Geochemistry of Brines from Salt Ore Deposits in Western Tarim Basin   总被引：2，自引：0，他引：2  

马万栋  马海州  谭红兵  董亚萍  张西营  孙国芳 《中国地球化学学报》2004,23(3):238-244

In the geological evolution of the Tarim Basin, many transgressions and relictions happened. So there have been plentiful sources of salt. Moreover, because of uttermost drought, a lot of salt has been deposited. It is possible to find potash salt in this area. In our fieldwork, we have found salt and brine in western Tarim Basin. Based on a geological survey and the characteristics of sedimentary facies and paleogeography, this paper deals with the geochemical parameters and discusses the possibility of formation of potash salt in terms of the chemical analyses of samples collected from western Tarim Basin. Results of brine analysis lead to some conclusions: most of these salt brines have eluviated from very thick halite beds, mainly chloridetype salt and this kind of halite does not reach the stage of potash deposition in all aspects; WKSL (Wukeshalu) occupies a noticeable place, and we should attach importance to this district because there have been some indicators of the occurrence of potash deposits as viewed from the contents of Br and K. Finally, low Br contents are recognized in the Tarim Basin as a result of salt aggradation, and this point of view has been proved by the results of this experiment and the data available. It cannot depend upon the index of Br to judge the evolution stage of halite. We must look for other facies of potash except marine facies.  相似文献   

Research on Relationship Between Fluorine in Tap Water and That in Urine of Chinese Residents     

王滨滨  郑宝山  翟城  刘小静  安宁 《中国地球化学学报》2004,23(4):373-379

In this study, the relationship between fluorine in drinking water and that in urine of urban residents in China is assessed. Fluorine concentrations in tap water and those in urine show a good correlation with a linear regression coefficient of 0. 9798, indicating that the fluorine concentrations in big cities under investigation are extremely low, and the main source of fluorine is tap water. The weather effect on the intake amount of fluorine is also discussed. When air temperature is above 15℃, people would intake more fluorine through drinking water with the rise of air temperature. When temperature is below 15℃, no remarkable relationship is observed between air temperature and the intake amount of fluorine. This phenomenon indicates that the main source of fluorine in China is tap water instead of foodstuff.  相似文献   

Organic Petrological Studies on Immature Source Rocks     

李贤庆  熊波  钟宁宁  马安来  王铁冠  张爱云 《中国地球化学学报》2004,23(1):15-25

Organic petrology is a marginal science that is quite practicable. At present, it has developed into a routine research tool that is widely applied in petroleum exploration and assessment. Based on several years‘ research of the authors, this paper presents the advances in organic petrological studies on immature source rocks, including the classification and characteristics of macerals, the composition of macerals and types of organic matter, the abundance and evolution of organic matter, oil-prone macerals, hydrocarbon generation and expulsion. All these results show that organic petrology is of considerable value pertaining to its application in the assessment of immature oil and gas. The immature source rocks consist of various macerals with obvious heterogeneity, contain different hydrocarbon-generating macerals with different oil thresholds and oil peaks, and show a two-staged evolutionary pattern of organic matter.  相似文献   

Migration Fractionation of Neutral Nitrogen Compounds of Crude Oils from Tabei Oilfield in the Tarim Basin, China     

张敏  张俊  赵红静  冯敏 《中国地球化学学报》2004,23(1):89-93

The absolute amounts and relative distributions of neutral nitrogen compounds in the Tabei oilfield (e. G. Blocks Ln1-Ln1 1) showed remarkable migration fractionation in the vertical direction. From Ordovician reservoirs (O) to oil legs TⅢ and T Ⅰ of Triassic reservoirs in blocks LN1-LN11, the concentrations of [a] [c] decreased from 1. 59μg/g, 0.49μg/g to 0.17 μg/g (oil). The ratios of various alkylcarbazole isomers, such as 1,8-dimethylcarbazole/nitrogenpartially shielded isomers and 1,8-dimethylcarbazole/nitrogen-exposed isomers, were adopted as the indicators of petroleum migration. The ratios increased from 0.13, 0.20 to 0.67 and from going from the south to the north of the Tabei oilfield, the absolute concentrations of neutral nitrogen compounds decreased drastically, and the nitrogen-shielded isomers were enriched relative to nitrogen-exposed isomers and nitrogen-partially shielded isomers. Crude oils in the Tabei oilfield migrated laterally from the Jilake structure to the Sangtamu fault uplift and Lunnan fault uplift, and crude oils in the same fault uplift migrated and remigrated vertically from Ordovician reservoirs, to oil legs TⅢ to TⅠ of Triassic reservoirs.  相似文献   

