Removal of uranium(VI) from aqueous solutions using Eucalyptus citriodora distillation sludge     

H. N. Bhatti  S. Hamid 《International Journal of Environmental Science and Technology》2014,11(3):813-822

Adsorption and desorption of uranium(VI) from dilute aqueous solutions by Eucalyptus citriodora distillation sludge was studied in a batch mode. The potential of Eucalyptus citriodora distillation sludge to remove uranium(VI) from aqueous solutions has been investigated at different conditions of solution pH, metal ion concentrations, biosorbent dosage, biosorbent particle size, contact time and temperature. The results indicated that biosorption capacity of Eucalyptus citriodora distillation sludge was strongly affected by the medium pH, the biosorbent dose, metal ion concentrations and medium temperature. Reduction in particle size increased the biosorption capacity. Langmuir and Freundlich isotherm models were applied to biosorption data to determine the biosorption characteristics. An optimum biosorption capacity (57.75 mg/g) was achieved with pH 4.0, particle size 0.255 mm, biosorbent dose 0.5 g/100 mL and initial uranium(VI) concentration of 100 mg/L. Uranium(VI) removal by Eucalyptus citriodora distillation sludge was rapid, the equilibrium was established within 60 min and pseudo-second-order model was found to fit with the experimental data. The biosorption process decreased with an increase in the temperature indicating its exothermic nature. Pretreatments of biomass with different reagents affected its biosorption capacity. A significant increase (34 %) in biosorption capacity (83.25 mg/g) was observed with benzene treatment. Fourier-transform infra-red studies showed the involvement of carbonyl, carboxyl and amide groups in the biosorption process. The results indicated that sulfuric acid had the best effects as an eluent showing 93.24 % desorption capacity.  相似文献   

Laboratory study of soil-CFRP interaction using pull-out test     

Vahid Toufigh  Farnam Saeid  Ahad Ouria  Chandrakant S. Desai  Hamid Saadatmanesh 《Geomechanics and Geoengineering》2014,9(3):208-214

Soil is a material which is weak in tension; however, different materials such as geotextiles are used to address this inadequacy. In recent years more than one million square metres of geotextiles were used for reinforcing soil. Nevertheless, there are several significant problems associated with geotextiles, such as creep, low modulus of elasticity and susceptibility to aggressive environments. Carbon fibre reinforced polymer (CFRP) was introduced over two decades ago to the field of structural engineering and it can also be used in geotechnical engineering. CFRP has all the benefits associated with geotextiles and it boasts a higher strength, higher modulus, no creep and reliability in aggressive environments. In this investigation, the interface properties of CFRP-sand and fine sand were investigated using the pull-out test. The pull-out test device was designed and assembled using a triaxial loading device and a direct shear device. In the pull-out test, the normal force applied by the triaxial loading and pull-out force is applied by a direct shear device. CFRP samples were prepared in the lab. Precast and cast-in-place samples were tested. The pull-out force and corresponding displacements of each of the materials were recorded and compared.  相似文献   

Distribution of heavy metals in the clastic fine-grained sediments of Gavkhuni playa lake (Southeast of Isfahan,Iran)   总被引：1，自引：1，他引：0  

Hamid Reza Pakzad  Mehrdad Pasandi  Hajar Rahimi 《Environmental Earth Sciences》2014,71(11):4683-4692

The sedimentary basin of Gavkhuni playa lake includes two sedimentary environments of delta and playa lake. These environments consist of mud, sand and salt flats. There are potentials for concentration of heavy metals in the fine-grained sediments (silt and clay) of the playa due to existence of Pb/Zn ore deposits, industrial and agricultural regions in the water catchment of Zayandehrud River terminating to this area. In order to study the concentration of heavy metals and the controlling factors on their distribution in the fine-grained sediments, 13 samples were taken from the muddy facies and concentration of the heavy metals were determined. The results showed that the heavy metal concentrations range in the sediments (in ppm) are Mn (395.5–1,040), Sr (100.4–725.76), Pb (14.66–91.06), Zn (23.59–80.9), Ni (37–73.66), Cu (13.83–29.83), Co (5.73–13.78), Ag (3.03–4.76) and Cd (2.3–5.5) in their order of abundances. The concentration of Ag is noticeable in the sediments relative to the average concentration of this element in mud sediments. The amounts of Pb and Zn are relatively high in all the samples in comparison with the other elements. The concentration of Ni is relatively high in the oxidized samples. The distribution of Pb is directly related to organic matter content of the sediments. The concentrations of Zn, Sr, Cu, Co and Cd in the samples of the playa are lower than those in the delta. The amount of illite is another factor influencing Zn and Pb concentrations. Sr is more concentrated in the sediments with the high content of calcium carbonate. The distribution pattern of Cu, Co, Pb and Mn resembles to that of the clay content of the sediments. The clay content shows positive correlations with Co, Cu and Mn concentrations and negative correlation with Ag. The Sr and Ag concentrations are positively correlated with the amount of CaCO₃. The amounts of Co, Cu, Ni and Mn show negative correlations with the calcium carbonate content. Pb and Co are noticeably correlated with Mn.  相似文献   

