A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)     

Delphine Yeghicheyan  Dominique Aubert  Martine Bouhnik‐Le Coz  Jrme Chmeleff  Sophie Delpoux  Irina Djouraev  Guy Granier  Franois Lacan  Jean‐Luc Piro  Tristan Rousseau  Christophe Cloquet  Aurlie Marquet  Christophe Menniti  Catherine Pradoux  Rmi Freydier  Emmanoel Vieira da Silva‐Filho  Krzysztof Suchorski 《Geostandards and Geoanalytical Research》2019,43(3):475-496

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.  相似文献   

Organotin accumulation in an estuarine food chain: comparing field measurements with model estimations     

Veltman K  Huijbregts MA  van den Heuvel-Greve MJ  Vethaak AD  Hendriks AJ 《Marine environmental research》2006,61(5):511-530

The bioaccumulation model OMEGA (optimal modelling for ecotoxicological applications) is used to explore accumulation of organotins in the Western Scheldt food chain, consisting of herbi-detritivores, primary and secondary carnivorous fish and a piscivorous bird. Organotins studied are tributyltin (TBT) and triphenyltin (TPT) and the respective di- and mono-organotin metabolites. Empirical elimination rate constants are compared to model predictions for organic substances and metals. It is found that field bioaccumulation ratios are higher than predicted based on elimination kinetics relevant for organic compounds. The results indicate that uptake of organotins mainly occurs via hydrophobic mechanisms, whereas elimination may occur via metal-like kinetics. This results in very low elimination rates, which are comparable to model predictions for metals.  相似文献   

How does the bed surface impact low-magnitude bedload transport rates over gravel-bed rivers?     

Emeline Perret  Céline Berni  Benoît Camenen 《地球表面变化过程与地形》2020,45(5):1181-1197

Bedload transport is a complex phenomenon that is not well understood, especially for poorly sorted sediment and low transport rates, which is what is typically found in alpine gravel-bed rivers. In this paper, the interaction between bedload rate, bed stability and flow is investigated using flume experiments. Significant differences in bedload rates were observed for experiments conducted on beds formed with the same gravel material but presenting diverse arrangements and bedforms. Tests were performed under regimes of low transport rate, which are mainly controlled by gravel-bed roughness. Different scales of roughness were identified using the statistical characteristics of detailed bed elevation measurements: grain, structure and large bedform scales. The role played by these different roughness scales in bedload dynamics was examined. For quasi-flat beds, bed stability was quantified using a combination of bed surface criteria describing grain and structure scales. It was found that bed stability affects the bedload rate directly and not only through its influence on the flow or on the incipient motion. For beds with large bedforms, the analysis of bedload dynamics also showed the importance of accounting for effective bed shear stress distributions. An empirical bedload model for low transport regimes was suggested. Compared with previous formulae developed for alpine rivers, this model accounts for bed stability and distribution of effective bed shear stress. It significantly improves the understanding of gravel dynamics over complex beds such as arranged beds or those with large bedforms. However, further tests are needed to use the model outside the range of conditions of this study. © 2019 John Wiley & Sons, Ltd.  相似文献   

Comparison of ground-based and UAV a-UHF artificial tracer mobility monitoring methods on a braided river     

M. Cassel  H. Piégay  G. Fantino  J. Lejot  L. Bultingaire  K. Michel  F. Perret 《地球表面变化过程与地形》2020,45(5):1123-1140

Radio frequency identification (RFID) technologies, which allow wireless detection of individual buried or immersed tracers, represent a step forward in sediment tracking, especially passive integrated transponders (PIT tags) that have been widely used. Despite their widespread adoption in the scientific community, they typically have low efficiency when deployed in river systems with active bedload transport or deep wet channels, attributed to their technical specifications. A recent evaluation of active ultra-high frequency transponders (a-UHF tags) assessed their larger detection range and provided a methodology for their geopositioning. In this study, we test five different survey methods (one including an unmanned aerial vehicle [UAV]) in a sediment tracking study, and compare them in terms of recovery rate, field effort, geopositioning error, and efficiency. We then tested the method on a larger reach following a Q₅ flood and performed cross-comparisons between active and passive RFIDs. The results confirmed that the a-UHF RFID technology allowed rapid (1.5 h ha⁻¹) survey of a large area (<34 ha) of emerged bars and shallow water channels with recovery of a high percentage of tracers (72%) that had travelled large distances (mean ≈ 1000 m; max ≈ 3400 m). Moreover, the tracers were identified with low geopositioning error (mean ≈ 7.1 m, ≤1% of their travel distance). We also showed that a UAV-based survey was fast (0.38 h ha⁻¹), efficient (recovery rate = 84%), and low error (mean ≈ 4.2 m). Thus, a-UHF RFID technology permits the development of a variety of survey methods, depending on the study objectives and the human and financial resources available. This allows field efforts to be optimized by determining an appropriate balance between the high equipment cost of a-UHF tracers and the resulting reduced survey costs. © 2019 John Wiley & Sons, Ltd.  相似文献   

