Raman spectroscopic analysis of cyanobacterial colonization of hydromagnesite, a putative martian extremophile     

Howell G.M. Edwards  Caroline D. Moody  Susana E. Jorge Villar  Michael J. Russell 《Icarus》2005,175(2):372-381

Raman spectra of an extremophile cyanobacterial colony in hydromagnesite from Lake Salda in Turkey have revealed a biogeological modification which is manifest as aragonite in the stratum associated with the colony. The presence of key spectral biomarkers of organic protectant molecules such as β-carotene and scytonemin indicate that the survival strategy of the cyanobacteria is significantly one of UV-radiation protection. The terrestrial location of this extremophile is worthy of consideration further because of its possible putative link with the “White Rock” formations in Sabaea Terra and Juventae Chasma on Mars.  相似文献   

The Indo-Australian monsoon and its relationship to ENSO and IOD in reanalysis data and the CMIP3/CMIP5 simulations     

Nicolas C. Jourdain  Alexander Sen Gupta  Andréa S. Taschetto  Caroline C. Ummenhofer  Aurel F. Moise  Karumuri Ashok 《Climate Dynamics》2013,41(11-12):3073-3102

A large spread exists in both Indian and Australian average monsoon rainfall and in their interannual variations diagnosed from various observational and reanalysis products. While the multi model mean monsoon rainfall from 59 models taking part in the Coupled Model Intercomparison Project (CMIP3 and CMIP5) fall within the observational uncertainty, considerable model spread exists. Rainfall seasonality is consistent across observations and reanalyses, but most CMIP models produce either a too peaked or a too flat seasonal cycle, with CMIP5 models generally performing better than CMIP3. Considering all North-Australia rainfall, most models reproduce the observed Australian monsoon-El Niño Southern Oscillation (ENSO) teleconnection, with the strength of the relationship dependent on the strength of the simulated ENSO. However, over the Maritime Continent, the simulated monsoon-ENSO connection is generally weaker than observed, depending on the ability of each model to realistically reproduce the ENSO signature in the Warm Pool region. A large part of this bias comes from the contribution of Papua, where moisture convergence seems to be particularly affected by this SST bias. The Indian summer monsoon-ENSO relationship is affected by overly persistent ENSO events in many CMIP models. Despite significant wind anomalies in the Indian Ocean related to Indian Ocean Dipole (IOD) events, the monsoon-IOD relationship remains relatively weak both in the observations and in the CMIP models. Based on model fidelity in reproducing realistic monsoon characteristics and ENSO teleconnections, we objectively select 12 “best” models to analyze projections in the rcp8.5 scenario. Eleven of these models are from the CMIP5 ensemble. In India and Australia, most of these models produce 5–20 % more monsoon rainfall over the second half of the twentieth century than during the late nineteenth century. By contrast, there is no clear model consensus over the Maritime Continent.  相似文献   

Relative sea‐level observations in western Scotland since the Last Glacial Maximum for testing models of glacial isostatic land movements and ice‐sheet reconstructions     

Ian Shennan  Sarah Hamilton  Caroline Hillier  Amanda Hunter  Ruth Woodall  Sarah Bradley  Glenn Milne  Anthony Brooks  Sophie Bassett 《第四纪科学杂志》2006,21(6):601-613

Observations of relative sea‐level change and local deglaciation in western Scotland provide critical constraints for modelling glacio‐isostatic rebound in northern Britain over the last 18 000 years. The longest records come from Skye, Arisaig and Knapdale with a shorter, Holocene, record from Kintail. Biostratigraphic (diatom, pollen, dinoflagellate, foraminifera and thecamoebian), lithological and radiocarbon analyses provide age and elevation parameters for each sea‐level index point. All four sites reveal relative sea‐level change that is highly non‐monotonic in time as the local vertical component of glacio‐isostatic rebound and eustasy (or global meltwater influx) dominate at different periods. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Spectroscopic follow-up of a cluster candidate at z= 1.45     

Caroline van Breukelen  Garret Cotter  Steve Rawlings  Tony Readhead  David Bonfield  Lee Clewley  Rob Ivison  Matt Jarvis  Chris Simpson  Mike Watson 《Monthly notices of the Royal Astronomical Society》2007,382(3):971-984

