Isotope Fractionation in TiO2 Polymorphs (Rutile,Anatase, Brookite) Estimated from “First Principles”     

Krylov  D. P.  Kuznetsov  A. B. 《Doklady Earth Sciences》2019,489(1):1294-1296

Doklady Earth Sciences - Temperature relations of β-factors for 18O/16O fractionations in TiO2 polymorphs have been determined using the density functional theory:...  相似文献   

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal     

Jeffrey Poort  Oleg M. Khlystov  Lieven Naudts  Albert D. Duchkov  Hitoshi Shoji  Shin’ya Nishio  Marc De Batist  Akihiro Hachikubo  Masato Kida  Hirotsugu Minami  Andrey Y. Manakov  Marina V. Kulikova  Alexey A. Krylov 《Geo-Marine Letters》2012,32(5-6):407-417

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.  相似文献   

Factors of 18O/16O fractionation in garnets: Evidence from calculations of isotope frequency shifts     

Krylov  D. P.  Glebovitsky  V. A. 《Doklady Earth Sciences》2017,475(1):818-821

Doklady Earth Sciences - Based on the density functional theory (DFT), frequency shifts of garnet end-members upon isotope substitutions (18O/16O, as well as “non-traditional” stable...  相似文献   

Separation between sedimentary and magmatic silicate rocks by discriminant analysis of major element contents     

S. D. Velikoslavinskii  V. A. Glebovitskii  D. P. Krylov 《Doklady Earth Sciences》2013,453(1):1150-1153

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Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal   总被引：4，自引：4，他引：0  

Akihiro Hachikubo  Oleg Khlystov  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Shin’ya Nishio  Masato Kida  Takao Ebinuma  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   

Geochemical and microbiological characteristics of sediments near the Malenky mud volcano (Lake Baikal, Russia), with evidence of Archaea intermediate between the marine anaerobic methanotrophs ANME-2 and ANME-3   总被引：1，自引：1，他引：0  

Tamara I. Zemskaya  Tatiayna V. Pogodaeva  Olga V. Shubenkova  Svetlana M. Сhernitsina  Olga P. Dagurova  Savelii P. Buryukhaev  Bair B. Namsaraev  Oleg M. Khlystov  Aleksandr V. Egorov  Aleksei A. Krylov  Gennadii V. Kalmychkov 《Geo-Marine Letters》2010,30(3-4):411-425

Detailed lithological, biogeochemical and molecular biological analyses of core sediments collected in 2002–2006 from the vicinity of the Malenky mud volcano, Lake Baikal, reveal considerable spatial variations in pore water chemical composition, with total concentrations of dissolved salts varying from 0.1 to 1.8‰. Values of methane δ¹³С in the sediments suggest a biogenic origin (δ¹³С_min. ?61.3‰, δ¹³С_max. ?72.9‰). Rates of sulphate reduction varied from 0.001 to 0.7 nmol cm^?3 day^?1, of autotrophic methanogenesis from 0.01 to 2.98 nmol CH₄ cm^?3 day^?1, and of anaerobic oxidation of methane from 0 to 12.3 nmol cm^?3 day^?1. These results indicate that methanogenic processes dominate in gas hydrate-bearing sediments of Lake Baikal. Based on clone libraries of 16S rRNA genes amplified with Bacteria- and Archaea-specific primers, investigation of microbial diversity in gas hydrate-bearing sediments revealed bacterial 16S rRNA clones classified as Deltaproteobacteria, Gammaproteobacteria, Chloroflexi and OP11. Archaeal clone sequences are related to the Crenarchaeota and Euryarchaeota. Baikal sequences of Archaea form a distinct cluster occupying an intermediate position between the marine groups ANME-2 and ANME-3 of anaerobic methanotrophs.  相似文献   

Quasi-Alfvén oscillations of magnetic surfaces     

Alexander L. Krylov  Alexander E. Lifshitz 《Planetary and Space Science》1984,32(4):481-492

A system of equations has been derived for the modes of free oscillation of the magnetosphere when it is regarded as an adiabatic magnetic dipole trap filled with cold inhomogeneous plasma. The limiting case of infinite longitudinal conductivity corresponding to the assumption that the electric field is orthogonal to the geomagnetic field has been studied. The boundary at the ionosphere is supposed to be perfectly conducting.The eigenmode spectrum has been found to have discrete and continuous components. The eigenmodes of the discrete component correspond to quasi-magnetosonic modes and the eigenmodes of the continuous component to quasi-Alfvén modes.Assuming the magnetosphere to be axisymmetric, a general expression in the form of a Frobenius series has been derived for quasi-Alfvén oscillations of magnetic shells near resonant magnetic surfaces.  相似文献   

