Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H₂S concentrations   总被引：2，自引：0，他引：2  

Chunfang Cai  Zengye Xie  Richard H. Worden  Guoyi Hu  Lansheng Wang  Hong He 《Marine and Petroleum Geology》2004,21(10):1265-1279

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.  相似文献   

A Numerical Model of Coastal Processes of Sand Beaches Based on Long-Term Wave Series     

Zhang Changkuan  Wang Zhen  Zhang Dongsheng Associate Professor  Dept. of Navigation  Ocean Engineering  Hohai University  Nanjing Lecturer  Dept. of Navigation  Ocean Engineering  Hohai University  Nanjing Professor  Dept. of Navigation  Ocean Engineering  Hohai University  Nanjing 《中国海洋工程》1995,(2)

A numerical model of shoreline change of sand beaches based on long-term field wave data is proposed, the explicit and implicit finite difference forms of the model are described, and an application of the model is presented. Results of the application indicate that the model is sensitive to the order of the input wave data, and that the effects of long-term wave series and the effects of the mean annual wave conditions on the model are different. Instead of a single wave condition, the wave series will make the calibration and the verification of the model more practical and the results of the model more reasonable.  相似文献   

中国对虾人工诱导雌核发育的研究 Ⅱ.紫外线辐射对精子顶体反应和受精能力的影响     

陈本楠  蔡难儿  李光友 《海洋科学》1997,21(1):41-47

研究了 36 5 nm波长紫外线辐射中国对虾精子对其顶体反应和受精能力的影响。结果表明 ,低剂量紫外线辐射促进精子发生顶体反应 ,大剂量辐射使精子丧失发生顶体反应的生理机能并死亡。 36 5 nm波长紫外线能够透过精荚和纳精囊盖 ,对其内精子起到杀伤作用。精液稀释液在紫外线下辐射 5～ 8s,仍有部分精子具有受精能力 ,但胚胎在早期阶段即死亡。人工诱导雌核发育的过程中 ,紫外线辐射精液稀释液 5～ 8s,可获得遗传物质失活的精子 (激活源 )。经透射电镜观察分析 ,紫外线对精子遗传物质的损伤是一种使染色质变性的化学作用。  相似文献   

海水中痕量硅酸盐硅钼黄分析法研究     

刘文远  蔡兴远 《海洋学报》1982,4(3):384-389

海水中痕量硅酸盐常用硅钼黄法测定[1-4].本文进一步研究酸度对硅钼黄形成反应的影响,采用合理的高酸度以获得较高的灵敏度和稳定性,使盐效应校正系数降低至4%.试验用人工海水工作曲线,结果免除了盐效应校正手续.试验将反应试剂事先混合后一次加入,简化了分析操作,缩短了工作时间,减少了船上的工作量.监于硅酸盐可能有聚合及水解反应,曾试验本方法制备的硅标准溶液的稳定性,结果可稳定一年之久.  相似文献   

Microbial degradation of chemically dispersed crude oil in marine enclesure ecosystem Ⅰ.Comparisons of different nutrients at low level primary productivity     

Cai Ziping  Wu Jiping 《海洋学报(英文版)》1994,13(2):305-309

Ｍｉｃｒｏｂｉａｌｄｅｇｒａｄａｔｉｏｎｏｆｃｈｅｍｉｃａｌｌｙｄｉｓｐｅｒｓｅｄｃｒｕｄｅｏｉｌｉｎｍａｒｉｎｅｅｎｃｌｅｓｕｒｅｅｃｏｓｙｓｔｅｍ—Ⅰ．Ｃｏｍｐａｒｉｓｏｎｓｏｆｄｉｆｆｅｒｅｎｔｎｕｔｒｉｅｎｔｓａｔｌｏｗｌｅｖｅｌｐｒｉｍａｒ...  相似文献   

一种新型潜水器HROV及其关键技术综述   总被引：8，自引：0，他引：8  

沈明学  胡震  刘正元 《海洋工程》2006,24(3):119-123

介绍一种新概念潜水器———混合型潜水器(HROV)。该潜水器能在两种不同的模式下工作,可以像AUV一样进行大范围的探测和搜索,也可以通过直径小于1 mm的微细光纤,执行传统ROV的近距离观察和采样任务。介绍了HROV的系统组成和工作过程,探讨与之相关的关键技术及其主要研究内容,并对HROV技术的应用前景也作了一些分析。  相似文献   

银川盆地中更新世以来的孢粉记录及古气候研究   总被引：8，自引：1，他引：8  

杨振京  刘志明  张俊牌  童国榜  阳小兰 《海洋地质与第四纪地质》2001,21(3):43-49

银川盆地中更新世以来的孢粉记录及据此所重建的古气候参数，揭示了该区中更新世以来的古气候演变特征，其演变经过了温湿→凉湿→温和→冷湿→温干→凉较湿→冷湿→温干→凉润→温较干→温干的变化，并与新疆地区，黄土高原以及深海δ^18O曲线进行了对比，结果表明，各地的古环境变化大致同步，该区由于位置靠西，邻近沙漠，最近地质历史时期的区域性干旱特色明显。  相似文献   

传感器电桥电路的非线性修正──用反馈补偿法修正传感器电桥电路的非线性误差     

蔡明华 《中国海洋大学学报(自然科学版)》1995,(4)

介绍一种反馈补偿法修正传感器电桥电路的非线性。提出反馈补偿原理及应用实例，指出用该方法可获得满意的补偿效果。  相似文献   

应用遗传神经网格方法分析赤潮监测数据   总被引：1，自引：1，他引：1  

杨建强  高振会  孙培艳  石强  李钦亮 《海洋科学进展》2002,20(2):77-82

简要介绍了遗传神经网络方法的原理 ,探讨了应用遗传神经网络方法研究辽东湾海域丹麦细柱藻 (Leptocylindrusdanicus)赤潮与其环境因子之间的关系 ,计算了各环境因子对丹麦细柱藻赤潮的贡献。结果表明 ,温度、盐度、DIN的变化对研究海域丹麦细柱藻种群密度的增长有比较重要的影响 ,DIN是营养限制因子。遗传神经网络是分析赤潮监测数据的有效方法 ,值得进一步探索  相似文献   

基于神经网络的平底结构砰击压力预报   总被引：1，自引：0，他引：1  

陈震  肖熙 《海洋工程》2005,23(2):26-31,41

对利用神经网络预报平底结构入水砰击压力的方法进行了探讨。首先利用仿真软件计算各种情况下平底结构入水所产生的砰击压力，以此形成训练神经网络的数据集。其次利用数据集对三层反馈式网络进行了训练，讨论了不同隐含层节点数对该非线性系统的拟合能力，并且对梯度下降法、动量修正法和基于优化的LM算法的有效性和精度进行了比较，最后得出了适合平底结构入水砰击系统的网络结构。  相似文献