Reply to Discussion on "Giant versus small porphyry copper deposits of Cenozoic age in northern Chile: adakitic versus normal calc-alkaline magmatism" by Oyarzun R,Márquez A,Lillo J,López I,Rivera S (Mineralium Deposita 36:794–798, 2001)     

Roberto Oyarzun  Alvaro Márquez  Javier Lillo  Ivan López  Sergio Rivera 《Mineralium Deposita》2002,37(8):795-799

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Coupled evolution of back-arc and island arc-like mafic crust in the late-Neoproterozoic Agardagh Tes-Chem ophiolite, Central Asia: evidence from trace element and Sr–Nd–Pb isotope data   总被引：3，自引：0，他引：3  

Jörg A. Pfänder  Klaus Jochum  Ivan Kozakov  Alfred Kröner  Wolfgang Todt 《Contributions to Mineralogy and Petrology》2002,143(2):154-174

. We report major-element, trace-element and isotopic data of volcanic rocks from the late-Neoproterozoic (570 Ma) Agardagh Tes-Chem ophiolite in Central Asia, south-west of Lake Baikal (50.5°N, 95°E). The majority of samples are high-alumina basalts and basaltic andesites having island-arc affinities. They were derived from an evolved parental magma (Mg#̾.60, Cr~180 ppm, Ni~95 ppm) by predominantly clinopyroxene fractionation. The parental magma developed from a primary mantle melt by fractionation of about 12% of an olivine+spinel assemblage. The island-arc rocks have high abundances of incompatible trace elements (light rare-earth element abundances up to 100 times chondritic, chondrite-normalised (La/Yb)_n=14.6-5.1) and negative Nb anomalies (Nb/La=0.37-0.62), but low Zr/Nb ratios (7-14). Initial )_Nd values are around +5.5, initial Pb isotopic compositions are ²⁰⁶Pb/²⁰⁴Pb=17.39-18.45, ²⁰⁷Pb/²⁰⁴Pb=15.49-15.61, ²⁰⁸Pb/²⁰⁴Pb=37.06-38.05. Enrichment of large-ion lithophile elements within this group is significant (Ba/La=11-130). Another group of samples consists of back-arc basin-related volcanic rocks. They are most likely derived from the same depleted mantle source as the island-arc rocks, but underwent higher degrees of melting (8-15%) and are not influenced by slab components. They have lower abundances of incompatible trace elements, flat rare-earth element patterns [(La/Yb)_n=0.6-2.4] and higher )_Nd values (+7.8 to +8.5). Negative Nb anomalies are absent (Nb/La=0.81-1.30), but Zr/Nb is high (21-48). At least three components are necessary to explain the geochemical evolution of the volcanic rocks: (1) an enriched (ocean island-like) component characterised by a high Nb concentration (up to 30 ppm), an absent negative Nb anomaly, a low Zr/Nb ratio (~6.5), a low )_Nd value (around 0), and radiogenic ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb; (2) a back-arc basin component similar to N-MORB with a flat rare-earth element pattern and a high )_Nd value (around +8.5); and (3) an island-arc component from a mantle source which was modified by the downgoing slab. Crystal fractionation superimposed on mixing and source contamination by subducted sediments is suitable to explain the observed geochemical data. The most likely geodynamic environment to produce these characteristics is a young, intra-oceanic island-arc system and an associated back-arc basin.  相似文献   

Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS     

Michael A.W. Marks  Roberta L. Rudnick  Thomas Ludwig  Horst Marschall  Thomas Zack  Ralf Halama  William F. McDonough  Detlef Rost  Thomas Wenzel  Edward P. Vicenzi  Ivan P. Savov  Rainer Altherr  Gregor Markl 《Geostandards and Geoanalytical Research》2008,32(3):295-310

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.  相似文献   

On the role of diffractions in velocity model building: a full-waveform inversion example     

Dell  Sergius  Abakumov  Ivan  Znak  Pavel  Gajewski  Dirk  Kashtan  Boris  Ponomarenko  Andrey 《Studia Geophysica et Geodaetica》2019,63(4):538-553

Studia Geophysica et Geodaetica - Imaging of small-scale heterogeneities is important for the geological exploration in complex environments. It requires a processing sequence tuned to...  相似文献   

How fast does tufa grow? Very high-resolution measurement of the tufa growth rate on artificial substrates by the development of a contactless image-based modelling device     