Optimal water and waste load allocation in reservoir–river systems: a case study     

Mohammad Reza Nikoo  Reza Kerachian  Akbar Karimi  Ali Asghar Azadnia  Keighobad Jafarzadegan 《Environmental Earth Sciences》2014,71(9):4127-4142

In this paper, a new methodology is developed for optimization of water and waste load allocation in reservoir–river systems considering the existing uncertainties in reservoir inflow, waste loads and water demands. A stochastic dynamic programming (SDP) model is used to optimize reservoir operation considering the inflow uncertainty, and another model called PSO-SA is developed and linked with the SDP model for optimizing water and waste load allocation in downstream river. In the PSO-SA model, a particle swarm optimization technique with a dynamic penalty function for handling the constraints is used to optimize water and waste load allocation policies. Also, a simulated annealing technique is utilized for determining the upper and lower bounds of constraints and objective function considering the existing uncertainties. As the proposed water and waste load allocation model has a considerable run-time, some powerful soft computing techniques, namely, Regression tree Induction (named M5P), fuzzy K-nearest neighbor, Bayesian network, support vector regression and an adaptive neuro-fuzzy inference system, are trained and validated using the results of the proposed methodology to develop real-time water and waste load allocation rules. To examine the efficiency and applicability of the methodology, it is applied to the Dez reservoir–river system in the south-western part of Iran.  相似文献   

Investigation of surface and subsurface displacements due to multiple tunnels excavation in urban area     

Alireza Talebinejad  Hamid Chakeri  Mahdi Moosavi  Yılmaz Özçelik  Bahtiyar Ünver  Mehmet Ali Hindistan 《Arabian Journal of Geosciences》2014,7(9):3913-3923

Underground structures are currently widely used and are built as urbanism develops. The interactions between perpendicularly crossing and parallel tunnels in the Tehran region are investigated by using a full three-dimensional (3D) finite difference analysis with elastic-plastic material models. Special attention is paid to the effect of subsequent tunneling on the support system, i.e., the shotcrete lining and rock bolts of the existing tunnel. Eventually, as the tunnels are excavated at certain levels, the interaction between the tunnels will certainly have a significant influence on both stress distribution and consequently deformations. Since multilayer tunneling is a three-dimensional phenomenon in nature, 3D numerical solutions must be utilized for analyzing effect of perpendicularly crossing tunnels at various levels. As Tohid twin tunnels and Line 7 pass beneath the Line 4 metro tunnel, changes in stress distribution, deformations, and surface settlements are studied for various conditions and the results are presented in this paper. Consequently, it is shown that there is a significant interaction between tunnels that necessitate certain preventive measures to maintain a stable tunneling operation.  相似文献   

Application of artificial intelligence techniques for predicting the flyrock distance caused by blasting operation   总被引：2，自引：0，他引：2  

Ebrahim Ghasemi  Hasel Amini  Mohammad Ataei  Reza Khalokakaei 《Arabian Journal of Geosciences》2014,7(1):193-202

Flyrock arising from blasting operations is one of the crucial and complex problems in mining industry and its prediction plays an important role in the minimization of related hazards. In past years, various empirical methods were developed for the prediction of flyrock distance using statistical analysis techniques, which have very low predictive capacity. Artificial intelligence (AI) techniques are now being used as alternate statistical techniques. In this paper, two predictive models were developed by using AI techniques to predict flyrock distance in Sungun copper mine of Iran. One of the models employed artificial neural network (ANN), and another, fuzzy logic. The results showed that both models were useful and efficient whereas the fuzzy model exhibited high performance than ANN model for predicting flyrock distance. The performance of the models showed that the AI is a good tool for minimizing the uncertainties in the blasting operations.  相似文献   

Diagenetic model of carbonate rocks of Guri Member of Mishan Formation (Lower to Middle Miocene) SE Zagros basin,Iran     

