The formation of phosphoran olivine and stanfieldite from the pyrometamorphic breakdown of apatite in slags from a prehistoric ritual immolation site (Goldbichl, Igls, Tyrol, Austria)     

Philipp Schneider  Peter Tropper  Reinhard Kaindl 《Mineralogy and Petrology》2013,107(2):327-340

In this study we report P-rich olivine and the tric-calcium phosphate (TCP) stanfieldite in partially molten quartzphyllites from the ritual immolation site at the Goldbichl, near Innsbruck in the Tyrol, Austria. During partial melting, foamy patches of dark glassy material formed at the surface of the rocks and also as layers within the rocks. The pyrometamorphic rocks contain mostly the mineral assemblage olivine + orthopyroxene + plagioclase + spinel + glass. During the investigation of slag samples from this prehistoric ritual immolation site, extremely P-rich, apatite-bearing micro-domains were found. In these domains phosphoran olivine was found whose P contents are approaching the maximum P contents in olivine according to the experimental investigations of Boesenberg and Hewins (Geochim Cosmochim Acta 74:1923–1941, 2010). The textures within these domains indicate strongly disequilibrium conditions. The phosphoran olivines formed due to reactions involving apatite and the mineral assemblage of the quartzphyllites, and coexist with plagioclase and a tri-calcium phosphate phase (TCP) showing stanfieldite Ca₄(Mg, Fe²⁺, Mn²⁺)₅(PO₄)₆ composition. In terms of its chemical composition, olivine shows a wide range in composition with P ranging from 0.3 to 0.54 a.p.f.u, which corresponds to maximal 23 wt.% P₂O₅. These are the highest P-contents in olivine reported from rocks so far. The incorporation of P correlates with decreasing Si contents according to the charge balancing scheme $ 2{{\mathrm{P}}^{5+ }}+□{{\mathrm{M}}_{1,2 }}=2\mathrm{S}{{\mathrm{i}}^{4+ }}+{{\left( {\mathrm{M}\mathrm{g},\mathrm{Fe}} \right)}^{2+ }}{{\mathrm{M}}_{1,2 }} $ . Therefore P can only be incorporated in combination with a vacancy on the M_1,2 position. Micro-Raman spectroscopy of phosphoran olivines indicates that these olivines can easily be identified with this method due to the strong signals of the SiO₄ and PO₄ vibrations. The external vibrations of the M_1,2 sites at low wave-numbers are more complex than for P-free olivine. This might be due to the effect of P⁵⁺ on the M₁ ²⁺ and M₂ ²⁺ positions and the formation of vacancies on these sites. Since micro-Raman investigations of the TCP phase yielded no conclusive match with a known Raman spectrum of a phosphate mineral so far, therefore it is most likely that the TCP phase is stanfieldite, whose Raman spectrum has not been obtained yet. Schematical Schreinemakers analysis in the system CaO-Al₂O₃-FeO-SiO₂-P₂O₅-H₂O shows that P-rich olivine (fayalite-sarcopside solid solution) can form from mineral reactions involving chlorite, apatite and quartz and show that the occurrence of P-rich Fe-olivines spans a large T-range but is restricted to domains with high aSiO₂. The mineral assemblage in the P-rich micro-domains shows that the formation of phosphoran olivine is not only restricted to the interaction between bone material and rocks in slags from ritual immolation sites as suggested by Tropper et al. (Eur J Mineral 16:631–640, 2004) from the immolation site in Oetz but can form locally due to the pyrometamorphic breakdown of a P-rich accessory precursor phase such as apatite.  相似文献   

Parameterization of historical earthquakes in Switzerland   总被引：1，自引：1，他引：0  

Sonia álvarez-Rubio  Philipp K?stli  Donat F?h  Souad Sellami  Domenico Giardini 《Journal of Seismology》2012,16(1):1-24

Macroseismic earthquake parameters of historical events have been reassessed in the framework of the update of the Earthquake Catalogue of Switzerland ECOS-09. The Bakun and Wentworth method (Bakun and Wentworth 1997) has been used to assess location, magnitude, and, when possible, focal depth. We apply a two-step procedure. Intensity attenuation is assessed first by fitting a model with a logarithmic and a linear term, using a set of 111 earthquakes. The magnitude range is 3 and 5.8. Then, intensity to magnitude relation is developed. A subset of the 111 events, all having an instrumental moment magnitude, was used to perform this intensity to magnitude calibration. Five final calibration strategies were developed based on different intensity calibration datasets, regionalized or non-regionalized models, and fixed or variable source depth. The final assessment of the macroseismic earthquake parameters is based on an expert judgment procedure, using the results derived from all five strategies, and taking into consideration the historical knowledge available for the particular earthquake. A bootstrap procedure has been applied to assess the uncertainty of parameters. Indicative lower and upper bounds of uncertainty are derived from distributions of location and magnitude for a number of events, obtained through bootstrap sampling of the intensity field and of the single intensity values. The final uncertainties are given in terms of parameter uncertainty classes already used in previous versions of the earthquake catalogue of Switzerland.  相似文献   

