Partition of arsenic in soils sediments and the origin of naturally elevated concentrations in groundwater of the southern pampa region (Argentina)     

María del Carmen Blanco  Juan Darío Paoloni  Hector Morrás  Carmen Fiorentino  Mario Eduardo Sequeira  Nilda N. Amiotti  Oscar Bravo  Silvana Diaz  Martín Espósito 《Environmental Earth Sciences》2012,66(7):2075-2084

Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L⁻¹) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations (loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L⁻¹; in 27% As concentrations ranged from 10 to 50 μg L⁻¹ and in 58% it reached 60–500 μg L⁻¹. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba (p < 0.01; r ² = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r ² = 0.85) and As–Cr (p < 0.05; r ² = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding the guideline value for drinking water.  相似文献   

Sedimentary record of Late Paleozoic rift and break-up in Northern Gondwana: a case history from the Thini Chu Group and Tamba-Kurkur Formation (Dolpo Tethys Himalaya,Nepal)     

Dario Sciunnach  Eduardo Garzanti 《Geodinamica Acta》2013,26(1):41-56

The Gottero unit of the Northern Apennines, Italy, is representative of the sedimentary cover of the Ligure-Piemontese oceanic lithosphere. This unit consists of a thick sedimentary sequence that includes Valanginian-Santonian pelagic deposits and Campanian-early Paleocene turbiditic deposits. The latter are overlain by early Paleocene trench deposits related to frontal tectonic erosion of the accretionary wedge slope. This sequence is interpreted as recording trenchward motion of the oceanic lithosphere.

The Gottero unit records a pre-Late Oligocene, complex deformation history related to subduction and accretion events. This deformation history has developed through underthrusting (D1a), underplating (D1b and D1c) and later exhumation (D2a and D2b) episodes. The folding phase related to the main underplating sub-phase (D1b) is predated by a sub-phase (D1a) connected to rapid fluid escape and followed by a sub-phase dominated by the development of shear zones (D1c). The D1b sub-phase is characterized by similar folds and a slaty cleavage developed under P/T conditions of 0.4GPa/210°-270 °C. The D1c sub-phase, characterized by west-verging thrusts, is particularly signficative in understanding the dynamics of the Ligure-Piemontese accretionary wedge because it testifies active shortening of the Gottero unit also after its transfer to the prism. In addition, sub-phase D1c represents the transition from the sub-phases connected to accretion and the tectonics dominated by extension, characterized by parallel folds and low-to high-angle normal faults. The gravity driven extension is represented by the D2a and D2b sub-phases and can be interpreted as the result of the thicknening of the Ligure-Piemontese accretionary wedge, produced by continuous underplating at its base but also by shortening of the previously underplated units. These final tectonic events resulted in the exhumation of the Gottero unit to the surface during the Early Oligocene, when this Unit became one of the source areas of the conglomerates deposited in the Tertiary Piedmont basin.

This deformation history suggests the occurrence of a complex sequence of deformations during the transition from accretion to exhumation, even in the intermediate levels of the accretionary wedge.  相似文献   

Climate signal in varve thickness: Lake La Cruz (Spain), a case study   总被引：1，自引：0，他引：1  

Lidia Romero-Viana  Ramon Julià  Antonio Camacho  Eduardo Vicente  Maria Rosa Miracle 《Journal of Paleolimnology》2008,40(2):703-714

Lake La Cruz is a meromictic, karstic lake with annually laminated sediment formed by summer pulses of calcite deposition. The aim of this study was to explore the potential use of the laminated sediment from Lake La Cruz as a quantitative climate proxy, by calibrating lamina thickness against instrumental climate data. Statistical analysis of the relation between lamina thickness and the meteorological dataset indicated a high correlation between calcium carbonate lamina thickness and rainfall from December to March (r  = 0.725, P < 0.01, n = 35). Winter rainfall anomalies in the area are, in turn, highly negatively correlated with the North Atlantic Oscillation index (NAO, r = −0.832; P < 0.01; n = 53). We propose a regression model to infer past winter rainfall from calcium carbonate laminae thickness. These results highlight new possibilities for paleoenvironmental research using calcite laminated sediment records as climate proxies, especially to study past rainfall variability.  相似文献   

Quantitative assessment of the salinity gradient within the estuarine systems in the southern Bay of Biscay using benthic foraminifera     

Eduardo Leorri  Alejandro Cearreta 《Continental Shelf Research》2009

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Grain-size dependence of sediment composition and environmental bias in provenance studies     

Eduardo Garzanti  Sergio Andò  Giovanni Vezzoli 《Earth and Planetary Science Letters》2009,277(3-4):422-432

