Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: field measurements and theoretical analysis     

Michael M. Reddy  Micaela B. Reddy  Kenneth L. Kipp  Aaron Burman  Paul Schuster  Peter S. Rawlik Jr. 《水文研究》2008,22(11):1713-1724

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.  相似文献   

Optimization techniques for integrating spatial data     

Ute C. Herzfeld  Daniel F. Merriam 《Mathematical Geology》1995,27(5):559-588

Two optimization techniques ta predict a spatial variable from any number of related spatial variables are presented. The applicability of the two different methods for petroleum-resource assessment is tested in a mature oil province of the Midcontinent (USA). The information on petroleum productivity, usually not directly accessible, is related indirectly to geological, geophysical, petrographical, and other observable data. This paper presents two approaches based on construction of a multivariate spatial model from the available data to determine a relationship for prediction. In the first approach, the variables are combined into a spatial model by an algebraic map-comparison/integration technique. Optimal weights for the map comparison function are determined by the Nelder-Mead downhill simplex algorithm in multidimensions. Geologic knowledge is necessary to provide a first guess of weights to start the automatization, because the solution is not unique. In the second approach, active set optimization for linear prediction of the target under positivity constraints is applied. Here, the procedure seems to select one variable from each data type (structure, isopachous, and petrophysical) eliminating data redundancy. Automating the determination of optimum combinations of different variables by applying optimization techniques is a valuable extension of the algebraic map-comparison/integration approach to analyzing spatial data. Because of the capability of handling multivariate data sets and partial retention of geographical information, the approaches can be useful in mineral-resource exploration.  相似文献   

Evidence for high-pressure core-mantle differentiation from the metal-silicate partitioning of lithophile and weakly-siderophile elements     

Ute Mann  Daniel J. Frost  David C. Rubie 《Geochimica et cosmochimica acta》2009,73(24):7360-470

Liquid Fe metal-liquid silicate partition coefficients for the lithophile and weakly-siderophile elements Ta, Nb, V, Cr, Si, Mn, Ga, In and Zn have been measured in multianvil experiments performed from 2 to 24 GPa, 2023-2873 K and at oxygen fugacities of −1.3 to −4.2 log units relative to the iron-wüstite buffer. Compositional effects of light elements dissolved in the metal liquid (S, C) have been examined and experiments were performed in both graphite and MgO capsules, specifically to address the effect of C solubility in Fe-metal on siderophile element partitioning. The results were used to examine whether there is categorical evidence that a significant portion of metal-silicate equilibration occurred under very high pressures during core-mantle fractionation on Earth. Although the depletion of V from the mantle due to core formation is significantly greater than that of Nb, our results indicate that both elements have similar siderophile tendencies under reducing conditions at low pressures. With increasing pressure, however, Nb becomes less siderophile than V, implying that average metal-silicate equilibration pressures of at least 10-40 GPa are required to explain the Nb/V ratio of the mantle. Similarly the moderately-siderophile, volatile element ratios Ga/Mn and In/Zn are chondritic in the mantle but both volatility and core-mantle equilibration at low pressure would render these ratios strongly sub-chondritic. Our results indicate that pressures of metal-silicate partitioning exceeding 30-60 GPa would be required to render these element ratios chondritic in the mantle. These observations strongly indicate that metal-silicate equilibration must have occurred at high pressures, and therefore support core-formation models that involve deep magma oceans. Moreover, our results allow us to exclude models that envisage primarily low-pressure (<1 GPa) equilibration in relatively small planetary bodies. We also argue that the core cannot contain significant U as this would require metal-silicate equilibration at oxygen fugacities low enough for significant amounts of Ta to have also been extracted from the mantle. Likewise, as In is more siderophile than Pb but similarly volatile and also quite chalcophile it would have been difficult for Pb to enter the core without reversing the relative depletions of these elements in the mantle unless metal-silicate equilibration occurred at high pressures >20 GPa.  相似文献   

Geostatistics for Compositional Data: An Overview   总被引：1，自引：0，他引：1  

Tolosana-Delgado  Raimon  Mueller  Ute  van den Boogaart  K. Gerald 《Mathematical Geosciences》2019,51(4):485-526

Mathematical Geosciences - This paper presents an overview of results for the geostatistical analysis of collocated multivariate data sets, whose variables form a composition, where the components...  相似文献   

An Integrated Mapping Approach to Petroleum Exploration on the Pratt Anticline,Pratt County,Kansas     

Merriam  Daniel F.  Herzfeld  Ute C.  Fuhr  Beth A. 《Natural Resources Research》1999,8(1):69-86

