Another sea area separated from the Panthalassic Ocean in the Norian,the Late Triassic: The lowest Sr isotopic composition of the Ishimaki limestone in central Japan     

Kazuhiro Suzuki  Yoshihiro Asahara  Koichi Mimura  Tsuyoshi Tanaka 《Chemie der Erde / Geochemistry》2012,72(1):77-84

Mt. Ishimaki is the Jurassic accretionary complex of the Chichibu Belt in Toyohashi City, near Nagoya in central Japan. The Ishimaki limestone is thought to be seamount-type limestone. The P₁ elements of the conodonts Norigondolella navicula and Ancyrogondolella quadrata found in the limestone indicate it is of Norian age. The Sr isotopic compositions of 45 Ishimaki limestone samples ranged from 0.7055 to 0.7077. Eighteen of these samples had lower Sr isotopic compositions than the lowest Sr isotopic composition (0.7068) of seawater throughout the Phanerozoic. The Sr isotopic compositions in the limestone block are generally lower at the base of the block and higher at the top. The present Sr isotopic compositions of the Ishimaki limestone are unlikely to have been reduced by post-depositional alteration because most of the limestone samples had a low amount of Mn (<300 ppm) or high Sr/Mn ratios (>2) and the conodont elements had low (1–2) CAI (conodont alteration index) values. Additionally, there was little acid-insoluble residue. Thus, the low Sr isotopic compositions are thought to represent the strontium of the past ambient seawater. The low Sr isotopic compositions are in complete disagreement with the generally recognised range of seawater Sr isotopic compositions in the Norian stage of the Late Triassic (0.7075–0.7078) because the depositional environment of the Ishimaki limestone was closed or semi-closed from the Panthalassic Ocean. Therefore, the Sr isotopic composition of the limestone differs from that of the Panthalassic seawater. The low Sr isotopic compositions were probably affected by Sr inflows from mafic oceanic crust by hydrothermal fluid circulation or from hinterlands surrounded by mafic rocks by river water circulation.  相似文献   

Concentration of polychlorinated biphenyls (PCBs) in beached resin pellets: variability among individual particles and regional differences   总被引：1，自引：0，他引：1  

Endo S  Takizawa R  Okuda K  Takada H  Chiba K  Kanehiro H  Ogi H  Yamashita R  Date T 《Marine pollution bulletin》2005,50(10):1103-1114

Concentrations of polychlorinated biphenyls (PCBs) in beached resin pellets were examined to reveal variability between individual particles and differences among beaches. Fifty-five resin pellets from a beach in Tokyo were individually analyzed for PCBs, and showed concentrations ranging from <28 to 2,300 ng/g. This indicates that concentrations are highly variable between particles. Among several characters, discoloration (e.g., yellowing) had a positive relationship with PCB concentration: discolored pellets contained more PCBs than others on most of the beaches sampled. Given the color-selective ingestion of food by some organisms, this may be ecotoxicologically important. Measurements of samples from 47 beaches in Japan showed regional differences in PCB concentrations in resin pellets consistent with those in mussels. Sporadic high concentrations of PCBs were also found in pellets from remote islands, suggesting that resin pellets could be the dominant route of exposure to the contaminants at remote sites. The similarity of PCB concentrations between resin pellets and mussels suggests a potential use of resin pellets to monitor pollution in seawater.  相似文献   

The infrared and ultraviolet absorptions of micro-organisms and their relation to the Hoyle-Wickramashinghe hypothesis     

Shin Yabushita  Kazuhiro Wada 《Astrophysics and Space Science》1985,110(2):405-411

Absorption of yeast andE. coli in the infrared and ultraviolet regions and that of diatomaceous soil in the infrared region have been obtained. Electron microscope photographs of aggregates ofE. coli have also been obtained. These results are discussed in relation to the Hoyle-Wickramasinghe hypothesis regarding the nature of interstellar grains.Department of Nuclear Engineering  相似文献   

The distribution of chiral asymmetry in meteorites: An investigation using asymmetric autocatalytic chiral sensors     

