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291.
Developing useful biological isoscapes for areas of the world is a priority. This is the case for Mexico that hosts a large percentage of North America's Neotropical migrant birds. Here we investigated the use of House Sparrow (Passer domesticus) feathers to create a spatially explicit feather deuterium isoscape for that country using samples (n = 461) that were collected across Mexico. Considerable and useful spatial hydrogen isotopic structure was observed, suggesting that isotopes may be a potential forensic tool for evaluating origins of Mexican derived fauna and flora. The most positive feather δD values occurred in the northeast and most negative in the south-central part of the country, roughly matching δD patterns observed in groundwater. A weak negative isotopic relationship was found with altitude in both the Pacific and Atlantic drainage systems. The most parsimonious model describing isotopic spatial variation in feathers between 300 and 3000 m a.s.l. included groundwater δDDgw; precipitation proxy), sex, amount of precipitation, and the coefficient of variation in amount of precipitation. Overall, δDgw was a poor predictor of sparrow δDf values for all of Mexico. However, this relationship was considerably strengthened when we considered sex separately, removed the Baja peninsula from our sample, and considered the Atlantic and Pacific drainage basins separately. The strongest relationship between δDgw and δDf was found for female sparrows in the Atlantic drainage basin (r2 = 0.464). We recommend that researchers interested in inferring origins of migratory birds and other animals in Mexico create species specific isotopic basemaps that may be guided by the isotopic patterns we have observed for House Sparrows and groundwater.  相似文献   
292.
Numerous studies have shown that precipitation isocapes drive δD and δ18O patterns in surficial waters and in terrestrial food webs. While the GNIP (Global Network for Isotopes in Precipitation) dataset provided a key foundation for linking precipitation-terrestrial isoscapes globally, it has insufficient spatial coverage in many countries like Mexico. To overcome this limitation, we hypothesized that shallow phreatic groundwaters in Mexico could be used as an isotopic integrator of long-term seasonally weighted precipitation inputs to the landscape to aid in calibrating spatial H and O isotope datasets for terrestrial, biological and hydrological research. Groundwater was sampled from 234 sites in Mexico at ~ 50 km latitudinal spacing to obtain high spatial resolution and country-wide coverage for the construction of a groundwater isoscape. Our data revealed that shallow groundwater infiltration in Mexico appears largely unaffected by evaporation and reflects seasonally weighted precipitation inputs. These precipitation inputs are primarily biased to summertime when highest rainfall occurs, but a small degree of post-precipitation evaporation revealed a lower d-excess zone that corresponded to the interior semi-arid ecozone. We developed a predictive general linear model (GLM) for hydrogen and oxygen isotopic spatial patterns in Mexican groundwater and then compared the results to a validation subset of our field data, as well external data reported in the literature. The GLM used elevation, latitude, drainage basin (Atlantic vs. Pacific), and rainfall as the most relevant predictive variables. The GLM explained 81% of the overall isotopic variance observed in groundwater, 68% of the variance within our validation subset, and 77% of the variance in the external data set. Our predictive GLM is sufficiently accurate to allow for future ecological, hydrological and forensic isoscape applications in Mexico, and may be an approach that is applicable to other countries and regions where GNIP stations are lacking.  相似文献   
293.
Abstract– On the basis of morphological and petrographic characteristics, eight “giant” unmelted micrometeorites in the 300–1100 μm size range were selected from the Transantarctic Mountain micrometeorite collection, Victoria Land, Antarctica. Mineralogical and geochemical data obtained by means of scanning electron microscopy, electron probe microanalyses, and synchrotron X‐ray diffraction allow their classification as chondritic micrometeorites. The large size of the micrometeorites increases considerably the amount of mineralogical and geochemical information compared to micrometeorites in smaller size fractions, therefore allowing a better definition of their parent material. A large variety of material is observed: five micrometeorites are related to unequilibrated and equilibrated ordinary chondrite, one to CV chondrite, one to CM chondrite, and one to CI chondrite parent materials. Besides reporting the first occurrence of a CV‐like micrometeorite, our study shows that the abundance of chondritic material supports observations from recent studies on cosmic spherules that a large part of the micrometeorite flux in this size range is of asteroidal origin.  相似文献   
294.
