Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

南黄海及相邻陆区松散沉积层磁性地层的研究     

周墨清  葛宗诗 《海洋地质与第四纪地质》1990,(4)

本文通过研究区5个钻孔松散沉积岩心磁性地层的划分对比,获知布容与松山极性带的界线,南黄海和陆区北部位于80.0—99.5m。陆区的南部此界线于270.4m深处。松山和高斯极性带的界线,海区未揭露到,其沉积起始时间都小于1.7Ma。而陆区的南、北部分别位于117m和328.2m。高斯和吉尔伯特极性带的界线,陆区北部为140m,而南部区为460.15m。沉积起始时间为3.4Ma。吉尔伯特底界仅北部陆区所揭示,为190.5m。松散沉积层与下伏白垩纪(?)石灰岩接触面位于400.35m,沉积起始时间约17.0Ma。  相似文献   

常压法合成Methomyl的研究     

钱佐国  孙明昆  杨福顺  孙林枫  周曾昊 《中国海洋大学学报(自然科学版)》1990,(3)

提出一种合成Methomyl的改良法。该方法的特点是反应可在常压下进行。对常压反应的优宜条件作了系统研究,并讨论了反应机理。  相似文献   

东海XH凹陷烃资源预测──勘探层分析及石油资源专家系统分析     

肖国林  周才凡  李桂群 《中国海洋大学学报(自然科学版)》1995,(3)

应用勘探层分析及石油资源专家系统对ＸＨ凹陷下第三系勘探目的层的三个勘探层烃资源量作出了综合预测，结果表明，凹陷内各勘探层，尤其是渐新统勘探层，烃资源量相当可观。提出在渐新统内的地层圈闭中可进一步作详细的勘探工作。  相似文献   

PLS-ANN分析血浆自体荧光光谱的二阶导数光谱识别胃癌   总被引：1，自引：0，他引：1  

马君  朱玉平  毛伟征  李颖  史晓凤  郑荣儿  孟继武 《中国海洋大学学报(自然科学版)》2006,36(3):505-508

探讨偏最小二乘法结合神经网络法(简称PLS-ANN)分析血浆自体荧光光谱的二阶导数光谱识别胃癌的优势,对20例胃癌病人和23例健康人血浆进行以405nm为激发光的自体荧光光谱检测,采用PLS-ANN法分别对血浆自体荧光光谱和二阶导数光谱进行判别分析。PLS-ANN分析血浆的自体荧光光谱法诊断胃癌的灵敏度为75%,特异度为83%,准确率为79%,PLS-ANN分析血浆的二阶导数光谱法诊断胃癌的灵敏度为90%,特异度为96%,准确率为93%。结果表明PLS-ANN分析血浆的二阶导数光谱法识别胃癌,优于PLS-ANN分析血浆的自体荧光光谱法,有望成为快速识别胃癌的较理想方法。  相似文献   

六溴苯的合成研究     

钱佐国  孙明昆  苗世昌  刘新河  周曾昊 《中国海洋大学学报(自然科学版)》1991,(2)

对直接溴化法合成六溴苯作了系统的研究,并对文献方法进行了一系列的改进。包括选择适当的摧化剂及其用量,使反应基本上在室温下进行;利用水汽蒸馏法驱除残余溴,可直接得到无色或近乎无色的纯净产物,而勿需进行还原脱溴,且得率较高。提出一种以溴化物形式回收副产物的方法。  相似文献   

Effect of shallow and narrow water on added mass of cylinders with various cross-sectional shapes     

Z.X. Zhou  Edmond Y.M. Lo  S.K. Tan 《Ocean Engineering》2005,32(10):1199-1215

The sway, heave and roll added masses of three uniform cylinders with semi-circular, rectangular and triangular cross-sectional shapes in shallow and narrow water are numerically analysed. The method is based on simulation of the potential flow induced by the cylinder's mode of motion. The effects of shallow and narrow water on added mass are analysed and presented. It is concluded that the shallow and narrow water effects on added mass depend on the different cross-section shapes of the cylinders. In particular, the water depth effect on sway added mass is stronger than that on heave added mass while the narrow water effect on sway is weaker than that on heave. The shallow water effect on added mass tends to weaken the narrow water effect. Lastly the effect of shallow and narrow water on added mass on a rectangular cylinder is the strongest while that on a triangular cylinder is the weakest.  相似文献   

自由生活海洋线虫的系统分类学   总被引：1，自引：0，他引：1  

张志南  周红 《中国海洋大学学报(自然科学版)》2003,33(6):891-900

自由生活海洋线虫是海洋中最丰富的后生动物 ,它属于小型底栖动物的永久性成员 ,即分选时 ,可通过 0 .5 mm或 1 mm网筛但被 0 .0 31 mm或 0 .0 4 2 mm孔径网筛蓄留的动物 ,本文讨论线虫在动物界的分类地位 ,与相近动物类群的亲缘关系 ,泄腺纲与泄管纲分类系统的由来和演变。海洋线虫属于泄腺纲 ,由 Bremerhaven种名录和 L orenzen确立的分类系统已得到广泛的应用。海洋线虫的分类系统仍处在发展和完善中 ,需要发现更多更有价值的共近裔性状用于物种水平和较高分类阶元的分析和鉴定  相似文献   

等鞭金藻8701培养液的营养组成研究   总被引：4，自引：0，他引：4  

周汝伦  孙爱淑 《海洋湖沼通报》1994,(1):17-24

等鞭金藻８７０１品系是作用（周，孙）新分离的一个单细饵料藻种。其形态构造与绿光等鞭金藻相同，便适温远较后者为低。通过单因子和正交试验表明，培养液的最佳配方是在天然海水中加入ＮａＮＯ３３０ｐｐｍ，ＣＯ（ＨＮ２）２１５ｐｐｍ，ＫＨ２ＰＯ４或ＮａＨ２ＰＯ４－８ｐｐｍ，ＦｅＣ６Ｈ５Ｏ７０．５ｐｐｍ，维生素Ｂ１０．１ｐｐｍ和维生素Ｂ１２０．０００５ｐｐｍ。  相似文献   

两种涡鞭毛藻的周日垂直迁移特性研究   总被引：3，自引：3，他引：3  

周名江  M. Elbrachter 《海洋与湖沼》1994,25(2):173-178

Ａｌｅｘａｎｄｒｉｕｍ ｌｕｓｉｔａｎｉｃｕｍ于１９８７年采自葡萄牙沿海，Ｙ－１００于１９８９年采自德国湾。在暗室中用一根柱长１５０ｃｍ，内径３．４ｃｍ的玻璃柱对两种涡鞭毛藻的垂直行特性进行研究。结果表明，两种藻均进行有规律的周日垂直迁移，且均在始前２ｈ开始向上迁移，光照结束前３ｈ开始向移速度约为２８０μｍ／ｓ，向下约为１４０μｍ／ｓ向下约为８５０μｍ／ｓ；Ｙ－１００向上迁移速度约为２８０μｍ／ｓ  相似文献