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11.
Mechanisms and Sources of Mantle Metasomatism: Major and Trace Element Compositions of Peridotite Xenoliths from Spitsbergen in the Context of Numerical Modelling 总被引：11，自引：6，他引：11
IONOV DMITRI A.; BODINIER JEAN-LOUIS; MUKASA SAMUEL B.; ZANETTI ALBERTO 《Journal of Petrology》2002,43(12):2219-2259
Mineral and whole-rock chemical data for peridotite xenolithsin basaltic lavas on Spitsbergen are examined to reassess mechanismsof melt–fluid interaction with peridotites and their relativerole versus melt composition in mantle metasomatism. The enrichmentpatterns in the xenoliths on primitive mantle-normalized diagramsrange from Th–La–Ce ‘inflections’ inweakly metasomatized samples (normally without amphibole) toa continuous increase in abundances from Ho to Ce typical foramphibole-bearing xenoliths. Numerical modelling of interactionbetween depleted peridotites and enriched melts indicates thatthese patterns do not result from simple mixing of the two end-membersbut can be explained by chromatographic fractionation duringreactive porous melt flow, which produces a variety of enrichmentpatterns in a single event. Many metasomatized xenoliths havenegative high field strength element and Pb anomalies and Srspikes relative to rare earth elements of similar compatibility,and highly fractionated Nb/Ta and Zr/Hf. Although amphiboleprecipitation can produce Nb–Ta anomalies, some of thesefeatures cannot be attributed to percolation-related fractionationalone and have to be a signature of the initial melt (possiblycarbonate rich). In general, chemical and mineralogical fingerprintsof a metasomatic medium are strongest near its source (e.g.a vein) whereas element patterns farther in the metasomatic‘column’ are increasingly controlled by fractionationmechanisms. KEY WORDS: Spitsbergen; lithospheric mantle; metasomatism; trace elements; theoretical modelling 相似文献
12.
CASTOR MUÑOZ SOBRINO PABLO RAMIL-REGO LUIS GÓMEZ-ORELLANA RAMÓN ALBERTO DÍAZ VARELA 《Boreas: An International Journal of Quaternary Research》2005,34(3):381-400
Three NW Iberia Cantabrian Mountain pollen records are presented. They reflect the main Holocene climatic shifts in the North Atlantic region as recorded in the isotopic data from Greenland ice, Irish speleothems and reconstructed sea surface temperatures. Two brief forest regression episodes reconstructed from pollen may be synchronous with GH-11.2 and GH-8.2 events. At mid-altitude, two woodland expansion phases (7000-6000 14C yr BP and 4000-2500 14C yr BP) are separated by a phase of heaths and peat deposits. Major woodland declines occurred during the Galician-Roman Period (which includes the Bronze Age, the Iron Age and the Roman occupation) and from the end of the Medieval Period. The pollen data, backed up by archaeological and historical sources, suggest climatic impact of the Iron Age Cold Period, but are indecisive concerning the Little Ice Age. However, the pollen records do not support any significant 'Neoglacial' period (4000-3000 14C yr BP) influence on NW Iberia. 相似文献
13.
CASTRO ANTONIO; GUILLERMO CORRETGE L.; EL-BIAD MOHAMMED; EL-HMIDI HASSAN; FERNANDEZ CARLOS; PATINO DOUCE ALBERTO E. 《Journal of Petrology》2000,41(10):1471-1488
We have studied experimentally the melting relationships ofthe Ollo de Sapo gneiss (OSG), an important crustal protolithfor the Iberian leucogranites, of possible volcanoclastic origin.The results of this study are compared with previously determinedPTt paths, allowing us to interpret the mechanisms of meltingand granitoid production during the Hercynian orogenic cycle.Phase relationships determined in fluid-absent experiments indicatethat the OSG is a fertile source for peraluminous leucogranites.The slope of the fluid-absent solidus is strongly controlledby the breakdown of Ms in the presence of Qtz, Pl and Kfs. Thissolidus curve has a positive slope ranging from dP/dT = 30 bar/°Cat low P (<6 kbar) to dP/dT = 70 bar/°C at higher P (6–15kbar). The relationships between the Ms vapour-absent solidusand the PTt metamorphic paths in different sectors of the Iberianmassif have two important implications: (1) melt productivityis strongly favoured at low P; (2) anatexis in the Iberian massifprobably took place by decompression associated with crustalthinning and extension. These results are in agreement withthe relationships between granite production and tectonic deformationphases observed in the Iberian massif. Our results emphasizethat anatexis is a process that is strongly controlled bothby the phase relationships of the crustal protoliths and bythe thermal structure of the continental crust. Consequently,one must be careful when assigning potential crustal protolithsto particular granite associations exclusively on the basisof geochemical comparisons. KEY WORDS: anatexis; Hercynian orogen; Iberian massif 相似文献
14.