Tsuneomi Kawasaki  Yusuke Fujii  Kenso Soai  Sandra Pizzarello 《Geochimica et cosmochimica acta》2006,70(21):5395-5402

We separated and analyzed several organic and inorganic phases of the carbonaceous chondrite matrix to determine whether they contained any inherent asymmetry. Our intent was to determine any possible foci of asymmetry besides the one determined for meteoritic amino acids. As a probe, we employed a very sensitive asymmetric autocatalytic reaction. We were able to determine that asymmetry still resides in powders after extraction with water and solvents as well as in the insoluble organic material (IOM) obtained after demineralization. Asymmetry is not found any longer in the IOM after hydrothermal treatment and in meteorite powders from which all organics had been removed by O₂ plasma at low temperature. The data are interpreted to indicate a diverse molecular asymmetry residing in yet unknown meteorite organics; these organics might have had an inductive effect on organic molecular evolution upon exogenous delivery to the early Earth.  相似文献   

Thematic Section: Fluids and metamorphism     

Toru Takeshita  Kazuhiro Miyazaki 《Island Arc》2007,16(1):4-5

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Formation of a high-temperature metamorphic complex due to pervasive melt migration in the hot crust   总被引：1，自引：0，他引：1  

Kazuhiro  Miyazaki 《Island Arc》2007,16(1):69-82

Abstract   Detailed reviews of metamorphic thermal structures and spatial distributions of granitic rocks in the high- T Higo metamorphic complex (HMC), central Kyushu, Japan, and Ryoke metamorphic complex in the Yanai district (RMC-Y), southwest Japan, reveal that the high-grade metamorphic rocks were associated with migmatites or syn-metamorphic granitoids. The close association of these rocks suggests that transport and solidification of granitic melts are appreciable heat sources. Partial melting of the pelitic host resists heating of the crust due to its endothermic reaction (i.e. absorption of latent heat). However, the effects of slower thermal evolution produced by partial melting are limited by the boundary conditions assumed for the HMC and RMC-Y. New thermal numerical modeling reveals that the volume fraction of the solidified melt products and the duration of melt migration required for crustal heating to a certain temperature decrease with increasing rates of melt migration. The model predicts that the melt migration rate during formation of the HMC is about three to 10 times higher than that of the RMC-Y, and the corresponding duration of melt migration is about one order of magnitude shorter. The model described here also explains the apparently contradictory observations made in different structural units of the RMC-Y: the metamorphic pressure–temperature ( P-T ) ratio of the southern unit is higher than those of the central and northern units, even though the volume fraction of granitic rocks in the southern unit is larger. The model suggests that the melt migration rate in the northern and central units was faster than that in the southern unit. Overall, the model implies that variations of metamorphic field P-T arrays and the spatial distributions of granitic rocks in high- T metamorphic complexes may be explained simply by variations in the rate and duration of melt migration in the hot crust.  相似文献   

CHIME dating of monazite, xenotime, zircon and polycrase: Protocol, pitfalls and chemical criterion of possibly discordant age data   总被引：7，自引：5，他引：2  

Kazuhiro  Takenori 《Gondwana Research》2008,14(4):569

This paper outlines the CHIME (chemical Th–U-total Pb isochron method) dating method, which is based on precise electron microprobe analyses of Th, U and Pb in Th- and U-bearing accessory minerals such as monazite, xenotime, zircon and polycrase. The age-mapping technique that is applicable to young monazite and zircon is also described. CHIME dating consists of analyzing multiple spots within homogeneous age domains that show sufficient compositional variation, and then these data are used to construct a “pseudo-isochron” from which an age can be obtained via regression. This method, when coupled with discrimination of possibly concordant age data by chemical criteria such as the (Ca + Si)/(Th + U + Pb + S) ratio for monazite and Ca and S contents for zircon, has the potential advantage of significant precision, and the ability to work with minerals that have a significant initial common Pb component. This technique can identify two or more homogeneous domains that are separated by age gaps smaller than the error on individual spot age analysis. Many features that are insignificant in major element analysis can have major impact in the acquisition of trace element data. Critical factors include the roles of collimator slit, detector gas, background estimation, accelerating voltage, probe current, X-ray interferences and count rate in affecting the accuracy, and a way to apply the Th and U interference correction without pure Th- and U-oxides or synthesized pure ThSiO₄. The age-mapping procedure for young monazite and zircon includes acquiring PbMα (or PbMβ) intensity of individual pixels with multiple spectrometers, correcting background with background maps computed from a measured background intensity by the intensity relationships determined in advance of the measurement, calibrating of intensity with standards and calculating of ages from the Th, U and Pb concentrations. This technique provides age maps that show differences in age domains on the order of 20 Ma with in monazite as young as 100 Ma. The effect of sample damage by irradiation of intense and prolonged probe measurement is also described.  相似文献   