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Stopping inward planetary migration by a toroidal magnetic field     

Caroline E. J. M. L. J. Terquem 《Monthly notices of the Royal Astronomical Society》2003,341(4):1157-1173

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Fe–Mg Interdiffusion in (Mg,Fe)O     

Stephen Mackwell  Misha Bystricky  Caroline Sproni 《Physics and Chemistry of Minerals》2005,32(5-6):418-425

We have performed a series of interdiffusion experiments on magnesiowüstite samples at room pressure, temperatures from 1,320° to 1,400°C, and oxygen fugacities from 10^?1.0 Pa to 10^?4.3 Pa, using mixed CO/CO₂ or H₂/CO₂ gases. The interdiffusion couples were composed of a single-crystal of MgO lightly pressed against a single-crystal of (Mg_1-x Fe _x )_1-δO with 0.07<x<0.27. The interdiffusion coefficient was calculated using the Boltzmann–Matano analysis as a function of iron content, oxygen fugacity, temperature, and water fugacity. For the entire range of conditions tested and for compositions with 0.01<x<0.27, the interdiffusion coefficient varies as $$\tilde D\, =\,2.9\times10^{ - 6}\,f_{{\text{O}}_2 }^{0.19}\,x^{0.73}\,{\text{e}}^{ - (209,000\, -\,96,000\,x)/RT}\,\,{\text{m}}^{\text{2}} {\text{s}}^{ -1} $$ These dependencies on oxygen fugacity and composition are reasonably consistent with interdiffusion mediated by unassociated cation vacancies. For the limited range of water activity that could be investigated using mixed gases at room pressure, no effect of water on interdiffusion could be observed. The dependence of the interdiffusion coefficient on iron content decreased with increasing iron concentration at constant oxygen fugacity and temperature. There is a close agreement between our activation energy for interdiffusion extrapolated to zero iron content (x=0) and that of previous researchers who used electrical conductivity experiments to determine vacancy diffusivities in lightly doped MgO.  相似文献   

Incorporation of argon, krypton and xenon into clathrates on Mars     

Timothy D. Swindle  Caroline Thomas  Jonathan I. Lunine 《Icarus》2009,203(1):66-4032

Calculations of the trapping of heavy noble gases within multiple guest clathrates under Mars-like conditions show that a substantial fraction of the martian Xe, perhaps even the vast majority, could be in clathrates. In addition, the Xe/Kr ratio in the clathrates would probably be much higher than in the atmosphere, so the formation or dissociation of a relatively small amount of clathrate could measurably change the atmospheric ratio. Relatively crude (factor of 2) measurements of the seasonal variability in that ratio by in situ spacecraft would be sensitive to ∼10% of the seasonal atmospheric CO₂ variability being a result of clathrates, rather than pure CO₂ frost. In addition, sequestration of Xe in clathrates remains a viable mechanism for explaining the variable Xe/Kr ratios seen in different suites of martian meteorites.  相似文献   

Denitrification coupled to pyrite oxidation and changes in groundwater quality in a shallow sandy aquifer     

Yan-Chun Zhang  Caroline P. Slomp  Hilde F. Passier 《Geochimica et cosmochimica acta》2009,73(22):6716-6726

This study focuses on denitrification in a sandy aquifer using geochemical analyses of both sediment and groundwater, combined with groundwater age dating (³H/³He). The study sites are located underneath cultivated fields and an adjacent forested area at Oostrum, The Netherlands. Shallow groundwater in the region has high nitrate concentrations (up to 8 mM) due to intense fertilizer application. Nitrate removal from the groundwater below cultivated fields correlates with sulfate production, and the release of dissolved Fe²⁺ and pyrite-associated trace metals (e.g. As, Ni, Co and Zn). These results, and the presence of pyrite in the sediment matrix within the nitrate removal zone, indicate that denitrification coupled to pyrite oxidation is a major process in the aquifer. Significant nitrate loss coupled to sulfate production is further confirmed by comparing historical estimates of regional sulfate and nitrate loadings to age-dated groundwater sulfate and nitrate concentrations, for the period 1950-2000. However, the observed increases in sulfate concentration are about 50% lower than would be expected from complete oxidation of pyrite to sulfate, possibly due to the accumulation of intermediate oxidation state sulfur compounds, such as elemental sulfur. Pollutant concentrations (NO₃, Cl, As, Co and Ni) measured in the groundwater beneath the agricultural areas in 1996 and 2006 show systematic decreases most likely due to declining fertilizer use.  相似文献   