Fluid-absent melting experiments on a zoisite- and phengite-bearingeclogite (omphacite, garnet, quartz, kyanite, zoisite, phengiteand rutile) were performed to constrain the melting relationsof these hydrous phases in natural assemblages, as well as themelt and mineral compositions produced by their breakdown. From1·0 to 3·2 GPa the solidus slopes positively from1·5 GPa at 850°C to 2·7 GPa at 1025°C,but bends back at higher pressures to 975°C at 3·2GPa. The melt fraction is always low and the melt compositionsalways felsic and become increasingly so with increasing pressure.The normative Ab–An–Or compositions of the initialmelts vary from tonalites at 1·0 GPa to tonalite–trondhjemitesat 1·5 GPa, adamellites at 2·1 and 2·7GPa, and to true granites at 3·2 GPa. At pressures < 相似文献
15.
We present results of dehydration melting experiments [3–15kbar, 810–950C f(O2) QFM (quartz-fayalite-magetite)and Ni-NiO] on two Fe-rich mixtures of biotite (37%), plagioclaseAn38 (27%), quartz (34%) and ilmenite (2%), which differ onlyin their biotite compositions (mg-number 23 and 0.4). Dehydrationmelting of metagreywackes of constant modal composition generatesa wide range of melt fractions, melt compositions and residualassemblages, through the combined effects of pressure, Fe/Mgratio and f(O2). Crystallization of garnet is the chief controlon melting behavior, and is limited by two reactions: (1) thebreakdown of garnet + quartz to orthopyroxene + plagioclaseat low P, and (2) the oxidation of garnet to magnetite + anorthite+ quartz (enstatite), which is sensitive to both f(O2) andP. Because of these reactions, melting of Mg-rich metagreywackesis rather insensitive to f(O2) but strongly sensitive to P;the converse is true for Fe-rich metagreywackes. Garnet crystallizationrequires that plagioclase break down incongruently, liberatingalbite. This increases the Na2O content of the melts and enhancesmelt production. Thus, melting of metagreywacke in a reducingdeep-crustal environment (with garnet stable) would producemore, and more sodic, melt than would garnet-absent meltingof the same source material in a relatively oxidizing, shallow-crustalenvironment. KEY WORDS: anatexis; metasediments; gneisses; granites; garnet
*Corresponding author. Telephone: 706-542-2394; fax: 706-542-2425; e-mail: alpatino{at}uga.cc.uga.edu 相似文献
16.
RAFFAELE DI CUIA ALBERTO RIVA ANDREA SCIFONI ALESSANDRO MORETTI CHRISTOPH SPÖTL BRUNO CALINE 《Sedimentology》2011,58(6):1347-1369
A multidisciplinary study, conducted over the carbonate platform deposits of the Liassic Calcari Grigi Group (Southern Alps), highlighted how the use of outcrop analogues can contribute to better define the distribution of dolomitic bodies related to fault networks, to characterize the petrophysical properties of the dolomitic sequence and unravel a complex diagenetic history. This study was carried out in the Asiago Plateau (southernmost part of the eastern Southern Alps, northern Italy) which provides excellent outcrops of the Jurassic Calcari Grigi Group. The dolomitization of the Jurassic sequence is variable in terms of stratigraphic extension and geographic distribution. In the studied localities the dolomitization is generally limited to the Mount Zugna Formation and is characterized by an undulatory front, with ‘sub‐vertical dolomitic chimneys’ along the major faults. Within this unit, and often associated with faults, stacked high‐porosity and permeability bed‐parallel dolomitic bodies are developed that show excellent petrophysical properties. The dolomitic intervals are characterized by pervasive unimodal and patchy polymodal dolomite crystals. Thin section, cathodoluminescence, isotopic and fluid inclusion analyses were used to constrain the paragenetic evolution of the sequence which is similar in all the studied localities. The first dolomitization stage is marked by zoned dolomite crystals with a dull luminescent core. The porosity is thought to have increased after this stage, with dark blue luminescent dolomite accompanied by the corrosion of older crystals. The appearance of saddle dolomite marks the onset of the porosity reduction stage, ending with the infilling of vugs and the remaining open pores with calcite cement. The diagenetic evolution locally stopped at the saddle dolomite stage with the complete occlusion of the remaining pores. Paragenetic and fluid‐inclusion data suggest an evolutionary trend of increasing temperatures and decreasing salinity toward brackish fluids responsible for dolomite and calcite precipitation. The integration of the available data seem to indicate that the diagenetic evolution of the study area is related to: (i) the interplay between evolving fluids (from marine to brackish); (ii) the burial of the sequence (increasing temperature); and (iii) the evolution of the hydrogeological system (fault and fracture network, fluid mixing). This complex paragenetic evolution is strongly linked to the evolution of the porosity framework that evolved from a good, widespread network in the early stages of the burial history to a confined system in the later stages due to reduction of porosity by the deposition of late calcite and dolomite cements. 相似文献
17.
