Atmospheric lead fallout over the last century recorded in Gulf of Lions sediments (Mediterranean Sea)     

Miralles J  Véron AJ  Radakovitch O  Deschamps P  Tremblay T  Hamelin B 《Marine pollution bulletin》2006,52(11):1364-1371

Six marine sediment cores from the Gulf of Lions continental slope (700-1700 m water depth) were analyzed for stable lead isotopes and (210)Pb geochronology in order to reconstruct lead atmospheric fallout pattern during the last century. The detrital lead contribution is 25 microg g(-1) and the mean sediment anthropogenic inventory is 110+/-7 microg cm(-2), a little bit higher than atmospheric deposition estimate. Anthropogenic lead accumulation in sediments peaked in early 1970s (1973+/-2) in agreement with lead emissions features. For the period 1986-1997, the sediment signal also reflect the decrease of atmospheric lead described by independent atmospheric fallout investigations. The anthropogenic Pb deposition in the late 1990s was similar to the 1950s deposition, attesting thus of the output of European environmental policies.  相似文献   

Lichens as bioindicators in volcanic areas: Mt. Etna and Vulcano Island (Italy)     

M. F. Grasso  R. Clocchiatti  F. Carrot  C. Deschamps  F. Vurro 《Environmental Geology》1999,37(3):207-217

 The aim of this paper is to verify whether lichens have the capacity to accumulate atmospheric contaminators linked to volcanic activity. About 100 lichens were collected in 1994 and 1995 from two active volcanic areas in Italy: Mount Etna and Vulcano Island. Twenty-seven elements were analyzed for each individual lichen using Instrumental Neutronic Activation Analysis and Inductively Coupled Plasma-Mass Spectrometry. Lichen composition reflects the contribution of the volcanic particulate material, and the two areas investigated can be distinguished on the basis of the concentration of some lithophile elements. Moreover, the distribution in lichens of the elements (As, Sb, Br, Pb) – derived from gas emissions (plume, fumaroles) – also shows different geochemical trends on Mt. Etna and Vulcano. Received: 20 April 1998 · Accepted: 4 July 1998  相似文献   

Use of Sonication for Enhanced Sampling of Attached Microbes from Groundwater Systems     

Murray Close  Phil Abraham  Judith Webber  Eliza Cowey  Bronwyn Humphries  Graham Fenwick  Simon Howard  Kimberly Huynh  Travis Grace  Pierre-Yves Dupont  Louise Weaver 《Ground water》2020,58(6):901-912

The vast majority of microorganisms in aquifers live as biofilms on sediment surfaces, which presents significant challenges for sampling as only the suspended microbes will be sampled through normal pumping. The use of a down-well low frequency sonicator has been suggested as a method of detaching microbes from the biofilm and allowing rapid sampling of this community. We developed a portable, easy to use, low-frequency electric sonicator and evaluated its performance for a range of well depths (tested up to 42 m below ground level) and casing types. Three sonicators were characterized in laboratory experiments using a 1 m long tank filled with pea gravel. These included a commercially available pneumatic sonicator, a rotating flexible shaft sonicator, and the prototype electric sonicator. The electric sonicator detached between 56 and 74% of microbes grown on gravel-containing biobags at distances ranging between 2 and 50 cm from the sonicator. The field testing comprises of a total of 55 sampling events from 48 wells located in 4 regions throughout New Zealand. Pre- and post-sonication samples showed an average 33 times increase in bacterial counts. Microbial sequence data showed that the same classes are present in pre- and post-sonicated samples and only slight differences were seen in the proportions present. The sampling process was rapid and the significant increases in bacterial counts mean that microbial samples can be quickly obtained from wells, which permits more detailed analysis than previously possible.  相似文献   

From outwash to coastal systems in the Portneuf–Forestville deltaic complex (Québec North Shore): Anatomy of a forced regressive deglacial sequence          下载免费PDF全文

Pierre Dietrich  Jean‐François Ghienne  Mathieu Schuster  Patrick Lajeunesse  Alexis Nutz  Rémy Deschamps  Claude Roquin  Philippe Duringer 《Sedimentology》2017,64(4):1044-1078