Numerical Simulation of a Solar Active Region. I: Bastille Day Flare     

Alain Vincent  Paul Charbonneau  Caroline Dubé 《Solar physics》2012,278(2):367-391

We present three-dimensional unsteady modeling and numerical simulations of a coronal active region, carried out within the compressible single-fluid MHD approximation. We focus on AR 9077 on 14 July 2000, and the triggering of the X5.7 GOES X-ray class “Bastille Day” flare. We simulate only the lower corona, although we include a virtual photosphere and chromosphere below. The boundary conditions at the base of this layer are set using temperature maps from line intensities and line-of-sight magnetograms (SOHO/MDI). From the latter, we generate vector magnetograms using the force-free approximation; these vector magnetograms are then used to produce the boundary condition on the velocity field using a minimum energy principle (Longcope, Astrophys. J. 612, 1181, 2004). The reconnection process is modeled through a dynamical hyper-resistivity which is activated when the current exceeds a critical value (Klimas et al., J. Geophys. Res. 109, 2218, 2004). Comparing the time series of X-ray fluxes recorded by GOES with modeled time series of various mean physical variables such as current density, Poynting energy flux, or radiative loss inside the active region, we can demonstrate that the model properly captures the evolution of an active region over a day and, in particular, is able to explain the initiation of the flare at the observed time.  相似文献   

Fracturing and fluid‐flow during post‐rift subsidence in carbonates of the Jandaíra Formation,Potiguar Basin,NE Brazil          下载免费PDF全文

Giovanni Bertotti  Kevin Bisdom  Brigit Oskam  Hubert B. Vonhof  Francisco H. R. Bezerra  Caroline L. Cazarin 《Basin Research》2017,29(6):836-853

Pervasive fracture networks are common in many reservoir‐scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates deposited during the early post‐rift stage of the Potiguar rift (NE Brazil). The Jandaíra Formation in the present onshore domain experienced <1.5 km thermal subsidence and, following Tertiary exhumation, forms outcrops over an area of >1000 km². The carbonates have a gentle, <5?, dip to the NE and are affected by few regional, low displacement faults or folds. Despite their simple tectonic history, carbonates display ubiquitous open fractures, sub‐vertical veins, and sub‐vertical as well as sub‐horizontal stylolites. Combining structural analysis, drone imaging, isotope studies and mathematical modelling, we reconstruct the fracturing history of the Jandaíra Formation during and following subsidence and analyse the impact fractures had on coeval fluid flow. We find that Jandaíra carbonates, fully cemented after early diagenesis, experienced negligible deformation during the first few hundreds of meters of subsidence but were pervasively fractured when they reached depths >400–500 m. Deformation was accommodated by a dense network of sub‐vertical mode I and hybrid fractures associated with sub‐vertical stylolites developed in a stress field characterised by a sub‐horizontal σ₁ and sub‐vertical σ₂. The development of a network of hybrid fractures, rarely reported in the literature, activated the circulation of waters charged in the mountainous region, flowing along the porous Açu sandstone underlying the Jandaíra carbonates and rising to the surface through the fractured carbonates. With persisting subsidence, carbonates reached depths of 800–900 m entering a depth interval characterised by a sub‐vertical σ₁. At this stage, sub‐horizontal stylolites developed liberating calcite which sealed the sub‐vertical open fractures transforming them in veins and preventing further flow. During Tertiary exhumation, several of the pre‐existing veins and stylolites opened and became longer, and new fractures were created typically with the same directions of the older features. The simplicity of our model suggests that most rocks in passive margin settings might have followed a similar evolution and thus display similar structures.  相似文献