Composition of Kerogen in Kupferschiefer from Southwest Poland     

孙玉壮 《中国地球化学学报》2004,23(2):101-111

Thirty-seven Kupferschiefer samples from southwestern Poland were analyzed by microscopy, Rock-Eval approach and instrumental neutron activation analysis to understand the geochemical and morphological characteristics of kerogen present in the samples. The analytical results indicate that there are two different types of kerogens. One type was only subjected to thermal alteration processes, and the other was further oxidized after deposition of the sediment.In the oxidized samples migrabitumen was transformed into pyrobitumen. Rock-Eval analyses show a significant decrease in HI values in the oxidized samples and an increase in OI values in relation to the samples that were not influenced by oxidation. Variations in S2 versus Corg contents indicate a change in kerogen from Type II to Type III with progressing oxidation. The presence of pyrobitumen and the depletion of hydrogen in the altered kerogen allow one to conclude that the kerogen was used as hydrogen donor for thermochemical sulfate reduction(TSR).  相似文献   

Isotopic Characteristics and Key Factors Favoring the Formation of Fuwan Super-large Silver Deposit in Guangdong Province     

梁华英  喻亨祥夏萍王秀璋  程景平 《中国地球化学学报》2004,23(4):293-300

Rb-Sr isochron age of fluid inclusions in quartz from the Fuwan super-large silver deposit is 68 - 6 Ma, the silver deposit is characterized by high μ values (10.67 - 10.95 ), which are much higher than those of the ore-hosted Paleozoic strata and are close to those of ores hosted in the Proterozoic metamorphic basement in western Guangdong Province. Based on the Pb isotopic characteristics, coupled with much high background silver contents (200-1000ng/g) in the Proterozoic basement and relatively low silver contents in the Paleozoic strata in the region of the Sanshui Basin, it is concluded that the ore-forming material of the super-large silver deposit came mainly from the old basement. The super-large silver deposit related genetically to the intense volcanic activities during the Upper Cretaceous to Eogene. The formation of the Fuwan super-large silver deposit is controlled by the following favorable geological conditions : ( 1 ) The intersection of deep faults and contemporaneous faults at the margin of the Sanshui Basin led to the formation of an excellent structure as passageway for ore fluids; (2) The special ore-hosted rock association forms a ore gathering-trap structure that favors the precipitation of ore; (3) The silver-rich old basement, multi-stage mineralization and multi-episode volcanic activities which constitute a geothermal convection system.  相似文献   

Biomarkers in the Molar Tooth （MT）-Bearing Limestones in the Jilin-Liaoning Area of China   总被引：2，自引：1，他引：2  

旷红伟  李艳霞  曾艳涛  孟祥化  葛铭 《中国地球化学学报》2004,23(4):334-341

The origin of Molar Tooth (MT) carbonates has been argued for more than 100 years, which are a kind of Proterozoic carbonates especially composed of microsparite with ptygmatically folded and sheet-like structures. Biomarkers detected in the microcalcsparite from the Wanlong and Xingmincun formations in the Jilin-Liaoning area showed there are abundant normal alkanes, isoprenoids, hopanes, steranes, alkylmethylcyclohexanes, and alkyleyclohexanes, indicating a diversity of biological source: long-chain isoprenoids, the major components of chlorophyll, such as C19, C20, a kind of major biomarkers synthesized early by isoprenoid monomers; hopanes a type of characteristic biomarkers from prokaryote, such as archaebacteria and cyanobacteria; sterane a biomarker for eukaryote; and two kinds of alkanes with C17, C18 as the main peaks representing aquatic bacteria and with C23, C24 as the main peaks representing fungi, respectively. Biomarker analysis showed that MT is the result of bacterial and algal activities, which is a kind of organisms between aerobic and anaerobic bacteria, reproducing well in normal or slightly saline sea water under weak oxidation-reduction conditions, resulting in rapid deposition of calcite as microsparite clue to some mechanisms.  相似文献   

