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11.
Tsutomu Ota Katsura Kobayashi Takuya Kunihiro Eizo Nakamura 《Geochimica et cosmochimica acta》2008,72(14):3531-3541
Subduction of lithosphere, involving surficial materials, into the deep mantle is fundamental to the chemical evolution of the Earth. However, the chemical evolution of the lithosphere during subduction to depth remains equivocal. In order to identify materials subjected to geological processes near the surface and at depths in subduction zones, we examined B and Li isotopes behavior in a unique diamondiferous, K-rich tourmaline (K-tourmaline) from the Kokchetav ultrahigh-pressure metamorphic belt. The K-tourmaline, which includes microdiamonds in its core, is enriched in 11B relative to 10B (δ11B = −1.2 to +7.7) and 7Li relative to 6Li (δ7Li = −1.1 to +3.1). It is suggested that the K-tourmaline crystallized at high-pressure in the diamond stability field from a silicate melt generated at high-pressure and temperature conditions of the Kokchetav peak metamorphism. The heavy isotope signature of this K-tourmaline differs from that of ordinary Na-tourmalines in crustal rocks, enriched in the light B isotope (δ11B = −16.6 to −2.3), which experienced isotope fractionation through metamorphic dehydration reactions. A possible source of the heavy B-isotope signature is serpentine in the subducted lithospheric mantle. Serpentinization of the lithospheric mantle, with enrichment of heavy B-isotope, can be produced by normal faulting at trench-outer rise or trench slope regions, followed by penetration of seawater into the lithospheric mantle. Serpentine breakdown in the lithospheric mantle subducted in subarc regions likely provided fluids with the heavy B-isotope signature, which was acquired during the serpentinization prior to subduction. The fluids could ascend and cause partial melting of the overlying crustal layer, and the resultant silicate melt could inherit the heavy B-isotope signature. The subducting lithospheric mantle is a key repository for modeling the flux of fluids and associated elements acquired at a near the surface into the deep mantle. 相似文献
12.
A geological and geophysical survey off Tottori, southern-west of Honshu, Japan, was carried out by the Hydrographic Department of Japan during May and June (26 days) of 1974.In the survey area, there is marginal plateau which lies under the slope of the continental shelf adjacent to the Sanin district. By the closely-spaced surveying the marginal plateau was divided into two different zones based on differences of genesis and structure, which are identified in this paper as marginal plateaus A (west side) and marginal plateau B (east side). The tectonic boundary between marginal plateaus A and B, previously believed to exist near Tottori City, was not confirmed. An erosional plane, beneath the horizontally bedded upper layer was found to be 75 m lower than the submerged surface of marginal plateau A. Marginal plateau B is hypothesized to have been generated by the sliding of the upper layer. This is suggested by the presence of prominent slumping directed toward the bottom of the Oki Trough. This result implies that the submergence of the Oki Trough area and formation of the marginal plateau are closely related. 相似文献
13.
Takuji Kobori Motoichi Takahashi Tadashi Nasu Naoki Niwa Katsura Ogasawara 《地震工程与结构动力学》1993,22(11):925-941
The Active Variable Stiffness (AVS) system is proposed as a seismic response control system. It actively controls structural characteristics, such as stiffness of a building, to establish a non-resonant state against earthquake excitations, thus suppressing the building's response. It consumes a relatively small amount of energy and maintains the safety of the building in moderate to severe earthquakes. In order to accumulate practical data and investigate them, a building has been constructed as a trial. This paper describes the applied system, the control algorithm, verification of stiffness selection, results of tests for verifying system characteristics, some observed earthquake records and simulation analyses. Responses in controlled and uncontrolled states have been compared to show the effectiveness of the proposed system. 相似文献
14.
15.
The connectivity of molten Fe-S in peridotite has been experimentally investigated by means of in situ electrical conductivity measurements at high temperatures and 1 GPa. Starting materials were powdered mixtures of peridotite KLB-1 with various amounts (0, 3, 6, 13, 19, 24 vol.%) of the 1 GPa eutectic composition in the Fe-FeS binary system. At temperatures above the eutectic point in the Fe-FeS system (∼980 °C) and below the solidus of KLB1 (∼1200 °C), molten Fe-S in a solid silicate matrix interconnects when the volume fraction is over ∼5%. Conductivity-temperature paths indicate that in the presence of partial silicate melting the connectivity of molten Fe-S in a peridotite matrix is inhibited. Based on observations of retrieved samples, the percolation threshold of Fe-S melts in the presence of low to moderate degrees of silicate melt is estimated at 13±2 vol.%. These results indicate that if the volume fraction of Fe-alloy in a planetesimal was initially greater than 5%, and if early heating by decay of radionuclides raised the temperature of the interior above the Fe-alloy melting point, initial metal segregation was controlled by permeable flow of molten iron alloy in a solid silicate matrix. These conditions were likely met by many terrestrial objects in the early solar nebula. Efficient removal of residual Fe-alloy (5 vol.%) from silicate requires high-degree melting of silicate so that metal can segregate as droplets. Giant impacts during the final stage of accretion of large planetary objects could supply the energy required for high-degrees of melting. Alternatively, if initial metal segregation were delayed until a planetary object grew to large size (∼1000 km in diameter), release of gravitational potential energy due to metal segregation could contribute enough heat to form a magma ocean. 相似文献
16.