In-water algorithms for ADEOS/OCTS     

Motoaki Kishino  Takashi Ishimaru  Ken Furuya  Tomohiko Oishi  Kiyoshi Kawasaki 《Journal of Oceanography》1998,54(5):431-436

In-water algorithms for OCTS standard products were developed using in situ data and installed for operationally processing at NASDA/EOC. This paper describes the in-water algorithms Version 1.0 for chlorophylla concentration, pigment concentration, and attenuation coefficient at a wavelength of 490 nm. The selected OCTS standard algorithms (Ver. 1.0) are as follows:   相似文献   

Modification of North Pacific Intermediate Water around Mixed Water Region     

Ryuichiro Inoue  Jiro Yoshida  Yutaka Hiroe  Kousei Komatsu  Kiyoshi Kawasaki  Ichiro Yasuda 《Journal of Oceanography》2003,59(2):211-224

The mixing processes in the Mixed Water Region (MWR) that lead to changes in the properties of North Pacific Intermediate Water (NPIW) have been studied using observational data sets obtained in May–June 1998. Neutral surfaces, the equation of water mass conversion rate on neutral surfaces and the equation of vertical velocity across neutral surfaces have been used to distinguish dominant processes by assuming the horizontal scale to be the streamer scale (under 100 km). The possibility of double diffusive convection is also discussed in relation to the density ratio. These results may be summarized as follows: (1) the difference between the potential density surface and the neutral surface may rise to −0.04 kg/m³ around the source water of NPIW; (2) horizontal diffusion causes strong modifications of the source water of NPIW; (3) the density range within which strong modification of the source water of NPIW occurs becomes dense from the northern part of MWR near the Oyashio Front to the southern part near the Kuroshio Front, and to the eastern part. Our modeling of these processes shows that cabbeling has effects on the density increment of the source water of NPIW in the northern and southern part of MWR. Double diffusive convection has effects on the density increment of the source water of NPIW, mainly in the northern part of MWR. The possible density increment due to cabbeling in these areas is estimated to be 0.01≈0.03 kg/m³. The possible density increment due to double diffusive convection is 0.01≈0.03 kg/m³. The total density increment due to cabbeling and double diffusive convection amounts to 0.06 kg/m³. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

A new method to detect viable bacteria in natural seawater using 16SrRNA oligonucleotide probe     

Masahiko Nishimura  Kumiko Kita-Tsukamoto  Kazuhiro Kogure  Kouichi Ohwada  Usio Simidu 《Journal of Oceanography》1993,49(1):51-56

Fluorescent oligonucleotide probes were used to detectVibrio cholerae directly under epifluorescence microscope. The probe which is complementary to the specific 16SrRNA sequence ofVibrio cholerae was labelled with Texas-Red, whereas the universal probe was labelled with Fluorescein. These probes allowed the distinctionVibrio cholerae from other eubacteria under the same microscopic field. In order to detect and enumerate specific bacteria in natural seawater, this method was combined with the direct viable count (DVC) technique. The combined method increased intracellular rRNA levels in the sample, and made it possible to detect the target bacteria with the specific gene probe. The applicability of this new method was confirmed both for the laboratory mixed culture system and natural seawater.  相似文献