A Least-squares Approach to Depth Determination from Numerical Horizontal Self-potential Gradients     

E. M. Abdelrahman  H. S. Saber  K. S. Essa  M. A. Fouda 《Pure and Applied Geophysics》2004,161(2):399-411

We have developed a least-squares minimization approach to depth determination of a buried ore deposit from numerical horizontal gradients obtained from self-potential (SP) data using filters of successive window lengths (graticule spacings). The problem of depth determination from SP gradients has been transformed into the problem of finding a solution to a nonlinear equation of the form f(z)=0. Formulas have been derived for vertical and horizontal cylinders and spheres. Procedures are also formulated to estimate the electrical dipole moment and the polarization angle. The method is applied to synthetic data with and without random noise. Finally, the validity of the method is tested on two field examples. In both cases, the depth obtained is found to be in a very good agreement with that obtained from drilling information.  相似文献   

Space-time mapping of soil salinity using probabilistic bayesian maximum entropy     

A. Douaik  M. van Meirvenne  T. Tóth  M. Serre 《Stochastic Environmental Research and Risk Assessment (SERRA)》2004,18(4):219-227

The mapping of saline soils is the first task before any reclamation effort. Reclamation is based on the knowledge of soil salinity in space and how it evolves with time. Soil salinity is traditionally determined by soil sampling and laboratory analysis. Recently, it became possible to complement these hard data with soft secondary data made available using field sensors like electrode probes. In this study, we had two data sets. The first includes measurements of field salinity (EC_a) at 413 locations and 19 time instants. The second, which is a subset of the first (13 to 20 locations), contains, in addition to EC_a, salinity determined in the laboratory (EC_2.5). Based on a procedure of cross-validation, we compared the prediction performance in the space-time domain of 3 methods: kriging using either only hard data (HK) or hard and mid interval soft data (HMIK), and Bayesian maximum entropy (BME) using probabilistic soft data. We found that BME was less biased, more accurate and giving estimates, which were better correlated with the observed values than the two kriging techniques. In addition, BME allowed one to delineate with better detail saline from non-saline areas.  相似文献   

Microseismicity and active deformation of Messinia,SW Greece     

J. Papoulia  J. Makris 《Journal of Seismology》2004,8(4):439-451

By deploying a 30 3-component digital seismic array in the Messiniakos gulf and the surrounding region, we recorded for a period of 45 days the microseismic activity. With a minimum of six records per event, we located 1121 earthquakes corresponding to an average of 20 events per day. For the hypocenter location we used a local velocity model adopted to two controlled source seismic experiments. Within the array, traveltime residuals were within ± 0.2 s and the epicentral accuracy in the order of ± 2 km, while the hypocentral one is twice this value. Correlation of the seismicity with the tectonic elements indicated that most of the NW-SE oriented faults are active with strike-slip movement along this orientation and extension perpendicular to it. The neogene basins of Messini, Meligalas and Megalopolis are seismically very active and their eastern flanks are delineated by higher seismic activity than their western ones. This indicates that the basins are asymmetric with master faults defining their eastern-northeastern flanks. This hypothesis is supported by the asymmetric structure mapped at the offshore Messiniakos basin as densely spaced high resolution reflection seismic profiles have revealed. The western margins of the basins are less deformed and the seismic activity is dispersed over several minor NW-SE faults. Since the NW-SE striking faults onshore are truncated by major NE-SW oriented ones, their overall length is shortened, reducing their seismic potential and capacity to store large stresses that could produce events above Ms6.1. Offshore western Messinia, in the Ionian Sea, the size and activity of the faults is significantly larger and prone to develop events of larger magnitudes. Subcrustal seismicity indicates a deepening of the foci to the east-northeast.Part of this work was presented at the CIESM Conference, Monaco, 2001, and in the EGS General Assembly, Nice, 2001.  相似文献