Open spaces in epithermal veins of the Bohemia mining district, Oregon, USA, filled with sediments during hydrothermal activity. These sediments consist mainly of chalcedony, rock fragments, and vein quartz fragments. In addition, hematite is deposited during stage three of the vein development. Observed sedimentary features include draping laminae, erosion surfaces, slumping, and graded bedding. Such sediments can be used for reconstruction of the original orientation of vein systems, because the sediment laminae are initially deposited horizontally. Vein sediments record variations in fluid flow due to self-sealing, fracturing, and cessation of hydrothermal activity. Investigation of vein sediments therefore provides an additional tool to unravel the geologic history of epithermal systems. The chalcedonic vein sediments record large temperature drops and highly silica supersaturated waters, probably due to fracturing and pressure release. Hematitic vein sediments indicate sulfide deficient hydrothermal fluids. 相似文献
17.
Akio Makishima Katsura Kobayashi Eizo Nakamura 《Geostandards and Geoanalytical Research》2002,26(1):41-51
A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br2, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO+, CaO+, TiO+, CrO+ and VO+, were separated from Cr+, Ni+, Cu+ and Zn+. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS. 相似文献
18.
Sato Minoru Oba Takashi Hosokawa Takao Yamaguchi Toshiyasu Nakano Toshiki Saito Tadao Muramoto Koji Kahara T akashi Funayama Katsura Kobayashi Akio Nakano Takahisa 《中国海洋大学学报(英文版)》2005,4(3):209-213
Brown alga ( Undaria pinnatifida) was treated with alginate lyase and hydrolyzed using 17 kinds of proteases and the inhibitory activity of the hydrolysates for the angiotensin-I-converting enzyme (ACE) was measured. Four hydrolysates with potent ACE-inhibitory activity were administered singly and orally to spontaneously hypertensive rats (SHRs). The systolic blood pressure of SHRs decreases significantly after single oral administration of the brown alga hydrolysates by pro- tease S ' Amano' (from Bacillus stearothermophilus) at the concentration of 10 (mg protein) (kg body weight)^ - 1. In the 17 weeks of feeding experiment, 7-week-old SHRs were fed standard diet supplemented with the brown alga hydrolysates for 10 weeks. In SHRs fed 1.0 and 0.1% brown alga hydrolysates, elevating of systolic bloodpressure was significantly suppressed for 7 weeks. To elucidate the active components, the brown alga hydrolysates were fractionated by 1-butanol extraction and HPLC on a reverse-phase column. Seven kinds of ACE-inhibitory peptides were isolated and identified by amino acid composition analysis, sequence analysis, and LC-MS with the results Val-Tyr, Ile-Tyr, Ala-Trp, Phe-Tyr, Val-Trp, Ile-Trp, and Leu-Trp. Each peptide was determined to have an antihypertensive effect after a single oral administration in SHRs. The brown alga hydrolysates were also confirmed to decrease the blood pressure in humans. 相似文献
19.
Daisuke Yamazaki Eiji Ito Yoshinori Tange Takashi Yoshino Shuangmeng Zhai Hiroshi Fukui Anton Shatskiy Tomoo Katsura Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2007,34(4):269-273
In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO3 were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between
the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure
in MgSiO3. 相似文献
20.
S. Ono E. Ito T. Katsura A. Yoneda M. J. Walter S. Urakawa W. Utsumi K. Funakoshi 《Physics and Chemistry of Minerals》2000,27(9):618-622
In situ synchrotron X-ray experiments in the system SnO2 were made at pressures of 4–29 GPa and temperatures of 300–1400 K using sintered diamond anvils in a 6–8 type high-pressure
apparatus. Orthorhombic phase (α-PbO2 structure) underwent a transition to a cubic phase (Pa3ˉ structure) at 18 GPa. This transition was observed at significantly lower pressures in DAC experiments. We obtained the
isothermal bulk modulus of cubic phase K
0 = 252(28) GPa and its pressure derivative K
′=3.5(2.2). The thermal expansion coefficient of cubic phase at 25 GPa up to 1300 K was determined from interpolation of the
P-V-T data obtained, and is 1.7(±0.7) × 10−5 K−1 at 25 GPa.
Received: 7 December 1999 / Accepted: 27 April 2000 相似文献