Deglacial sequences typically include backstepping grounding zone wedges and prevailing glaciomarine depositional facies. However, in coastal domains, deglacial sequences are dominated by depositional systems ranging from turbiditic to fluvial facies. Such deglacial sequences are strongly impacted by glacio‐isostatic rebound, the rate and amplitude of which commonly outpaces those of post‐glacial eustatic sea‐level rise. This results in a sustained relative sea‐level fall covering the entire depositional time interval. This paper examines a Late Quaternary, forced regressive, deglacial sequence located on the North Shore of the St. Lawrence Estuary (Portneuf Peninsula, Québec, Canada) and aims to decipher the main controls that governed its stratigraphic architecture. The forced regressive deglacial sequence forms a thick (>100 m) and extensive (>100 km²) multiphased deltaic complex emplaced after the retreat of the Laurentide Ice Sheet margin from the study area ca 12 500 years ago. The sedimentary succession is composed of ice‐contact, glaciomarine, turbiditic, deltaic, fluvial and coastal depositional units. A four‐stage development is recognized: (i) an early ice‐contact stage (esker, glaciomarine mud and outwash fan); (ii) an in‐valley progradational stage (fjord head or moraine‐dammed lacustrine deltas) fed by glacigenics; (iii) an open‐coast deltaic progradation, when proglacial depositional systems expanded beyond the valley outlets and merged together; and (iv) a final stage of river entrenchment and shallow marine reworking that affected the previously emplaced deltaic complex. Most of the sedimentary volume (10 to 15 km³) was emplaced during the three‐first stages over a ca 2 kyr interval. In spite of sustained high rates of relative sea‐level fall (50 to 30 mm·year^?1), delta plain accretion occurred up to the end of the proglacial open‐coast progradational stage. River entrenchment only occurred later, after a significant decrease in the relative sea‐level fall rates (<30 mm·year^?1), and was concurrent with the formation and preservation of extensive coastal deposits (raised beaches, spit platform and barrier sands). The turnaround from delta plain accretion to river entrenchment and coastal erosion is interpreted to be a consequence of the retreat of the ice margin from the river drainage basins that led to the drastic drop of sediment supply and the abrupt decrease in progradation rates. The main internal stratigraphic discontinuity within the forced regressive deglacial sequence does not reflect changes in relative sea‐level variations.  相似文献   

The toxicological interaction between ocean acidity and metals in coastal meiobenthic copepods     

Pierre-Yves Pascal  John W. Fleeger  Fernando Galvez  Kevin R. Carman 《Marine pollution bulletin》2010,60(12):2201-2208

Increased atmospheric CO₂ concentrations are causing greater dissolution of CO₂ into seawater, and are ultimately responsible for today’s ongoing ocean acidification. We manipulated seawater acidity by addition of HCl and by increasing CO₂ concentration and observed that two coastal harpacticoid copepods, Amphiascoides atopus and Schizopera knabeni were both more sensitive to increased acidity when generated by CO₂. The present study indicates that copepods living in environments more prone to hypercapnia, such as mudflats where S. knabeni lives, may be less sensitive to future acidification. Ocean acidification is also expected to alter the toxicity of waterborne metals by influencing their speciation in seawater. CO₂ enrichment did not affect the free-ion concentration of Cd but did increase the free-ion concentration of Cu. Antagonistic toxicities were observed between CO₂ with Cd, Cu and Cu free-ion in A. atopus. This interaction could be due to a competition for H⁺ and metals for binding sites.  相似文献   

Damage seismic scenarios for Angra do Heroísmo, Azores (Portugal)     

Idalina Veludo  Paula Teves-Costa  Pierre-Yves Bard 《Bulletin of Earthquake Engineering》2013,11(2):423-453

