含量为1.78％～4.70％,MgO含量为3.92％～8.59％,属于拉斑玄武岩系列.大部分样品的稀土总量较低(47.3×10-6～109.5×10-6),富集轻稀土元素和大离子亲石元素(如Rb、Ba、La),亏损高场强元素(如Nb、Ta),Zr、Hf没有明显的亏损且未发生分馏作用.所有样品的Al2O3、CaO和Fe2O3T含量在主量元素相关性图解上分布规律且与MgO含量呈较好的相关性,Nb/La值(0.52～0.73)随SiO2和MgO含量的变化较小,表明岩浆在侵位过程中受地壳混染的程度较低,似"岛弧"型地球化学特征是富集岩石圈地幔源区遭受古俯冲组分改造的结果.结合已有的辽河群变质火山-沉积岩、辽吉花岗岩和基性岩的研究成果,胶-辽-吉造山带在～2.1 Ga处于陆内裂谷环境.  相似文献   

微束分析测试技术十年(2011~2020)进展与展望     

陈意  胡兆初  贾丽辉  李金华  李秋立  李晓光  李展平  龙涛  唐旭  王建  夏小平  杨蔚  原江燕  张迪  李献华 《矿物岩石地球化学通报》2021,40(1):前插2-前插3,1-35

现代地球科学研究的重大突破在很大程度上取决于观测和分析技术的创新。新世纪以来,我国地球科学领域引进了一批高性能新型微束分析仪器设备,建立了一批高规格的实验室。本文回顾了近十年来微束分析技术与方法的主要进展及其在地球科学研究中的应用实例,包括电子探针、扫描电镜、透射电镜、大型离子探针、纳米离子探针、飞行时间二次离子质谱、激光剥蚀等离子体质谱、激光诱导原子探针、原子探针技术、显微红外光谱、同步辐射等,这些分析技术的进步和广泛应用极大地提高了我们对地球和行星演化历史及许多地质过程的理解。今后,应加快微束分析的新技术、新方法和新标准的开发,特别是高水平人才队伍建设,提高创新能力并在国际学术舞台上发挥重要作用。  相似文献   

湖南省涟源凹陷泥盆纪佘田桥组页岩储层测井评价     

吕嵘  张保民  李芳  田巍 《华南地质与矿产》2021,37(3):313-320

湘中地区涟源凹陷泥盆纪佘田桥组(D3s)富有机质页岩发育,区内参数井-湘新页1井(XXY-1)已在该组钻遇良好页岩气.为研究该套储层特征,依托湘新页1井的岩心和测井资料,通过数控测井系统的综合测井曲线响应特征和数据处理结果对该套储层进行了评价.结果表明,湘新页1井泥盆纪佘田桥组底部为优质页岩发育段,厚度达81.1 m,页岩TOC、物性均较好,具有较大资源潜力.  相似文献   

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples     

Wei‐Xin Lv  Hao‐Ming Yin  Meng‐Shu Liu  Fang Huang  Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.  相似文献