Public expectation as an element of human perception of climate change   总被引：2，自引：1，他引：1  

Martine Rebetez 《Climatic change》1996,32(4):495-509

Human expectations regarding weather and climate sometimes lead to perceptions of climate change which are not supported by observational evidence. This paper analyses two very characteristic complaints about current climate in Switzerland, i.e., the lack of snow in winter and the lack of sunshine in summer, through a statistical investigation of climatological data. As one major problem of public perception of climate in mid-latitude regions is linked to the strong variability of the climatic parameters, the paper suggests means of presenting climatic data which include a measure of this variability. Such presentations would help overcome the common confusion between the terms weather and climate, and stress the fact that short-term extreme events are not necessarily indicative of a long-term shift in climate.  相似文献   

The Holocene volcanic history of Gran Canaria island: implications for volcanic hazards     

Alejandro Rodriguez‐Gonzalez  Jose L. Fernandez‐Turiel  Francisco J. Perez‐Torrado  Alex Hansen  Meritxell Aulinas  Juan C. Carracedo  Domingo Gimeno  Hervé Guillou  Raphaël Paris  Martine Paterne 《第四纪科学杂志》2009,24(7):697-709

Previous published data, combined with our results of 13 new radiocarbon ages and extensive geological fieldwork, indicate that during the past 11 ka 24 monogenetic basaltic eruptions occurred in the north sector of Gran Canaria. These eruptions can be grouped into three periods of eruptive activity: 1900–3200 ¹⁴C a BP; 5700–6000 ¹⁴C a BP; and an older period represented by only one eruption, El Draguillo, dated at 10 610 ± 190 ¹⁴C a BP. Archaeological studies have shown that the more recent eruptions affected prehistoric human settlements on the island. Field studies demonstrate that the eruptions typically built strombolian cones (30–250 m in height) and associated relatively long lava flows (100–10 350 m in length); a few eruptions also produced tephra fall deposits. The total erupted volume of these eruptions is about 0.388 km³ (46.1% as tephra fall, 41.8% as cinder cone deposits and 12.1% as lava flows). The relatively low eruption rate (～0.04 km³ ka^?1) during the past 11 ka is consistent with Gran Canaria's stage of evolution in the regional volcano‐tectonic setting of the Canary Archipelago. The results of our study were used to construct a volcanic hazards map that clearly delimits two sectors in the NE sector of Gran Canaria, where potential future eruptions would pose a substantial risk for densely populated areas. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Late glacial to Holocene planktic foraminifera bioevents and climatic record in the South Adriatic Sea     

Giuseppe Siani  Martine Paterne  Christophe Colin 《第四纪科学杂志》2010,25(5):808-821

Quantitative analyses of planktic foraminifera, sea‐surface temperatures (SSTs), oxygen isotope and radiocarbon dating from a deep‐sea core recovered in the South Adriatic Sea have been used to reconstruct a subcentennial climatic and biochronological record since the late glacial (the last 24 cal. ka BP). The identification and relative abundance of 25 species of planktic foraminifera along the core have provided a continuous record of the faunal changes over this time interval. These results have permitted the establishment of 10 biozones in the South Adriatic Sea based on the appearance and/or disappearance of the main specific taxa, from peaks of abundance and/or by modification in marine conditions. The robust chronology of the South Adriatic core allowed correlation of SST estimates to the GISP2 ice core record, indicating that the main climate changes recorded in Greenland ice cores over the last 24 ka are recorded and globally synchronous with those observed in the South Adriatic Sea. This finding further allows comparison of the planktic foraminifera record with the event stratigraphic scheme proposed by the INTIMATE group in order to better identify the relationship between past climatic changes and the response of microfaunal assemblages in the South Adriatic. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Formation of phyllosilicates in a fault zone affecting deeply buried arkosic sandstones: their influence on petrophysic properties (Annot sandstones, French external Alps)     

Henri Leclère  Martine Buatier  Delphine Charpentier  Jean-Pierre Sizun  Pierre Labaume  Thibault Cavailhes 《Swiss Journal of Geoscience》2012,105(2):299-312

