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41.
A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate (i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and (ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.  相似文献   
42.
In the framework of the WFD 2000/60/EC intercalibration process the updated versions of the EEI and R‐MaQI, proposed by Italy and Greece for the transitional waters, have been applied to the macrophytes of the Venice lagoon to test their comparability and relationships with the pressure gradients. Submerged macrophytes were collected during spring 2007 at 60 sites spread within the lagoon. At each site, five random samples were collected and the total coverage of benthic macrophytes in the field was estimated based on a number of tests of the bottom. To assess seagrass epiphytes, five shoots were collected for each replicate. Physico‐chemical data were collected in the water column at 14 sites selected to reflect the main hydro‐geomorphological and trophic gradients of the lagoon. The analyses performed indicated that the two metrics appeared to be weakly intercalibrated and only the 30% of the sampling sites displayed the same quality class. The main differences fell into the Moderate and Low classes and the two indices provided discordant results in the intermediate and confined areas of the lagoon. In contrast, the two indices showed good affinity in the marine areas of inlets, which are characterised by seagrass meadows and late‐successional macroalgae. Similar results were evidenced also in a redundancy analysis by the different relationships between quality classes and the physico‐chemical gradients. The main reason for this seems to be the heterogeneity of species–environment relationships inside the groups of species on which the indices are based. Critical aspects of methodological differences and applicability of the macrophyte indices proposed by Italy and Greece for the transitional waters of the Mediterranean eco‐region are discussed.  相似文献   
43.
Integration of geomorphology, stratigraphy, sedimentology and morphotectonics in the analysis of the lower Cecina River reach, coastal Tuscany, reveals an undocumented historical channel avulsion. Geomorphological evidence and radiocarbon dating support that, from the Last Glacial Maximum until the end of the 16th century, the Cecina River flowed north of the present course and formed a well-developed cuspate delta. Two concurrent factors, active tectonics as a preparing factor and discharge regime as an activation factor, are thus inferred to have favored the avulsion of Cecina River. Fragmentary archaeological and historical records indicate that the late Holocene Cecina River plain was virtually unpopulated until the latest 16th century. This seems the main reason why high-magnitude hydrological events and prominent river channel avulsions were not reported in historical chronicles. From this perspective, geomorphological data may provide important knowledge and understanding of recent dynamics of environmental change when historical record is lacking or missing.  相似文献   
44.
Laboratory sandbox validation of pollutant source location methods   总被引:1,自引:0,他引:1  
Inverse methods can be used to recover the pollutant source location from concentration data. In this paper, the relative effectiveness of two proposed methods, simultaneous release function and source location identification (SRSI) and backward probability model based on adjoint state method (BPM-ASM) are evaluated using real data collected by using experimental equipment. The device is a sandbox that reproduces an unconfined aquifer in which all the variables are controlled. A numerical model was calibrated using experimental observations. The SRSI is a stochastic procedure which finds the source location and the release history by means of a Bayesian geostatistical approach (GA). The BPM-ASM provides the backward probability location of the pollutant detected at a monitoring point by means of a reverse transport simulation. The results show that both methods perform well. While the simultaneous release function and SRSI method requires a preliminary delineation of a probable source area and some weak hypotheses about the statistical structure of the unknown release function, the backward probability model requires some hypothesis about the contaminant release time. A case study was performed using two observation points only, and despite the scarcity of data, both methodologies were able to accurately reconstruct the true source location. The GA has the advantage to recover the release history function too, whilst the backward probability model works well with fewer data. If there are many observations, both methodologies may be computationally heavy. A transfer function approach has been adopted for the numerical definition of the sensitivity matrix in the SRSI method. The reliability of the experimental equipment was tested in previous laboratory works, conducted under several different conditions.  相似文献   
45.
46.
Mineralogy and Petrology - Clinopyroxene and olivine are ubiquitous phases in Somma-Vesuvius (SV) volcanics and for the first time they were systematically studied in several products younger than...  相似文献   
47.