Age modeling of young non-varved lake sediments: methods and limits. Examples from two lakes in Central Chile     

Lucien von Gunten  Martin Grosjean  Jürg Beer  Philipp Grob  Arturo Morales  Roberto Urrutia 《Journal of Paleolimnology》2009,42(3):401-412

High-resolution and highly precise age models for recent lake sediments (last 100–150 years) are essential for quantitative paleoclimate research. These are particularly important for sedimentological and geochemical proxies, where transfer functions cannot be established and calibration must be based upon the relation of sedimentary records to instrumental data. High-precision dating for the calibration period is most critical as it determines directly the quality of the calibration statistics. Here, as an example, we compare radionuclide age models obtained on two high-elevation glacial lakes in the Central Chilean Andes (Laguna Negra: 33°38′S/70°08′W, 2,680 m a.s.l. and Laguna El Ocho: 34°02′S/70°19′W, 3,250 m a.s.l.). We show the different numerical models that produce accurate age-depth chronologies based on ²¹⁰Pb profiles, and we explain how to obtain reduced age-error bars at the bottom part of the profiles, i.e., typically around the end of the 19th century. In order to constrain the age models, we propose a method with five steps: (i) sampling at irregularly-spaced intervals for ²²⁶Ra, ²¹⁰Pb and ¹³⁷Cs depending on the stratigraphy and microfacies, (ii) a systematic comparison of numerical models for the calculation of ²¹⁰Pb-based age models: constant flux constant sedimentation (CFCS), constant initial concentration (CIC), constant rate of supply (CRS) and sediment isotope tomography (SIT), (iii) numerical constraining of the CRS and SIT models with the ¹³⁷Cs chronomarker of AD 1964 and, (iv) step-wise cross-validation with independent diagnostic environmental stratigraphic markers of known age (e.g., volcanic ash layer, historical flood and earthquakes). In both examples, we also use airborne pollutants such as spheroidal carbonaceous particles (reflecting the history of fossil fuel emissions), excess atmospheric Cu deposition (reflecting the production history of a large local Cu mine), and turbidites related to historical earthquakes. Our results show that the SIT model constrained with the ¹³⁷Cs AD 1964 peak performs best over the entire chronological profile (last 100–150 years) and yields the smallest standard deviations for the sediment ages. Such precision is critical for the calibration statistics, and ultimately, for the quality of the quantitative paleoclimate reconstruction. The systematic comparison of CRS and SIT models also helps to validate the robustness of the chronologies in different sections of the profile. Although surprisingly poorly known and under-explored in paleolimnological research, the SIT model has a great potential in paleoclimatological reconstructions based on lake sediments.  相似文献   

Frequency–Magnitude Distribution of −3.7 ≤ M W  ≤ 1 Mining-Induced Earthquakes Around a Mining Front and b Value Invariance with Post-Blast Time     

Makoto Naoi  Masao Nakatani  Shigeki Horiuchi  Yasuo Yabe  Joachim Philipp  Thabang Kgarume  Gilbert Morema  Sifiso Khambule  Thabang Masakale  Luiz Ribeiro  Koji Miyakawa  Atsushi Watanabe  Kenshiro Otsuki  Hirokazu Moriya  Osamu Murakami  Hironori Kawakata  Nana Yoshimitsu  Anthony Ward  Ray Durrheim  Hiroshi Ogasawara 《Pure and Applied Geophysics》2014,171(10):2665-2684

We investigated frequency-magnitude distribution (FMD) of acoustic emissions (AE) occurring near an active mining front in a South African gold mine, using a catalog developed from an AE network, which is capable of detecting AEs down to M _W  ?5. When records of blasts were removed, FMDs of AEs obeyed a Gutenberg?Richter law with similar b values, not depending on post-blasting time from the initial 1-min interval through more than 30 h. This result denies a suggestion in a previous study (Richardson and Jordan Bull Seismol Soc Am, 92:1766–1782, 2002) that new fractures generated by blasting disturb the size distribution of background events, which they interpreted as slip events on existing weak planes. Our AE catalog showed that the GR law with b ～ 1.2 was valid between M _W  ?3.7 and 0 for AEs around the mining front. Further, using the mine’s seismic catalog, which covers a longer time period of the same area, we could extend the validity range of the GR law with the same b value up to M _W 1.  相似文献