Apsidal motion and physical parameters of the eclipsing binary system AR Cas     

A. V. Krylov  L. V. Mossakovskaya  Kh. F. Khaliullin  A. I. Khaliullina 《Astronomy Reports》2003,47(7):551-561

Using the four-channel automatic photoelectric photometer of the Sternberg Astronomical Institute’s Tien Shan Mountain Observatory, we have acquired accurate (σ_obs≈0.004^m) W BV R brightness measurements for the eclipsing binary AR Cas during selected phases before eclipse ingress and after egress, as well as at the center of minima. A joint analysis of these measurements with other published data has enabled us to derive for the first time a self-consistent set of physical and geometrical parameters for the star and the evolutionary age of its components, t=(60±3)×10⁶ years. We have found the period of the apsidal motion (U_obs=1100±160 years, \(\dot \omega _{obs} = 0^\circ .327 \pm 0^\circ .049\) years^?1) and the apsidal parameter of the primary, logk _2,1 ^obs =?2.41±0.08, with the apsidal parameter being in good agreement with current models of stellar evolution. There is an ultraviolet excess in the primary’s radiation, Δ(U?B)=?0.12^m and Δ(B?V)=?0.06^m, possibly due to a metal deficiency in the star’s atmosphere.  相似文献   

Cretaceous Rocks of the Penzhina Bay: Mineralogy,Petrography, and Geodynamic Sedimentation Conditions     

Tuchkova  M. I.  Markevich  P. V.  Krylov  K. A.  Koporulin  V. I.  Grigor'ev  V. N. 《Lithology and Mineral Resources》2003,38(3):197-208

Cretaceous sedimentary and volcanosedimentary rocks from northwestern Kamchatka are considered. The stadial analysis has revealed variable impacts of three major provenances upon the Cretaceous Penzhina sedimentary basin. The provenances were composed of volcanic and volcanosedimentary rocks (Uda–Murgal island arc and Okhotsk–Chukotka volcanic belt) and granitic–metamorphic rocks (the mature Asian continental margin). Sediments were largely accumulated owing to the erosion of island-arc volcanics during reactivation of the Uda–Murgal island arc (Hauterivian–Barremian) or the Okhotsk–Chukotka volcanic belt (middle Albian–Cenomanian). Eroded granitic–metamorphic rocks of the mature Asian continental margin (Berriasian–Valanginian) or Asian metamorphic–volcanic rocks (Santonian–Campanian) were supplied to the basin during tectonically quiet periods (Berriasian–Valanginian and late Cenomanian–Campanian). Compositional changes in provenances were related to active tectonic processes at the continental margin, including evolution and closure of the Uda–Murgal island-arc system and origin of the Okhotsk–Chukotka volcanic belt. The postsedimentary modification of Cretaceous rocks deposited in forearc trough beyond the tectonically active accretionary prism is characterized by a low degree of clastic component alteration.  相似文献   

Reconnaissance paleomagnetism of Late Triassic blocks, Kuyul region, Northern Kamchatka Peninsula, Russia     

William Harbert  Sergei Sokolov  Maxim Alexutin  Kirill Krylov  Vladimir Grigoriev  Alexander Heiphetz   《Tectonophysics》2003,361(3-4):215-227

The northernmost Kamchatka Peninsula is located along the northwestern margin of the Bering Sea and consists of complexly deformed accreted terranes. Progressing inland from the northwestern Bering Sea, the Olyutorskiy, Ukelayat and Koryak superterranes (OLY, UKL and KOR) are crossed. These terranes were accreted to the backstop Okhotsk-Chukotsk volcanic-plutonic belt (OChVB) in northernmost Kamchatka. A sedimentary sequence of Albian to Maastrichtian age overlaps the terranes and units of the Koryak superterrane, and constrains their accretion time. A paleomagnetic study of blocks within the Kuyul (KUY) terrane of the Koryak superterrane was completed at two localities (Camp 2: λ=61.83°N, φ=165.83°E and Camp 3: λ=61.67°N, φ=164.75°E). At both localities, paleomagnetic samples were collected from Late Triassic (225–208 Ma) limestone blocks (2–10 m in outcrop height) within a melange zone. Although weak in remanent magnetization, two components of remanent magnetization were observed during stepwise thermal demagnetization at 32 sites. The A component of magnetization was observed between room temperature and approximately 250 °C. This magnetic component is always of downward directed inclination and shows the best grouping at relatively low degrees of unfolding. Using McFadden–Reid inclination-only statistics and averaging all site means, the resulting A component mean is I_opt=60.3°, I₉₅=5.0° and n=36 (sites). The B magnetic component is observed up to 565 °C, at which temperature, most samples have no measurable remanent magnetization, or growth of magnetic minerals has disrupted the thermal demagnetization process. Combining sites with Fisher estimates of kappa (k-value)≥13 and n (sites)≥3, where bedding orientation differs within a block, most of these sites show the best grouping of B component directions at 100% unfolding, and two of the blocks display remanent magnetizations of both upward and downward directed magnetic inclination. Combining sites with Fisher estimates of kappa (k-value)≥13 and n (sites)≥3, the resulting overall B component paleolatitude and associated uncertainty are λ_obs=30.4°N or S, λ₉₅=8.9° and n=19 (sites). When compared with the expected North America paleolatitude of λ_{APWP expected}=57.9°N, our data support a model in which blocks within the Koryak superterrane are allochthonous and far travelled.  相似文献