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71.
72.
Based on geological and archaeological proxies from NW Russia and NE Estonia and on GIS‐based modelling, shore displacement during the Stone Age in the Narva‐Luga Klint Bay area in the eastern Gulf of Finland was reconstructed. The reconstructed shore displacement curve displays three regressive phases in the Baltic Sea history, interrupted by the rapid Ancylus Lake and Litorina Sea transgressions c. 10.9–10.2 cal. ka BP and c. 8.5–7.3 cal. ka BP, respectively. During the Ancylus transgression the lake level rose 9 m at an average rate of about 13 mm per year, while during the Litorina transgression the sea level rose 8 m at an average rate of about 7 mm per year. The results show that the highest shoreline of Ancylus Lake at an altitude of 8–17 m a.s.l. was formed c. 10.2 cal. ka BP and that of the Litorina Sea at an altitude of 6–14 m a.s.l., c. 7.3 cal. ka BP. The oldest traces of human activity dated to 8.5–7.9 cal. ka BP are associated with the palaeo‐Narva River in the period of low water level in the Baltic basin at the beginning of the Litorina Sea transgression. The coastal settlement associated with the Litorina Sea lagoon, presently represented by 33 Stone Age sites, developed in the area c. 7.1 cal. ka BP and existed there for more than 2000 years. Transformation from the coastal settlement back to the river settlement indicates a change from a fishing‐and‐hunting economy to farming and animal husbandry c. 4.4 cal. ka BP, coinciding with the time of the overgrowing of the lagoon in the Narva‐Luga Klint Bay area.  相似文献   
73.
This paper compares stable isotope (δ18O and δ13C) records of early–middle Holocene land snail shells from the archaeological deposits of Grotta di Latronico 3 (LTR3; southern Italy) with modern shell isotopic data. No substantial interspecific variability was observed in shell δ18O (δ18Os) of modern specimens (Pomatias elegans, Cornu aspersum, Eobania vermiculata, Helix ligata and Marmorana fuscolabiata). In contrast, interspecific shell δ13C (δ13Cs) variability was significant, probably due to different feeding behaviour among species. The δ18Os values of living land snails suggest that species hibernate for a long period during colder months, so that the signal of 18O‐depleted winter rainfall in their δ18Os is lost. This suggests that δ18Os and δ13Cs values of Pomatias elegans from this archaeological succession provide valuable clues for seasonal (spring–autumn) climatic conditions during the early–middle Holocene. The δ18Os values of fossil specimens are significantly lower than in modern shells and in agreement with other palaeoclimatic records, suggesting a substantial increase of precipitation and/or persistent changes in air mass source trajectories over this region between ca. 8.8 cal ka BP and 6.2–6.7 ka ago. The δ13Cs trend suggests a transition from a slightly 13C‐enriched to a 13C‐depleted diet between early and middle Holocene compared to present conditions. We postulate that this δ13Cs trend might reflect changes in the C3 vegetation community, potentially combined with other environmental factors such as regional moisture increase and the progressive decrease of atmospheric CO2 concentration. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ56Fe and δ30Si with increasing silica content as well as a systematic increase in δ56Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ56Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ56Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ56Fe = +0.05 ± 0.02 ‰; δ30Si = ?0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.  相似文献   
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Emissions of biogenic volatile organic compounds (BVOC) were measured using a relaxed eddy accumulation (REA) technique on an above-canopy tower in a temperate forest (Changbai Mountain, Jilin province, China) during the 2010 and 2011 summer seasons. Solar global radiation and photosynthetically active radiation (PAR) were also measured. Based on PAR energy dynamic balance, an empirical BVOC emission and PAR transfer model was developed that includes the processes of BVOC emissions and PAR transfer above the canopy level, including PAR absorption and consumption, and scattering by gases, liquids, and particles (GLPs). Simulated emissions of isoprene and monoterpenes were in agreement with observations. The averages of the relative estimator biases for the flux were 39.3 % for isoprene, and 27.1 % for monoterpenes in the 2010 and 2011 growing seasons, with NMSE (normalized mean square error) values of 0.133 and 0.101, respectively. The observed and simulated mean diurnal variations of isoprene and monoterpenes in the 2010 and 2011 growing seasons were evaluated for the validation of the empirical model. Under observed atmospheric conditions, the sensitivity analysis showed that emissions of isoprene and monoterpenes were more sensitive to changes in PAR than to water vapor content or to the magnitude of the scattering factor. The emissions of isoprene and monoterpenes in the 2010 and 2011 growing seasons (from June to September) were estimated using this empirical model along with hourly observational data, with mean hourly emissions of 1.71 and 1.55 mg m?2 h?1 for isoprene, and 0.48 and 0.47 mg m?2 h?1 for monoterpenes in 2010 and 2011, respectively. As formaldehyde (HCHO) is considered as the main oxidation product of isoprene and monoterpenes, it is necessary to investigate the link between HCHO and BVOC emissions. GOME-2 HCHO vertical column densities (VCDs) can be used to estimate BVOC emission fluxes in the Changbai Mountain temperate forest.  相似文献   
79.
This article assesses Japan's carbon budgets up to 2100 in the global efforts to achieve the 2?°C target under different effort-sharing approaches based on long-term GHG mitigation scenarios published in 13 studies. The article also presents exemplary emission trajectories for Japan to stay within the calculated budget.