The Restefond fault, located in the Late Eocene-Early Oligocene Alpine foreland basin, affects the well lithified and low porosity Grès d??Annot. The fault core zone is characterized by the occurrence of highly deformed sandstone lenses. Deformation inside the lenses corresponds to mm to sub-mm-spaced cleavage planes rich in phyllosilicates and up to cm-thick and dm-long quartz-calcite pure extensional veins. The cleavages are mostly composed of newly-formed synkinematic white mica and chlorite. By using thermodynamic thermometers based on the chemical composition of chlorite, a temperature of 200?±?20?°C of fault activity was computed. This temperature shows that the Restefond fault was active at burial conditions comprised between 6.5 and 8?km, assuming a mean geothermal gradient between 25 and 30?°Ckm^?1. The petrophysic properties of sandstones from the core zone and in the hanging and foot wall of the fault were determined on drilled plugs following three spacial directions. The permeability of the highly deformed sandstone from the core zone is about one order of magnitude higher than in the host rock. This increase in permeability occurs in the direction parallel to the S?CC structures and is explained by the occurrence of well-connected micropores localized between platy phyllosilicates. This study shows that the fault petrophysic properties are mostly controlled by the precipitation of synkinematic phyllosilicates under deep burial conditions.  相似文献   

An improved description of the interactions between rare earth elements and humic acids by modeling: PHREEQC-Model VI coupling     

Rémi Marsac  Mélanie Davranche  Gérard Gruau  Martine Bouhnik-Le Coz  Aline Dia 《Geochimica et cosmochimica acta》2011,75(19):5625-5637

The Humic Ion Binding Model VI (Model VI) - previously used to model the equilibrium binding of rare earth elements (REE) by humic acid (HA) - was modified to account for differences in the REE constant patterns of the HA carboxylic and phenolic groups, and introduced into PHREEQC to calculate the REE speciation on the HA binding sites. The modifications were shown to greatly improve the modeling. They allow for the first time to both satisfactorily and simultaneously model a large set of multi-REE experimental data with the same set of equations and parameters. The use of PHREEQC shows that the light rare earth elements (LREE) and heavy rare earth elements (HREE) do not bind to HA by the same functional groups. The LREE are preferentially bound to carboxylic groups, whereas the HREE are preferentially bound to carboxy-phenolic and phenolic groups. This binding differentiation might lead to a fractionation of REE-HA patterns when competition between REE and other metals occur during complexation. A survey of the available data shows that competition with Al³⁺ could lead to the development of HREE-depleted HA patterns. This new model should improve the hydrochemical modeling of the REE since PHREEQC takes into account chemical reactions such as mineral dissolution/precipitation equilibrium and redox reactions, but also models kinetically controlled reactions and one-dimensional transport.  相似文献   

Hydrothermal alteration in andesitic volcanoes: Trace element redistribution in active and ancient hydrothermal systems of Guadeloupe (Lesser Antilles)     

Anne Salaün  Benoît Villemant  Martine Gérard  Jean-Christophe Komorowski  Agnès Michel 《Journal of Geochemical Exploration》2011,111(3):59-83

The mineralogy and the trace element compositions of hydrothermally-altered volcanic materials collected from ash fall deposits and in four debris-avalanche deposits (DADs) at La Soufrière volcano in Guadeloupe have been determined. Phreatic explosions of the 1976 eruption and flank collapse events have sampled various parts of the active and ancient hydrothermal systems of the volcano. Hydrothermal mineral assemblages (smectite + silica polymorphs ± pyrite/jarosite ± gypsum) are typical of rock alteration by low-temperature acid-sulphate fluids. High-temperature mineral assemblages are rare, indicating that phreatic explosions and flank collapse events have sampled mainly the upper parts of the volcanic edifice.Andesitic eruptive products affected by shallow hydrothermal alteration are complex assemblages of volcanic materials (glass, phenocrysts and xenocrysts with complex magmatic histories) of different ages and compositions. The use of incompatible element ratios and REE compositions normalised to an unaltered reference material overcomes the interpretation difficulties related to mass balance effects of alteration processes and the petrologic heterogeneity of the initial material.REE and other incompatible elements (Th, U, Hf, Zr) are mainly concentrated in the glassy matrix of unaltered andesitic rocks. Secondary S-bearing mineral phases (e.g., gypsum, jarosite) that have precipitated from acid-sulphate fluids do not contain substantial incompatible elements (REE, U, Th, Hf, Zr). Compositional variations of incompatible elements in hydrothermally-altered andesitic materials reflect mainly volcanic glass–smectite transformation, which is characterised by (i) strong depletion of alkalis and alkaline earths (Ba, Sr) and first transition series elements (Zn, Cu, Cr, Co, Ni), (ii) immobility of highly incompatible elements (Th, Zr, Hf, LREE) and (iii) strong depletion of MREE and HREE. The sigmoid shape of normalised REE pattern is characteristic of glass–smectite transformation by low-temperature acid-sulphate fluids. This transformation also produces significant variations in U/Th values, which offer the opportunity to date the cessation of hydrothermal alteration and to reconstruct the evolution in space and time of hydrothermal activity in a volcanic edifice.  相似文献