Ivan Marić  Ante Šiljeg  Neven Cukrov  Vlatko Roland  Fran Domazetović 《地球表面变化过程与地形》2020,45(10):2331-2349

Accurate determination of the tufa growth rate (TGR) is required to answer the fundamental geomorphological question of tufa evolution. The TGR has been measured by various direct and indirect methods. One of the most popular direct methods uses modified micro-erosion meter (MEM), which has several drawbacks. Here, we present for the first time a coordinate measuring macro-photogrammetry device (CMD) for monitoring the TGR in a contactless manner. The CMD was applied on 28 limestone plates at 14 locations within the Skradinski buk area, Croatia, and measurements were performed in the laboratory. The TGR was derived from digital tufa high-resolution models (DTHRMs). The accuracy of the device was evaluated using state-of-the-art three-dimensional (3D) scanners and error calculation at checkpoints. Moreover, the precision was evaluated with the split test (n = 5). A total of 74 DTHRMs with a spatial resolution of 0.0236 mm were created. The TGR ranged from 0.327 to 19.302 mm a⁻¹, with an average of 5.771 mm a⁻¹. A higher TGR was observed on the limestone plates near mosses, located in fast and turbulent water rather than in stagnant water. We found that specific micro-environmental factors (e.g. proximity to moss) positively affected tufa growth. Erosion events were observed, as well as the presence of aquatic insect larvae (Simuliidae and Chironomidae), which positively affected tufa growth. The CMD is a precise and accurate device that does not suffer from the drawbacks of the MEM method and has many other advantages. It has a high capability of tufa erosion detection, enables the identification of macroinvertebrates, and multispectral or hyperspectral cameras can be mounted on the device for spectral reflectance analysis of the tufa surface. The CMD can be applied in any study requiring a sub-millimetre data quality and involving the comparison of consecutive 3D models and derivation of various parameters of smaller objects. © 2020 John Wiley & Sons, Ltd.  相似文献   

Structure and tectonic evolution of the Pirin-Pangaion Structural Zone (Rhodope Massif,southern Bulgaria and northern Greece)     

Ivan S. Zagor ev 《Geological Journal》1994,29(3):241-268

The Pirin-Pangaion Structural Zone occupies the south-western part of the Rhodope Massif. It consists of Proterozoic amphibolite facies metamorphic rocks of the Rhodopian Supergroup, and granitoids of Hercynian, Late Cretaceous and Palaeogene age. The pre-Hercynian structure of the zone is dominated by an interference pattern of three superimposed fold generations of NE-SW and NW-SE trends. These structures are cut by Hercynian granitoids, and the entire complex is affected by late Hercynian or early Alpine conical folds. The zone was overthrusted by the Ogražden and Kroussia Units (Serbo-Macedonian ‘Massif’) along the north-east vergent Mid-Cretaceous Strimon overthrust, and by the Central Rhodope Zone of the Rhodope Massif, along the south-west vergent Meso-Rhodopean Overthrust. With this thrusting event, the Pirin-Pangaion Structural Zone was brought together with the Serbo-Macedonian ‘Massif’ and the Central Rhodope Zone to form the Late Cretaceous Morava-Rhodope Zone, which acted as a ‘plateau’ along the southern edge of the Eurasian plate. Late Cretaceous granitoid magma of crustal origin intruded this zone, whereas north of it the Srednogorie volcanic island arc was the site of igneous activity with magmas originating in the upper mantle. The West Thrace Zone developed as a Palaeocene to Oligocene depression superimposed over the older basement obliquely to the southern periphery of the Rhodope Massif. In the Late Eocene and Early Oligocene, this depression represented a volcanic island arc with mantle-derived basic to intermediate magmas; contemporaneous granitoid magmas formed through crustal melting in the thickened crust of the Rhodope Massif (Pirin and Pangaion Units included). Early Miocene thrusting was most intense in the Pangaion Unit, and was followed by Late Miocene to Quaternary extension.  相似文献   

Correction to: Zeolite containing rocks of kudurs and reasons of geophagy within the territory of Sikhote-Alin Nature Zapovednik,Far East of Russia     

Panichev  Aleksander  Seryodkin  Ivan  Popov  Vladimir  Chekryzhov  Igor  Makarevich  Raisa  Lutsenko  Tatiana  Stolyarova  Tatiana  Sergievich  Aleksander  Khoroshikh  Pavel  Maksimova  Darya  Petrunenko  Yury 《Arabian Journal of Geosciences》2020,13(4):1-11