The literature data allow for an in-depth analysis of four effort-sharing categories. For a 450?ppm CO2e stabilization level, the remaining carbon budgets for 2014–2100 were negative for the effort-sharing category that emphasizes historical responsibility and capability. For the other three, including the reference ‘Cost-effectiveness’ category, which showed the highest budget range among all categories, the calculated remaining budgets (20th and 80th percentile ranges) would run out in 21–29 years if the current emission levels were to continue. A 550?ppm CO2e stabilization level increases the budgets by 6–17 years-equivalent of the current emissions, depending on the effort-sharing category. Exemplary emissions trajectories staying within the calculated budgets were also analysed for ‘Equality’, ‘Staged’ and ‘Cost-effectiveness’ categories. For a 450?ppm CO2e stabilization level, Japan's GHG emissions would need to phase out sometime between 2045 and 2080, and the emission reductions in 2030 would be at least 16–29% below 1990 levels even for the most lenient ‘Cost-effectiveness’ category, and 29–36% for the ‘Equality’ category. The start year for accelerated emissions reductions and the emissions convergence level in the long term have major impact on the emissions reduction rates that need to be achieved, particularly in the case of smaller budgets.

Policy relevance

In previous climate mitigation target formulation processes for 2020 and 2030 in Japan, neither equity principles nor long-term management of cumulative GHG emissions was at the centre of discussion. This article quantitatively assesses how much more GHGs Japan can emit by 2100 to achieve the 2?°C target in light of different effort-sharing approaches, and how Japan's GHG emissions can be managed up to 2100. The long-term implications of recent energy policy developments following the Fukushima nuclear disaster for the calculated carbon budgets are also discussed.  相似文献   
80.
During the onset of caldera cluster volcanism at a new location in the Snake River Plain (SRP), there is an increase in basalt fluxing into the crust and diverse silicic volcanic products are generated. The SRP contains abundant and compositionally diverse hot, dry, and often low-δ18O silicic volcanic rocks produced through time during the formation of individual caldera clusters, but more H2O-rich eruptive products are rare. We report analyses of quartz-hosted melt inclusions from pumice clasts from the upper and lower Arbon Valley Tuff (AVT) to gain insight into the initiation of caldera cluster volcanism. The AVT, a voluminous, caldera-forming rhyolite, represents the commencement of volcanism (10.44 Ma) at the Picabo volcanic field of the Yellowstone hotspot track. This is a normal δ18O rhyolite consisting of early and late erupted members (lower and upper AVT, respectively) with extremely radiogenic Sr isotopes and unradiogenic Nd isotopes, requiring that ~50 % of the mass of these elements is derived from melts of Archean upper crust. Our data reveal distinctive features of the early erupted lower AVT melt including: variable F concentrations up to 1.4 wt%, homogenous and low Cl concentrations (~0.08 wt%), H2O contents ranging from 2.3 to 6.4 wt%, CO2 contents ranging from 79 to 410 ppm, and enrichment of incompatible elements compared to the late erupted AVT, subsequent Picabo rhyolites, SRP rhyolites, and melt inclusions from other metaluminous rhyolites (e.g., Bishop Tuff, Mesa Falls Tuff). We couple melt inclusion data with Ti measurements and cathodoluminescence (CL) imaging of the host quartz phenocrysts to elucidate the petrogenetic evolution of the AVT rhyolitic magma. We observe complex and multistage CL zoning patterns, the most critical being multiple truncations indicative of several dissolution–reprecipitation episodes with bright CL cores (higher Ti) and occasional bright CL rims (higher Ti). We interpret the high H2O, F, F/Cl, and incompatible trace element concentrations in the context of a model involving melting of Archean crust and mixing of the crustal melt with basaltic differentiates, followed by multiple stages of fractional crystallization, remelting, and melt extraction. This multistage process, which we refer to as distillation, is further supported by the complex CL zoning patterns in quartz. We interpret new Δ18O(Qz-Mt) isotope measurements, demonstrating a 0.4 ‰ or ~180 °C temperature difference, and strong Sr isotopic and chemical differences between the upper and lower AVT to represent two separate eruptions. Similarities between the AVT and the first caldera-forming eruptions of other caldera clusters in the SRP (Yellowstone, Heise and Bruneau Jarbidge) suggest that the more evolved, lower-temperature, more H2O-rich rhyolites of the SRP are important in the initiation of a caldera cluster during the onset of plume impingement.  相似文献   
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