Akbar Heidari  Luis A. Gonzalez  Asadollah Mahboubi  Reza Moussavi-Harami  Greg A. Ludvigson  Govind J. Chakrapani 《Journal of the Geological Society of India》2014,84(1):87-104

In order to understand the post-depositional history of carbonate rocks of Guri Member (Lower to Middle Miocene), three stratigraphic sections were selected in north Bandar-Abbas in southeast of Iran. Sampling was carried out, analyzed for selective parameters such as oxygen and carbon isotopic compositions (δ¹⁸O and δ¹³C) and interpreted in the present study. We recognized several diagenetic processes including micritization, cementation, neomorphism, compaction, dissolution, silicification, dolomitization, fracturing and vein filling. Some of the diagenetic processes occurred at different conditions, so in order to achieve precise interpretation, samples from different carbonate components such as, micrite, fracture cement, solution pore cement, intergranular cement, and some biotic allochems were analyzed. In this study micrite samples were subdivided into two groups including micro-spary and micrite. They were recognized under Cathodoluminescence microscope. In addition, micrite samples were classified into five groups based on their depositional environments: supratidal, lagoon, coral bar, open sea, and open basin. There were minor changes in stable isotope ratios based on the sedimentary environments, stratigraphy successions, and micro-spary or micrite properties. In this study, similar calcite cements in petrography studies were differentiated by stable isotope data. Those calcite cements have formed in different diagenetic environments such as meteoric and burial cements. Paragenetic sequence of carbonate rocks were interpreted by integration of petrographic and isotopic studies. We have reconstructed diagenetic models of Guri Member into four stages including marine, meteoric, burial, and uplifting.  相似文献   

Brittleness Effect on Rock Fatigue Damage Evolution   总被引：1，自引：0，他引：1  

Hamid Reza Nejati  Abdolhadi Ghazvinian 《Rock Mechanics and Rock Engineering》2014,47(5):1839-1848

The damage evolution mechanism of rocks is one of the most important aspects in studying of rock fatigue behavior. Fatigue damage evolution of three rock types (onyx marble, sandstone and soft limestone) with different brittleness were considered in the present study. Intensive experimental tests were conducted on the chosen rock samples and acoustic emission (AE) sensors were used in some of them to monitor the fracturing process. Experimental tests indicated that brittleness strongly influences damage evolution of rocks in the course of static and dynamic loading. AE monitoring revealed that micro-crack density induced by the applied loads during different stages of the failure processes increases as rock brittleness increases. Also, results of fatigue tests on the three rock types indicated that the rock with the most induced micro-cracks during loading cycles has the least fatigue life. Furthermore, the condition of failure surfaces of the studied rocks samples, subjected to dynamic and static loading, were evaluated and it was concluded that the roughness of failure surfaces is influenced by loading types and rock brittleness. Dynamic failure surfaces were rougher than static ones and low brittle rock demonstrate a smoother failure surface compared to high brittle rock.  相似文献   

An alternative method for non-negative estimation of variance components   总被引：1，自引：1，他引：0  

Khosro Moghtased-Azar  Ramin Tehranchi  Ali Reza Amiri-Simkooei 《Journal of Geodesy》2014,88(5):427-439

A typical problem of estimation principles of variance and covariance components is that they do not produce positive variances in general. This caveat is due, in particular, to a variety of reasons: (1) a badly chosen set of initial variance components, namely initial value problem (IVP), (2) low redundancy in functional model, (3) an improper stochastic model, and (4) data’s possibility of containing outliers. Accordingly, a lot of effort has been made in order to design non-negative estimates of variance components. However, the desires on non-negative and unbiased estimation can seldom be met simultaneously. Likewise, in order to search for a practical non-negative estimator, one has to give up the condition on unbiasedness, which implies that the estimator will be biased. On the other hand, unlike the variance components, the covariance components can be negative, so the methods for obtaining non-negative estimates of variance components are not applicable. This study presents an alternative method to non-negative estimation of variance components such that non-negativity of the variance components is automatically supported. The idea is based upon the use of the functions whose range is the set of all positive real numbers, namely positive-valued functions (PVFs), for unknown variance components in stochastic model instead of using variance components themselves. Using the PVF could eliminate the effect of IVP on the estimation process. This concept is reparameterized on the restricted maximum likelihood with no effect on the unbiasedness of the scheme. The numerical results show the successful estimation of non-negativity estimation of variance components (as positive values) as well as covariance components (as negative or positive values).  相似文献   

Flood seasonality‐based regionalization methods: a data‐based comparison     

Ali Sarhadi  Reza Modarres 《水文研究》2011,25(23):3613-3624

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