This article investigates both experimentally and theoretically the compositional changes associated with textural effects and hydraulic sorting during sediment transport and deposition, which cause systematic distortion in quantitative provenance analysis (“environmental bias”). Traditional procedures aimed at eliminating textural noise find limited success. The Gazzi–Dickinson method cannot remove hydrodynamic-related modal variability. Multiple size-window strategies are time-consuming. Narrow or moving size-window strategies represent misleading or impractical short cuts, being less convenient options than simply analysing each sample in bulk. New concepts introduced here unravel the superposed causes of compositional variability in modern sediments. Intrasample modal variability, fundamentally explained by settling-equivalence relationships, can be accurately modelled mathematically. Intersample modal variability, principally resulting from selective entrainment, can be assessed and removed by a simple principle. In absence of provenance changes and environmental bias, the weighted average density of terrigenous grains (SRD index) should be equal, for each sample and each grain-size class of each sample, to the weighted average density of source rocks. By correcting relative abundances of detrital minerals in proportion to their densities, we can restore the appropriate SRD index for any provenance and subprovenance type in each sample or grain-size class. Modal variability is effectively reduced by this procedure, which can be applied confidently to modern sediments deposited by tractive currents in any environment. Good results are obtained even for placer sands and finest classes where heavy-mineral concentration is strongest. Such “SRD correction” also successfully compensates for biased narrow-window modes, thus providing a numerical solution of general validity to the problem of environmental bias in sedimentary petrology. After compensating for settling-equivalence and selective-entrainment effects, residual size-dependent compositional variability may be provenance-related. Minor in Ganga–Brahmaputra sediments, provenance-related effects are spectacularly displayed in the Nile basin, where volcaniclastic silt mixes with basement-derived quartzofeldspathic sand and wind-blown Saharan quartz.  相似文献   

Populus nigra L. establishment and fluvial landform construction: biogeomorphic dynamics within a channelized river          下载免费PDF全文

Dov Corenblit  Johannes Steiger  Gaspard Charrier  José Darrozes  Virginia Garófano‐Gómez  Alexandre Garreau  Eduardo González  Angela M. Gurnell  Borbála Hortobágyi  Frédéric Julien  Luc Lambs  Sébastien Larrue  Thierry Otto  Erwan Roussel  Franck Vautier  Olivier Voldoire 《地球表面变化过程与地形》2016,41(9):1276-1292

Populations of the riparian pioneer species Populus nigra L. which establish on alluvial bars within river channels modulate sediment dynamics and fluvial landforms. Dense cohorts of P. nigra have colonized gravel point bars along the channelized River Garonne, France, during the last 20 years and have enhanced the vertical, lateral and longitudinal development of the bars. For this period, the geomorphic characteristics of two wooded point bars on this laterally stable river are closely linked to the spatial distribution and intensity of establishment and resistance of different cohorts of P. nigra. Furthermore, P. nigra colonization dynamics were controlled by engineer effects of this same species. This relationship is illustrated by a significant correlation between key geomorphic and biological variables measured in situ and characterized with a set of four aerial photographs taken between 2000 and 2010. The development of wooded point bars, which are discrete biogeomorphic units, over the studied period, appear to result from a specific biogeomorphic positive feedback of matter aggregation and vegetation establishment related to sediment trapping and stabilization by pioneer engineer plants. We propose a conceptual model of biogeomorphic unit construction for channelized, lateral stable rivers. We consider the resultant biogeomorphic units as functional from an ecological point of view because P. nigra enhances at the cohort scale (i) its own inherent capacity to resist hydrogeomorphic disturbances, and (ii) its resilience capacity as a result of successful colonization, especially downstream of mature poplar stands. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Tracking sediment provenance and erosional evolution of the western Greater Caucasus          下载免费PDF全文

Giovanni Vezzoli  Eduardo Garzanti  Stephen J. Vincent  Sergio Andò  Andrew Carter  Alberto Resentini 《地球表面变化过程与地形》2014,39(8):1101-1114