This paper establishes a mechanical model of the stress distribution in front of the driving face during coal roadway excavation. Theoretical research shows that the stress state in the plastic zone of the driving face is consistent with the limit equilibrium equation, and the elastic zone is in accordance with the equilibrium equation based on elasticity mechanics. Based on this improved mechanical state solution model, different coal material constitutive hypotheses are used for the analysis. The width of the plastic zone calculated under the brittle-perfectly elastic model can reach 2–5 times the height of the roadway, and the stress concentration coefficient can reach two or more times. 3DEC numerical simulation software was used to simulate the stress distribution of the heading face. The results of the simulation are similar to those of the theoretical analysis. Compared with the elastic-perfectly plastic model, the calculated results of the brittle-perfectly elastic model are more consistent with the numerical simulation results. The heading face coal during roadway excavation shows obvious damage, and the strength characteristics of the coal decrease.  相似文献   

δ15N and δ13C in the Mondego estuary food web: Seasonal variation in producers and consumers     

Alexandra Baeta  Rute Pinto  Ivan Valiela  Pierre Richard  Nathalie Niquil  João C. Marques 《Marine environmental research》2009,67(3):109-116

Assessments of temporal variation in stable carbon and nitrogen ratios were used to examine seasonal trends of the water column and benthic food webs in the Mondego estuary (Portugal). There was a marked seasonality in weather and water column conditions, including nutrient supply and chlorophyll concentrations. In spite of the pronounced environmental changes, we found little evidence of seasonal variation in δ¹³C and δ¹⁵N of producers and consumers in the Mondego estuary, with a few notable exceptions. Nitrogen isotope ratios in macrophytes (Zostera noltii, Ulva sp., Enteromorpha sp., and Gracilaria sp.), and in two grazers (Idotea chelipes and Lekanesphaera levii) increased during late summer, with the highest δ¹⁵N values being measured in July, during a period of elevated temperatures and drought, which may have favored high rates of denitrification and heavier δ¹⁵N values. The results suggest that stable-isotope values from macrophytes and selected grazers are useful as tracers of seasonal changes in nitrogen inputs into estuaries, and that those of consumers reflect other factors beyond seasonal variations in N and C sources.  相似文献   

The 2dF Galaxy Redshift Survey: the luminosity function of cluster galaxies     

Roberto De Propris  Matthew Colless  Simon P. Driver  Warrick Couch  John A. Peacock  Ivan K. Baldry  Carlton M. Baugh  Joss Bland-Hawthorn  Terry Bridges  Russell Cannon  Shaun Cole  Chris Collins  Nicholas Cross  Gavin B. Dalton  George Efstathiou  Richard S. Ellis  Carlos S. Frenk  Karl Glazebrook  Edward Hawkins  Carole Jackson  Ofer Lahav  Ian Lewis  Stuart Lumsden  Steve Maddox  Darren S. Madgwick  Peder Norberg  Will Percival  Bruce Peterson  Will Sutherland  Keith Taylor 《Monthly notices of the Royal Astronomical Society》2003,342(3):725-737

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The age of the meteorite recovery surfaces of Roosevelt County,New Mexico,USA     

Michael E. Zolensky  Helen M. Rendell  Ivan Wilson  Gordon L. Wells 《Meteoritics & planetary science》1992,27(4):460-462

Abstract— We have obtained minimum age estimates for the sand units underlying the two largest meteorite deflation surfaces in Roosevelt County, New Mexico, USA, using thermoluminescence dating techniques. The dates obtained ranged from 53.5 (±5.4) to 95.2 (±9.5) ka, and must be considered lower limits for the terrestrial ages of the meteorites found within these specific deflation surfaces. These ages greatly exceed previous measurements from adjacent meteorite-producing deflation basins. We find that Roosevelt County meteorites are probably terrestrial contemporaries of the meteorites found at most accumulation zones in Antarctica. The apparent high meteorite accumulation rate reported for Roosevelt County by Zolensky et al. (1990) is incorrect, as it used an age of 16 ka for all Roosevelt County recovery surfaces. We conclude that the extreme variability of terrestrial ages of the Roosevelt County deflation surfaces effectively precludes their use for calculations of the meteorite accumulation rate at the Earth's surface.  相似文献