地质微生物地球化学作用的意义与展望     

张胜  张翠云  张云  李政红  张明 《地质通报》2005,(Z1)

概要论述了地质微生物学、地下水微生态学、微生物地球化学作用的基本概念、研究内容、研究现状、科学意义、关键问题、发展前景和在地下水环境保护中的作用。该研究领域不仅拓宽了整个地质科学的研究范畴,而且推动了地质科学的发展,具有一定的创新性。  相似文献   

Ab initio molecular orbital calculations for boron isotope fractionations on boric acids and borates   总被引：1，自引：0，他引：1  

Yun Liu  John A. Tossell 《Geochimica et cosmochimica acta》2005,69(16):3995-4006

Ab initio quantum chemistry calculations have been performed on the isotopic exchange reaction between B(OH)₃ and B(OH)₄⁻. Several calculation methods have been carefully compared and evaluated. The “water-droplet” method is chosen to investigate this isotope exchange reaction using cluster models with up to 34 water molecules surrounding the solute. HF/6-31G* level calculations coupled with a 0.920 scaling factor are used for the frequency calculations. A larger K value (1.027) is obtained from this study compared to the commonly used 1.0194 (Kakihana et al., 1977).The fractionations for several boric acid polymers and boron minerals are also studied. Our results suggest that assuming the BO₄ bonding in B(OH)₄⁻ is identical to that in borosilicates is wrong. Tetrahedral boron in silicates has a significantly smaller reduced isotopic partition function ratio (RPFR) and hence will be much isotopically lighter than in B(OH)₄⁻.The new theoretical curve of pH vs. δ¹¹B composition of B(OH)₄⁻ using our calculated 1.027 can be used to predict pH values for equilibrium cases such as incorporation into inorganic calcite. We also find that the shape of this curve is very sensitive to both K and pK_a value, giving the possibility of also predicting salinity from the different shapes of the curve.  相似文献   

Development of a soil moisture‐based distributed hydrologic model for determining hydrologically based critical source areas          下载免费PDF全文

Sisi Li  Margaret Gitau  David Bosch  Bernard A. Engel  Liang Zhang  Yun Du 《水文研究》2017,31(20):3543-3557

A simple grid cell‐based distributed hydrologic model was developed to provide spatial information on hydrologic components for determining hydrologically based critical source areas. The model represents the critical process (soil moisture variation) to run‐off generation accounting for both local and global water balance. In this way, it simulates both infiltration excess run‐off and saturation excess run‐off. The model was tested by multisite and multivariable evaluation on the 50‐km² Little River Experimental Watershed I in Georgia, U.S. and 2 smaller nested subwatersheds. Water balance, hydrograph, and soil moisture were simulated and compared to observed data. For streamflow calibration, the daily Nash‐Sutcliffe coefficient was 0.78 at the watershed outlet and 0.56 and 0.75 at the 2 nested subwatersheds. For the validation period, the Nash‐Sutcliffe coefficients were 0.79 at the watershed outlet and 0.85 and 0.83 at the 2 subwatersheds. The per cent bias was less than 15% for all sites. For soil moisture, the model also predicted the rising and declining trends at 4 of the 5 measurement sites. The spatial distribution of surface run‐off simulated by the model was mainly controlled by local characteristics (precipitation, soil properties, and land cover) on dry days and by global watershed characteristics (relative position within the watershed and hydrologic connectivity) on wet days when saturation excess run‐off was simulated. The spatial details of run‐off generation and travel time along flow paths provided by the model are helpful for watershed managers to further identify critical source areas of non‐point source pollution and develop best management practices.  相似文献   

海域使用权属数据质量控制系统设计          下载免费PDF全文

张建丽  张云  宋德瑞  王飞  景昕蒂 《海洋开发与管理》2018,35(11):14-18

海域使用权属数据是海域使用科学研究和海域综合管理决策制定的重要依据。文章分析了海域使用权属数据质量控制的现状,研究了海域使用权属问题数据质量控制的判别方法。设计了计算机与人工校验相结合的数据质量控制系统,实现海域使用权属数据系统化的质量控制和管理,为海域使用统计和海域使用管理决策支持提供参考。  相似文献   

Vortex-Induced Vibrations of A Long Flexible Cylinder in Linear and Exponential Shear Flows     

Gao  Yun  Yang  Bin  Zou  Li  Zong  Zhi  Zhang  Zhuang-zhuang 《中国海洋工程》2019,33(1):44-56

A numerical study based on a wake oscillator model was conducted to determine the response performance of vortex-induced vibration(VIV) on a long flexible cylinder with pinned-pinned boundary conditions subjected to linear and exponential shear flows. The coupling equations of a structural vibration model and wake oscillator model were solved using a standard central finite difference method of the second order. The VIV response characteristics including the structural displacement, structural frequency, structural wavenumber, standing wave behavior,travelling wave behavior, structural velocity, lift force coefficient and transferred energy from the fluid to the structure with different flow profiles were compared. The numerical results show that the VIV displacement is a combination of standing waves and travelling waves. For linear shear flow, standing waves and travelling waves dominate the VIV response within the low-velocity and high-velocity zones, respectively. The negative values of the transferred energy only occur within the low-velocity zone. However, for exponential shear flow, travelling waves dominate the VIV response and the negative energy occurs along the entire length of the cylinder.  相似文献   