This study focuses on storm deposits in the Muschelkalk facies of the Betic Cordillera (southern Spain) and interprets their deposition mechanisms. Three types of storm deposit are distinguished: (i) pot/gutter casts; (ii) tempestite beds; and (iii) storm‐winnowed deposits. Each deposit provides information about the carbonate platform environment in which it was deposited. The tempestite models proposed are: (i) the bypass‐zone tempestite model, occurring in a muddy ramp at the epicontinental basin margin. This model is characterized by potholes and gutters that form in a shoreline bypass‐zone during storms; (ii) the gradient‐current tempestite model in which frequent tempestite beds are related to storm gradient currents. Thickness and grain size decrease towards the deep distal ramp; and (iii) the winnowed deposit tempestite model whereby storm deposits are winnowed and deposited in the same environment with only short lateral transport having occurred. This model evokes more restricted and shallower conditions, lagoons or inland seas. The distribution of all these deposits in the stratigraphic sections studied corroborate the eustatic third‐order cycle identified, although the different features of the storm deposits and their positions in each section indicate a subsidence varying in time and space. In the transgressive stage, the margins of the epicontinental basin were a well‐developed ramp with potholes and gutters. In contrast, during the high sea‐level stage, storm deposits generated tempestite beds or storm‐winnowed deposits in the different areas. The epicontinental carbonate platform with ramp edges evolved into a complex depositional system of coastal and shallow‐marine environments with lagoons and restricted inland seas. Thus, the epicontinental platform underwent substantial change from the Late Anisian to the Late Ladinian and this is reflected in its storm deposits. 相似文献
18.
ALBERTO V. REYES GRANT D. ZAZULA SVETLANA KUZMINA THOMAS A. AGER DUANE G. FROESE 《第四纪科学杂志》2011,26(3):345-352
Last interglacial sediments in unglaciated Alaska and Yukon (eastern Beringia) are commonly identified by palaeoecological indicators and stratigraphic position ～2–5 m above the regionally prominent Old Crow tephra (124 ± 10 ka). We demonstrate that this approach can yield erroneous age assignments using data from a new exposure at the Palisades, a site in interior Alaska with numerous exposures of last interglacial sediments. Tephrochronology, stratigraphy, plant macrofossils, pollen and fossil insects from a prominent wood‐rich organic silt unit are all consistent with a last interglacial age assignment. However, six 14C dates on plant and insect macrofossils from the organic silt range from non‐finite to 4.0 14C ka BP, indicating that the organic silt instead represents a Holocene deposit with a mixed‐age assemblage of organic material. In contrast, wood samples from presumed last interglacial organic‐rich sediments elsewhere at the Palisades, in a similar stratigraphic position with respect to Old Crow tephra, yield non‐finite 14C ages. Given that local permafrost thaw since the last interglaciation may facilitate reworking of older sediments into new stratigraphic positions, minimum constraining ages based on 14C dating or other methods should supplement age assignments for last interglacial sediments in eastern Beringia that are based on palaeoecology and stratigraphic association with Old Crow tephra. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
19.
We performed vapor-absent melting and crystallization experimentson two bulk compositions that model metamorphic rocks containinga single hydrous phase: a biotite gneiss [37% bio (mg-number55), 34% qtz, 27% plg (An38), 2% ilm] and a quartz amphibolite[54% hbl (mg-number 60), 24% qtz, 20% plg (An38), 2% ilm]. Experimentswere performed at 3 and 5 kbar in internally heated pressurevessels (IHPV), and at 7, 10, 125 and 15 kbar in piston cylinderapparatus (PC), from the vapor-absent solidi to (at least) thetemperature at which the hydrous mineral disappeared. Dehydration-meltingbegins at similar temperatures in both bulk compositions, rangingfrom T850C at P = 3 kbar T930C at P = 15 kbar. The hydrousmineral disappears 50C above the solidus in both systems, exceptin IHPV experiments at f(O2) above Ni–NiO, in which biotitestability extends up to atleast 80C above the solidus. At theT at which the hydrous minerals disappear the biotite gneissproduces 2–3 times more melt than the quartz amphibolite(50–60 wt% vs 20–30 wt%). In both systems, variationsin melt productivity with P are controlled by three competingfactors: (1) the positive d P/dT slopes of the solidi, (2) decreasingH2O activity with increasing P at constant H2O content, and(3) Na2O activity, which increases with P concomitantly withbreakdown of plagioclase. Melt productivities at T = 920–950Care maximized at intermediate pressures (7 kbar). The biotitegneiss produces strongly peraluminous granitic melts (SiO2>70wt%) and residual assemblages of quartz norite (P>125 kbar)or garnet pyroxenite (P>125 kbar). The quartz amphiboliteproduces strongly peraluminous granodioritic melts (SiO2>70wt%) that coexist with clinopyroxene + orthopyroxene + plagioclase+ quartz at P>10 kbar)garnet. The results of coupled meltingand crystallization experiments on the quartz amphibolite suggestthat strongly peraluminous granitoid rocks (e.g. cordierite-bearingand two-mica granites) can be derived from melting of Al-poorprotoliths. KEY WORDS: dehydration-melting; biotite gneiss; amphibolite; felsic magmas
*Corresponding author 相似文献
20.