Angra do Heroísmo, located in Terceira Island, is the main town of the Central Group of Azores Archipelago and it is classified as World Heritage by Unesco. The preservation of this patrimony, located inside a seismic region, includes the implementation of a policy to protect it against earthquakes. The development of credible damage scenarios could help this objective, as they can be used in prevention measures to minimize the impact of future earthquakes. Two methods were used for seismic damage estimation: the capacity spectrum method and a new method, based on the direct response of a 1D non-linear oscillator to simulate the building seismic performance. Both methods seem to overestimate the damages for the near sources, but this could be due to the empirical model used to estimate the input ground motion. Comparison with the damage observed after the January 1st, 1980 earthquake show a large discrepancy with an underestimation bias, which can be explained, mainly, by the difference of building performance and on the plausible hypothesis of 2D site effects.  相似文献   

Instability structures, synsedimentary faults and turbidites, witnesses of a Liassic seismotectonic activity in the Dauphiné Zone (French Alps): A case example in the Lower Pliensbachian at Saint-Michel-en-Beaumont     

Franoise Bergerat  Pierre-Yves Collin  Anne-Cline Ganzhorn  Franois Baudin  Bruno Galbrun  Isabelle Rouget  Johann Schnyder 《Journal of Geodynamics》2011,51(5):344-357

Instability structures, synsedimentary faults and turbidites have been studied in the Lower Pliensbachian succession of Saint-Michel-en-Beaumont, belonging to the Taillefer block, an ancient half-graben emplaced during the Liassic Tethyan rifting. Geometrical and mechanical analyses demonstrate that the instability structures occurred thanks to movements along spineless synsedimentary normal faults, when the turbiditic and limestone layers were already case-hardened and partly fractured by tension gashes even when the mudstones were still unlithified. Both the tension gashes and the synsedimentary faults are homogeneous in strike with the major regional faults and are in good agreement with the regional direction of extension for this period. The characters of the turbiditic beds, with erosive base, graded bedding, and incomplete Bouma sequence, are in favour of a seismic origin. Instability structures, spineless synsedimentary faults and turbiditic inflows are thus considered as seismites and interpreted as the result of high seismicity periods including some events with M > 5 in the general extensive ambiance of the Liassic Tethyan rifting. The analysis of the geometrical relationships between all these sedimentary features allows to distinguish the successive stage of occurrence of an instability structure, from the sedimentation of alternating marls and limestones, and sudden turbiditic inflows, then early case-hardening of the turbidites, until the important seismotectonic event generating the spineless normal faults, themselves triggering the fall of indurated blocks and locally the forming of breccias. The Ornon Fault, which constitutes the border of the Taillefer block, 15 km eastward, played a major role during the Liassic sedimentation and may represent the major seismic fault related to the seismites occurrence in the Beaumont basin.  相似文献   

Pb,Hf and Nd isotope compositions of the two Réunion volcanoes (Indian Ocean): A tale of two small-scale mantle “blobs”?     

Delphine Bosch  Janne Blichert-Toft  Frédéric Moynier  Bruce K. Nelson  Philippe Telouk  Pierre-Yves Gillot  Francis Albarède 《Earth and Planetary Science Letters》2008,265(3-4):748-765

Pb, Hf, Nd and Sr isotopes of basaltic lavas from the two Réunion Island volcanoes are reported in order to examine the origin of the sources feeding these volcanoes and to detect possible changes through time. Samples, chosen to cover the whole lifetime of the two volcanoes (from 2 Ma to present), yield a chemically restricted (compared to OIB lavas) but complex distribution. Réunion plume isotopic characteristics have been defined on the basis of the composition of uncontaminated shield-building lavas from the Piton de la Fournaise volcano. The average ?_Nd, ?_Hf, ⁸⁷Sr/⁸⁶Sr and ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb isotope ratios calculated for this component are + 4.4, + 9.1, 0.70411, 18.97, 15.59 and 39.03, respectively. In Pb–Pb isotope space, each volcano defines a distinct linear trend but slight variations are also detected within the various volcanic sequences. The Piton des Neiges volcano yields a distinct and significantly more scattered isotopic distribution than Piton de la Fournaise for both Pb, Hf and Nd isotope tracers. A principal component analysis of the Pb isotope data from Piton de la Fournaise reveals a major contribution of the C and EM-1 components (with a clear Dupal flavor) as main components for the modern Réunion plume. The same components have been identified for Piton des Neiges but with a stronger participation of a depleted mantle component and a weaker EM-1 contribution. The compositional change of the lavas erupted by the Piton des Neiges and Piton de la Fournaise volcanoes is attributed to the impingement of two small-scale blobs of plume material at the base of the Réunion lithosphere. Compared to other hot-spots worldwide, in particular Hawaii and Kerguelen, magmas beneath Réunion are generated from a considerably more homogeneous, compositionally more primitive plume higher in ²⁰⁶Pb. Although shallow-level contamination processes have been locally detected they did not alter significantly the composition of the plume magmas. This is tentatively attributed to mantle dynamics producing small, high-velocity blobs that ascend rapidly through the lithosphere, and to the lack of a well-developed magma chamber at depth in the lithosphere.  相似文献   