Rare earth elements and yttrium in ferromanganese deposits from the South China Sea: distribution, composition and resource considerations     

ZHONG Yi  CHEN Zhong  GONZALEZ Francisco Javier  ZHENG Xufeng  LI Gang  LUO Yun  MO Aibin  XU Antao  WANG Shuhong 《海洋学报(英文版)》2018,37(7):41-54

Ferromanganese nodules and crusts contain relatively high concentration of rare earth elements(REE) and yttrium(REY),with a growing interest in exploitation as an alternative to land-based REY resources.On the basis of comprehensive geochemical approach,the abundance and distribution of REY in the ferromanganese nodules from the South China Sea are analyzed.The results indicate that the REY contents in ferromanganese deposits show a clear geographic regularity.Total REY contents range from 69.1×10~(–6) to 2 919.4×10~(–6),with an average value of 1 459.5×10~(–6).Especially,the enrichment rate of Ce content is high,accounting for almost 60% of the total REY.This REE enrichment is controlled mainly by the sorption of ferromanganese oxides and clay minerals in the nodules and crusts.Moreover,the total REY are higher in ferromanganese deposits of hydrogenous origin than of diagenetic origin.Finally,Light REE(LREE) and heavy REE(HREE) oxides of the ferromanganese deposits in the study area can be classified into four grades: non-enriched type,weakly enriched type,enriched type,and extremely enriched type.According to the classification criteria of rare earth resources,the Xisha and Zhongsha platform-central deep basin areas show a great potential for these rare earth metals.  相似文献   

Critical role of boreal summer North Pacific subtropical highs in ENSO transition     

Kyung-Sook Yun  Kyung-Ja Ha  Sang-Wook Yeh  Bin Wang  Baoqiang Xiang 《Climate Dynamics》2015,44(7-8):1979-1992

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南海开放共享航次关键科学问题的思考——从多尺度海洋动力学角度出发     

杜岩  陈举  经志友  王祥鹏  陈更新  徐驰  储小青  陈植武  徐杰  施震  唐世林  何云开  梁韵  施平 《热带海洋学报》2020,39(6):1-17

南海是西太平洋最大的边缘海, 通过一系列的海峡与西太平洋和印度洋相联通, 其不同时空尺度的海洋环流动力过程及其生态环境效应是南海区域海洋学研究的重要内容。自20世纪50年代末全国第一次海洋普查开始, 我国对海洋调查的支持力度不断加大, 以科学考察船为代表的海洋科学观测平台建设不断加强; 进入新千年以来, 国内海洋科考船依托的各主要研究所和院校本着开放的理念, 先后组织多单位联合进行海上观测。尤其是最近10年, 国家自然科学基金委员会支持实施了船时共享航次计划, 进一步促进了国内海洋界的交流和合作, 南海区域海洋学的相关研究取得了很多重要的成果。从多尺度环流动力学的角度出发, 本文简要回顾了南海海洋观测的发展历程, 并初步总结了近些年来南海关键科学问题的研究进展, 包括南海和西太平洋的水体交换过程、南海中小尺度过程、多尺度相互作用及其生态环境效应等; 并且在现有的研究基础上, 对未来南海的观测和科学问题提出若干思考与展望。  相似文献   

基于纵横波保幅分离的粘弹介质弹性波正演模拟     

侯志强  尹文笋  李键  孙永壮  刘云 《中国海洋大学学报(自然科学版)》2020,(1):82-92

地下介质往往表现为粘弹特性,研究基于粘弹假设的数值模拟方法对于正确认识地震波的传播规律和提高地震勘探精度具有重要意义。波动方程正演过程中纵横波的保幅解耦是研究准确的粘弹介质中地震波传播机理的前提,基于散度和旋度算子的纵横波解耦方法会使波场的相位和振幅产生畸变,且解耦后的波场在极性反转位置上无法与分离前混合波场各分量对应。在散度和旋度算子上再做一次梯度和旋度运算的波场分离方法虽然能够克服上述缺陷,但存在保幅性差等问题。本文从粘弹介质中的一阶速度-应力方程出发,推导了矢量纵横波分离的波数域表达式,结合有限差分思路给出了其在空间域的求解方法。本文方法利用纵横波的传播速度对现有的矢量波场分离方法进行振幅校正,并将校正结果分别作为纵波与横波对时间的二阶偏导,实现了粘弹介质中的纵横波分离。模型试算结果表明,本文方法能够克服现有方法的缺陷,获得更具保幅性的波场分离结果。  相似文献   

觉华岛国家级海洋公园生态保护数字化建设研究          下载免费PDF全文

刘明  樊楠  周志娟  张云  龚艳君 《海洋开发与管理》2020,37(12):67-70

为保护海洋生态环境和资源，文章从海洋公园建设角度概述觉华岛国家级海洋公园的开发与保护发展现状,分析存在的主要问题，并提出海洋公园的数字化发展对策。研究结果表明：觉华岛国家级海洋公园是典型的北方海岛生态保护区域，对促进环境保护与经济建设和谐发展具有重要作用；针对海洋公园当前在管理制度、监视监测技术、科技支撑能力和资金支持等方面的不足，应加强物联网监测体系建设、数字化评估建设、科研和人才建设以及生态保护和文化宣传。  相似文献