The hydrogeomorphology of the Vietnamese Mekong Delta (VMD) has been significantly altered by natural and anthropogenic drivers. In this study, the spatiotemporal changes of the flow regime were examined by analysing the long-term daily, monthly, annual and extreme discharges and water levels from 1980 to 2018, supported by further investigation of the long-term annual sediment load (from the 1960s to 2015), river bathymetric data (in 1998, 2014 and 2017) and daily salinity concentration (from the 1990s to 2015) using various statistical methods and a coupled numerical model. Then, the effects of riverbed incision on the hydrology were investigated. The results show that the dry season discharge (i.e., in March–June) of the Tien River increased by up to 23% from the predam period (1980–1992) to the postdam period (1993–2018) but that the dry season water level at My Thuan decreased by up to −46%. The annual mean and monthly water levels in June at Tan Chau and in January and June–October at My Thuan in the Tien River decreased statistically, even though the respective discharges increased significantly. These decreased water levels instead of the increased discharges were attributed to the accelerated riverbed incision upstream from My Thuan, which increased by more than three times, from a mean rate of −0.16 m/year (−16.7 Mm3/year) in 1998–2014 to −0.5 m/year (−52.5 Mm3/year) in 2014–2017. This accelerated riverbed incision was likely caused by the reduction in the sediment load of the VMD (from 166.7 Mt/year in the predam period to 57.6 Mt/year in the postdam period) and increase in sand mining (from 3.9 Mm3 in 2012 to 13.43 Mm3 in 2018). Collectively, the decreased dry season water level in the Tien River is likely one of the main causes of the enhanced salinity intrusion.  相似文献   
295.
We present a high-resolution dark matter reconstruction of the   z = 0.165  Abell 901/902 supercluster from a weak lensing analysis of the Hubble Space Telescope STAGES survey. We detect the four main structures of the supercluster at high significance, resolving substructure within and between the clusters. We find that the distribution of dark matter is well traced by the cluster galaxies, with the brightest cluster galaxies marking out the strongest peaks in the dark matter distribution. We also find a significant extension of the dark matter distribution of Abell 901a in the direction of an infalling X-ray group Abell 901α. We present mass, mass-to-light and mass-to-stellar mass ratio measurements of the structures and substructures that we detect. We find no evidence for variation of the mass-to-light and mass-to-stellar mass ratio between the different clusters. We compare our space-based lensing analysis with an earlier ground-based lensing analysis of the supercluster to demonstrate the importance of space-based imaging for future weak lensing dark matter 'observations'.  相似文献   
296.
Initiated by the need to quantify erosion rates and the impacts of global changes on erosion, several attempts have been made to apply erosion models at regional scales. However, these models have often been directed towards on-site soil erosion estimates, emphasising sheet and rill erosion processes, and disregarding gully erosion, channel erosion and sediment transport. These models are therefore of limited use for the assessment of sediment yield, off-site impacts of erosion, and for the development of environmental management to control these impacts at regional scale. This study analyses and compares three spatially distributed models for the prediction of soil erosion and/or sediment yield at regional scales: the WATEM-SEDEM model that is based on the empirical Revised Universal Soil Loss Equation (RUSLE) in combination with a sediment transport equation, the physics-based Pan European Soil Erosion Risk Assessment model (PESERA), and a newly developed Spatially Distributed Scoring model (SPADS). The three models were applied to 61 Spanish drainage basins and model predictions were evaluated against data on measured reservoir sedimentation rates. Global data sets on land use, climate, elevation and soil characteristics were used as model input for WATEM-SEDEM and SPADS, whereas published soil erosion estimates of PESERA at 1 km2 resolution were used directly. SPADS and WATEM-SEDEM provided best results after separate calibration for basins with a Sediment Delivery Ratio (SDR) higher than 5% and those with an SDR lower than 5%. In this way, SPADS explained 67% of variation in sediment yield, while WATEM-SEDEM explained 48% of the variation. PESERA represents a promising alternative to the use of empirical models at the regional scale as it can be applied to very diverse environments with little calibration. However, PESERA provides soil erosion rates and not sediment yield estimates. For most basins PESERA soil erosion rates vary between fifty and close to zero percent of total sediment yield. Two major factors may explain this discrepancy between modelled soil erosion rates and measured sediment yield. First, it may be that PESERA underestimates soil erosion under Mediterranean conditions, although PESERA soil erosion rates are of the same order of magnitude as erosion rates measured in erosion plot studies. Second, gully-, river channel erosion and sediment transport processes may be much more important than sheet- and rill erosion for regional scale sediment yield in these environments. These issues therefore require further attention in future model development. Although spatially lumped models provide better predictions of sediment yield at the basin scale, and while validation of the predicted spatial patterns of sources and sinks of sediment requires further research, spatially distributed models are expected to be of value to support management decisions regarding the assessment of on-site and off-site impacts of erosion at the regional scale.  相似文献   
297.