This article investigates landscape characteristics and sediment composition in the western Greater Caucasus by using multiple methods at different timescales. Our ultimate goal is to compare short‐term versus long‐term trends in erosional processes and to reconstruct spatio‐temporal changes in sediment fluxes as controlled by partitioning of crustal shortening and rock uplift in the orogenic belt. Areas of active recent uplift are assessed by quantitative geomorphological techniques [digital elevation model (DEM) analysis of stream profiles and their deviation from equilibrium] and compared with regions of rapid exhumation over longer time intervals as previously determined by fission‐track and cosmogenic‐nuclide analyses. Complementary information from petrographic and heavy‐mineral analyses of modern sands and ancient sandstones is used to evaluate erosion integrated throughout the history of the orogen. River catchments displaying the highest relief, as shown by channel‐steepness indices, correspond with the areas of most rapid exhumation as outlined by thermochronological data. The region of high stream gradients is spatially associated with the highest topography around Mount Elbrus, where sedimentary cover strata have long been completely eroded and river sediments display the highest metamorphic indices and generally high heavy‐mineral concentrations. This study reinforces the suggestion that the bedrock–channel network can reveal much of the evolution of tectonically active landscapes, and implies that the controls on channel gradient ultimately dictate the topography and the relief along the Greater Caucasus. Our integrated datasets, obtained during a decade of continuing research, display a general agreement and regularity of erosion patterns through time, and consistently indicate westward decreasing rates of erosional unroofing from the central part of the range to the Black Sea. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Occurrence,distribution and partitioning of nonionic surfactants and pharmaceuticals in the urbanized Long Island Sound Estuary (NY)     

Pablo A. Lara-Martín  Eduardo González-Mazo  Mira Petrovic  Damià Barceló  Bruce J. Brownawell 《Marine pollution bulletin》2014

This work deals with the environmental distribution of nonionic surfactants (nonylphenol and alcohol ethoxylates), their metabolites (NP, nonylphenol; NPEC, nonylphenol ethoxycarboxylates; and PEG, polyethylene glycols) and a selection of 64 pharmaceuticals in the Long Island Sound (LIS) Estuary which receives important sewage discharges from New York City (NYC). Most target compounds were efficiently removed (>95%) in one wastewater treatment plant monitored, with the exception of NPEC and some specific drugs (e.g., hydrochlorothiazide). Concentrations of surfactants (1.4–4.5 μg L⁻¹) and pharmaceuticals (0.1–0.3 μg L⁻¹) in seawater were influenced by tides and sampling depth, consistent with salinity differences. Surfactants levels in suspended solids samples were higher than 1 μg g⁻¹, whereas only most hydrophobic or positively charged pharmaceuticals could be found (e.g., tamoxifen, clarithromycin). Maximum levels of target compounds in LIS sediments (PEG at highest concentrations, 2.8 μg g⁻¹) were measured nearest NYC, sharply decreasing with distance from major sewage inputs.  相似文献   

Occurrence and spatial distribution of metals in intertidal sediments of a temperate estuarine system (Bahía Blanca,Argentina)     

Pía Simonetti  Sandra Elizabeth Botté  Jorge Eduardo Marcovecchio 《Environmental Earth Sciences》2017,76(18):636

Intertidal sediments of the inner and middle zone from the Bahía Blanca estuary were sampled for geochemical and environmental assessment of metals (Cd, Cu, Pb, Zn, Mn, Ni, Cr and Fe). Results indicate that both the organic matter content and the sediment grain size plays an important role in controlling the differential concentrations of the metals found in sediments from both zones. For most of the elements (except Mn), sediment metal concentrations were greater in the middle zone, although the concentrations did not exceed the maximums for quality of marine sediments. In this sense, anthropogenic impact (i.e., sewage drain) appears to be a key factor in the distribution of metals within the estuarine system. Comparing the levels obtained with quality levels (LEL and SEL), except Cu that showed levels slightly above the LEL, the rest of the concentrations of metals were lower to those levels. The low metal concentrations obtained within this highly impacted estuarine system suggest that the great volume of water that flooding the extensive flats in each tidal cycle has much importance. Although the potential risks of metals to the estuarine environment were low, taking into account the toxicity of some of these metals, continuity of monitoring is highly recommended.  相似文献   

Hydrogeological characterization of carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias,N Spain) by means of geochemical and isotopic techniques     

Beatriz González-Fernández  Mónica Meléndez-Asensio  Eduardo Menéndez-Casares 《Environmental Earth Sciences》2009,59(4):913-928

Chemical and isotopic analyses of groundwater from the carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias, northern Spain) were carried out. Nine springs were sampled to determine major cations and anions, as well as the stable isotopes of the water molecule (δ²H and δ¹⁸O) and sulphate (δ³⁴S) values. Also, δ³⁴S values from gypsum coming both from Triassic rocks and bottom of Jurassic sequence were also determined. The results obtained were used to classify the waters with a genetic criteria in three groups: (1) waters with a high gypsum influence, with sulphate coming from Jurassic gypsum, (2) waters without gypsum influence, where sulphate source could be atmospheric deposition from industrial processes and marine aerosol, and (3) waters with some gypsum influence, in which sulphate origin could be a combination of different sources. In relation to recharge, δ²H and δ¹⁸O values were close to those of Global Meteoric Water Line and fit a local line that suggests a meteoric origin. The estimated elevations for spring recharge are in agreement with those obtained from hydrogeological maps.  相似文献