2D equivalent linear site effect simulation: example applications to two deep valleys     

Corinne Lacave  Pierre-Yves Bard  Marc Kham  Martin G. Koller 《Bulletin of Earthquake Engineering》2008,6(2):197-211

In the framework of the Sismovalp European project, an equivalent linear 2D code was developed to compute the response of a valley to SH waves, using the discrete wave-number method proposed by Aki and Larner (Aki K, Larner KL (1970) J Geophys Res 75:5). To overcome the frequency upper bound limitation, the Aki and Larner’s method is combined with a one-dimensional computation using a classical multi-layer method (Aki K, Richards PG (1980) Quantitative Seismology: Theory and Methods, vols. 1 & 2. W.H. Freeman & Co, San Francisco). The so-called “Aki–Larner extended method” is associated to an iterative algorithm, as proposed by Seed and Idriss (Seed HB, Idriss IM (1969) Report No. EERC 70–10, Earthquake Research Center, University of California, Berkeley, California) which accounts for the modulus and damping degradation using a linear visco-elastic model. A comparison of the results in the linear and the equivalent linear cases, for a magnitude 6.0 earthquake, shows that the account for the equivalent linear behaviour of the soil significantly reduces the amplification level, especially at frequencies higher than the fundamental resonance frequency of the site. In the case of site effects or microzonation studies devoted to produce design spectra for engineering structures, this can have a major impact on the associated results and costs, depending on the frequency of interest for the considered structure. As a first application of the developed technique, 2D equivalent linear Aki–Larner computations are used to perform the seismic microzonation study of the upper Rhone valley, in the Visp area (Switzerland), a typical 2D alpine valley. These investigations made it possible to determine site specific spectra, associated with different zones, to be used instead of the code spectra that do not take into account the local 2D amplification.  相似文献   

Shapes of chondrules determined from the petrofabric of the CR2 chondrite NWA 801     

Christopher R. J. Charles  Pierre-Yves F. Robin  Donald W. Davis  Phil J. A. McCausland 《Meteoritics & planetary science》2018,53(5):935-951

The approximately spherical shapes of chondrules has long been attributed to surface tension acting on ~1 mm melt droplets that formed and cooled in the microgravity field of the solar nebula. However, chondrule shapes commonly depart significantly from spherical. In this study, 109 chondrules in a sample of CR2 chondrite NWA 801 were imaged by X-ray computed tomography and best-fitted to ellipsoids. The analysis confirms that many chondrules are indeed not spherical, and also that the chondrules’ collective shape fabric records a definite 13% compaction in the host meteorite. Dehydration of phyllosilicates within chondrules may account for that strain. However, retro-deforming all chondrules shows that a large majority were already far from spherical prior to accretion. Possible models for these initial shapes include prior deformation of individual chondrules in earlier hosts, and, as suggested by previous authors, rotation of chondrules as they were solidifying, and/or “streaming” of molten chondrules by their differential velocities with their gaseous hosts after melting. More in situ 3-D work such as this study on a variety of unequilibrated chondrites, combined with detailed structural petrography, should help further constrain these models and refine our understanding of chondrite formation.  相似文献