Europa, the smallest of the Galilean satellites, has a young icy surface and most likely contains an internal ocean. The primary objective of possible future missions to Europa is the unambiguous detection and characterization of a subsurface ocean. The thickness of the overlying icy shell provides important information on the thermal evolution of the satellite and on the interaction between the ocean and the surface, the latter being fundamental for astrobiology. However, the thickness is not well known, and estimates range from several hundred of meters to some ten of kilometers. Here, we investigate the use of libration (rotation variation) observations to study the interior structure of Europa and in particular its icy shell. A dynamical libration model is developed, which includes gravitational coupling between the icy shell and the heavy solid interior. The amplitude of the main libration signal at 3.55 days (the orbital period) is shown to depend on Europa's shape and structure. Models of the interior structure of Europa are constructed and the equatorial flattening of the internal layers, which are key parameters for the libration, are calculated by assuming that Europa is in hydrostatic equilibrium. Europa's flattened shape is assumed to be due to rotation and permanent tides, and we extend the classical Radau equation for rotationally flattened bodies to include also tidal deformation. We show that the presence of an ocean increases the amplitude of libration by about 10%, depending mainly on the thickness of the icy shell. Therefore, libration observations offer possibility of detection of a subsurface ocean in Europa and estimation of the thickness of its overlying icy shell.  相似文献   
298.
We present the first spectra of Neptune taken with the Spitzer Space Telescope, highlighting the high-sensitivity, moderate-resolution 10-20 μm (500-1000 cm−1) spectra. We report the discovery of methylacetylene (CH3C2H) and diacetylene (C4H2) with derived 0.1-mbar volume mixing ratios of (1.2±0.1)×10−10 and (3±1)×10−12 respectively.  相似文献   
299.
Interplay of S and As in Mekong Delta sediments during redox oscillations   总被引:1,自引:1,他引:0  
The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam).  相似文献   
300.
Hans Van de Vyver 《水文研究》2018,32(11):1635-1647
Rainfall intensity–duration–frequency (IDF) curves are a standard tool in urban water resources engineering and management. They express how return levels of extreme rainfall intensity vary with duration. The simple scaling property of extreme rainfall intensity, with respect to duration, determines the form of IDF relationships. It is supposed that the annual maximum intensity follows the generalized extreme value (GEV) distribution. As well known, for simple scaling processes, the location parameter and scale parameter of the GEV distribution obey a power law with the same exponent. Although, the simple scaling hypothesis is commonly used as a suitable working assumption, the multiscaling approach provides a more general framework. We present a new IDF relationship that has been formulated on the basis of the multiscaling property. It turns out that the GEV parameters (location and scale) have a different scaling exponent. Next, we apply a Bayesian framework to estimate the multiscaling GEV model and to choose the most appropriate model. It is shown that the model performance increases when using the multiscaling approach. The new model for IDF curves reproduces the data very well and has a reasonable degree of complexity without overfitting on the data.  相似文献   
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