A quantitative map comparison/integration technique to aid in petroleum exploration was applied to an area in south-central Kansas. The visual comparison and integration of maps has become increasingly difficult with the large number and different types of maps necessary to interpret the geology and assess the petroleum potential of an area; therefore, it is desirable to quantify these relationships. The algebraic algorithm used in this application is based on a point-by-point comparison of any number and type of spatial data represented in map form. Ten geological and geophysical maps were compared and integrated, utilizing data from 900 wells located in a nine-township area on the Pratt Anticline in Pratt County, Kansas. Five structure maps, including top of the Lansing Group (Pennsylvanian), Mississippian chert, Mississippian limestone, Viola Limestone (Ordovician), and Arbuckle Group (Cambro-Ordovician), two isopachous maps from top of Mississippian chert to Viola and Lansing to Arbuckle, a Mississippian chert porosity map, Bouguer gravity map, and an aeromagnetic map were processed and interpreted. Before processing, each map was standardized and assigned a relative degree of importance, depending on knowledge of the geology of the area. Once a combination of weights was obtained that most closely resembled the pattern of proved oil fields (target map), a favorability map was constructed based on a coincidence of similarity values and of geological properties of petroleum reservoirs. The resulting favorability maps for the study area indicate location of likely Mississippian chert and lower Paleozoic production.  相似文献   

Parsimonious wave‐equation travel‐time inversion for refraction waves          下载免费PDF全文

Lei Fu  Sherif M. Hanafy  Gerard T. Schuster 《Geophysical Prospecting》2017,65(6):1452-1461

We present a parsimonious wave‐equation travel‐time inversion technique for refraction waves. A dense virtual refraction dataset can be generated from just two reciprocal shot gathers for the sources at the endpoints of the survey line, with N geophones evenly deployed along the line. These two reciprocal shots contain approximately 2N refraction travel times, which can be spawned into refraction travel times by an interferometric transformation. Then, these virtual refraction travel times are used with a source wavelet to create N virtual refraction shot gathers, which are the input data for wave‐equation travel‐time inversion. Numerical results show that the parsimonious wave‐equation travel‐time tomogram has about the same accuracy as the tomogram computed by standard wave‐equation travel‐time inversion. The most significant benefit is that a reciprocal survey is far less time consuming than the standard refraction survey where a source is excited at each geophone location.  相似文献   

Multiscale phase inversion for 3D ocean-bottom cable data     

Lei Fu  Zongcai Feng  Gerard T. Schuster 《Geophysical Prospecting》2020,68(3):786-801

We invert three-dimensional seismic data by a multiscale phase inversion scheme, a modified version of full waveform inversion, which applies higher order integrations to the input signal to produce low-boost signals. These low-boost signals are used as the input data for the early iterations, and lower order integrations are computed at the later iterations. The advantages of multiscale phase inversion are that it (1) is less dependent on the initial model compared to full waveform inversion, (2) is less sensitive to incorrectly modelled magnitudes and (3) employs a simple and natural frequency shaping filtering. For a layered model with a three-dimensional velocity anomaly, results with synthetic data show that multiscale phase inversion can sometimes provide a noticeably more accurate velocity profile than full waveform inversion. Results with the Society of Exploration Geophysicists/European Association of Geoscientists and Engineers overthrust model shows that multiscale phase inversion more clearly resolves meandering channels in the depth slices. However, the data and model misfit functions achieve about the same values after 50 iterations. The results with three-dimensional ocean-bottom cable data show that, compared to the full waveform inversion tomogram, the three-dimensional multiscale phase inversion tomogram provides a better match to the well log, and better flattens angle-domain common image gathers. The problem is that the tomograms at the well log provide an incomplete low-wavenumber estimate of the log's velocity profile. Therefore, a good low-wavenumber estimate of the velocity model is still needed for an accurate multiscale phase inversion tomogram.  相似文献   

From nappe stacking to exhumation: Cretaceous tectonics in the Apuseni Mountains (Romania)     

Reiser  Martin Kaspar  Schuster  Ralf  Spikings  Richard  Tropper  Peter  Fügenschuh  Bernhard 《International Journal of Earth Sciences》2017,106(2):659-685

International Journal of Earth Sciences - New Ar–Ar muscovite and Rb–Sr biotite age data in combination with structural analyses from the Apuseni Mountains provide new constraints on...  相似文献   

Generalized diffraction‐stack migration and filtering of coherent noise     

Ge Zhan  Wei Dai  Min Zhou  Yi Luo  Gerard T. Schuster 《Geophysical Prospecting》2014,62(3):427-442

We reformulate the equation of reverse‐time migration so that it can be interpreted as summing data along a series of hyperbola‐like curves, each one representing a different type of event such as a reflection or multiple. This is a generalization of the familiar diffraction‐stack migration algorithm where the migration image at a point is computed by the sum of trace amplitudes along an appropriate hyperbola‐like curve. Instead of summing along the curve associated with the primary reflection, the sum is over all scattering events and so this method is named generalized diffraction‐stack migration. This formulation leads to filters that can be applied to the generalized diffraction‐stack migration operator to mitigate coherent migration artefacts due to, e.g., crosstalk and aliasing. Results with both synthetic and field data show that generalized diffraction‐stack migration images have fewer artefacts than those computed by the standard reverse‐time migration algorithm. The main drawback is that generalized diffraction‐stack migration is much more memory intensive and I/O limited than the standard reverse‐time migration method.  相似文献   

Colluvial wedge imaging using traveltime and waveform tomography along the Wasatch Fault near Mapleton, Utah     

M.-L. Buddensiek  J. Sheng †  T. Crosby ‡  G. T. Schuster  R. L. Bruhn  R. He § 《Geophysical Journal International》2008,172(2):686-697

  相似文献