We use a multidisciplinary approach to gather preliminary evidence for a Quaternary east‐dipping extensional detachment in Central Italy. This structure crops out in the Sabini‐Eastern Simbruini (SES) and would be hidden at mid‐crustal depths beneath the L'Aquila 2009 (Mw6.3) epicentral area. The SES geometry is reconstructed through geological mapping, structural analysis and seismic line interpretation. The geometry of the mid‐crustal segment, referred to as the Ocre Segment (OS), is interpreted through seismological analyses of the largest aftershock (Mw5.4) of the L'Aquila 2009 sequence. The kinematic compatibility between the SES and the OS under a common SW–NE tensional field is tested through stress inversion of both geological and seismological data. The reliability of OS activation is tested through slip tendency analysis. Like other Italian cases, the SES and the OS are preliminarily interpreted as expressions at different depths of the same unknown east‐dipping extensional detachment, characterized by a ramp–flat–ramp geometry.  相似文献   
48.
Mineralogy and Petrology - Limestone represents the main raw material for ordinary Portland cement clinker production. In this study eight natural limestones from different geological environments...  相似文献   
49.
Two peridotite suites collected by submersible in the equatorial Atlantic Ocean (Hekinian et al., 2000) were studied for textures, modes, and in situ major and trace element compositions in pyroxenes. Dive SP12 runs along the immersed flank of the St. Peter and Paul Rocks islets where amphibole-bearing, ultramafic mylonites enriched in alkalies and incompatible elements are exposed (Roden et al., 1984), whereas dive SP03 sampled a small intra-transform spreading centre situated about 370 km east of the St. Peter and Paul Rocks. Both suites are characterized by undeformed, coarse-grained granular textures typical of abyssal peridotites, derived from residual mantle after ~ 15% melting of a DMM source, starting in the garnet stability field. Trace element modelling, textures and lack of mineral zoning indicate that the residual peridotites were percolated, reacted and refertilized by ~ 2.6% partially aggregated melts in the uppermost level of the melting region. This relatively large amount of refertilization is in agreement with the cold and thick lithosphere inferred by previous studies. Freezing of trapped melts occurred as the peridotite entered the conductive layer, resulting in late-stage crystallization of olivine, clinopyroxene, spinel, ± plagioclase. Chondrite-normalized REE patterns in clinopyroxenes from SP03 indicate that they last equilibrated with (ultra-) depleted partial melts. In contrast, REE concentrations in clinopyroxenes from SP12 display U and S shaped LREE-enriched patterns and the calculated compositions of the impregnating melts span the compositional range of the regional basalts, which vary from normal MORB to alkali basalt sometimes modified by chromatographic fractionation with no, or very limited, mineral reaction. Thus the mylonitic band forming the St. Peter and St. Paul Rocks ridge is not a fragment of subcontinental lithospheric mantle left behind during the opening of the Central Atlantic, nor the source of the alkaline basalts as previously suggested. Rather, dive SP12 sampled residual peridotites of normal MORB mantle that were located close to channels transporting alkali basalts. Reacted melts escaping from these channels, infiltrated, and locally equilibrated with, the peridotite matrix by ion exchange reactions. Relicts of the source of the alkaline basalts were not sampled but our study suggests that it was a component of the MORB mantle underlying the St. Paul region.  相似文献   
50.
This paper presents a comprehensive ground response study for the municipality of Villa Collemandina in Northern Tuscany (Italy). This site was selected following a macroseismic analysis of the 1920 Garfagnana earthquake (Mw=6.5), which, at Villa Collemandina, produced damage and losses that were larger than at any other site near the earthquake epicentre, thus indicating the presence of possible site effects. Hence, both experimental and numerical methods are applied in order to investigate the ground response at different locations within the Villa Collemandina municipality. Results obtained from the spectral analysis of earthquake recordings using the reference site method and those from a 2-dimensional dynamic simulation reveal the presence of site effects due to the buried geomorphology (basin-like effects), allowing us to explain the severe damage and losses produced by the 1920 Garfagnana earthquake. As a further result, horizontal to vertical spectral ratio techniques and 1D soil modelling are proved to be inadequate for an effective characterization of the ground response at sites that, like Villa Collemandina, present a complex local geology.  相似文献   
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