Infrared spectroscopic taxonomy for carbonaceous chondrites from speciation of hydrous components     

Takahito OSAWA  Hiroyuki KAGI  Tomoki NAKAMURA  Takaaki NOGUCHI 《Meteoritics & planetary science》2005,40(1):71-86

Abstract— Mid‐infrared absorption spectra for all types of carbonaceous chondrites were obtained in this study to establish a versatile method for spectroscopic classification of carbonaceous chondrites. Infrared spectra were measured using a conventional KBr pellet method and diamond press method. Spectra of hydrous carbonaceous chondrites exhibit intense O‐H stretching vibrations. CI chondrites are identifiable by a characteristic sharp absorption band appearing at 3685 cm^?1, which is mainly attributable to serpentine. X‐ray diffraction analysis showed the presence of serpentine. However, Yamato (Y‐) 82162 (C1) does not have the band at 3685 cm^?1 because of its thermal metamorphism. CM and CR chondrites have an intense absorption band at approximately 3600 cm^?1. This absorption tends to appear in CM chondrites more strongly than CR chondrites because the intensity ratios of an OH stretching mode at 3520 cm^?1 compared to 3400 cm^?1 for CM chondrites are in the range of 0.95–1.04, which is systematically higher than those of CR chondrites (0.86–0.88). Therefore, the two types of chondrites are distinguishable by their respective infrared spectra. The spectrum feature of the Tagish Lake meteorite is attributable to neither CI nor CM chondrites. CO chondrites are characterized by weak and broad absorption at 3400 cm^?1. CV chondrites have weak or negligible absorption of water. CK chondrites also have no water‐induced absorption. CH and CB chondrites have a sharp absorption at 3692 cm^?1 indicating the presence of chrysotile, which is also supported by observations of X‐ray diffraction and TEM. The combination of spectroscopic classification and the diamond press method allows classification of carbonaceous chondrites of very valuable samples with small quantities. As one example, carbonaceous chondrite clasts in brecciated meteorites were classified using our technique. Infrared spectra for a fragment of carbonaceous clasts (<1 μg) separated from Willard (b) and Tsukuba were measured. The 3685 cm^?1 band found in CI chondrites was clearly detected in the clasts, indicating that they are CI‐like clasts.  相似文献   

XMM–Newton observations of UW CrB: detection of X-ray bursts and evidence for accretion disc evolution     

Pasi Hakala  Gavin Ramsay  Panu Muhli  Phil Charles  Diana Hannikainen  Koji Mukai  Osmi Vilhu 《Monthly notices of the Royal Astronomical Society》2005,356(3):1133-1138

UW CrB (MS 1603+2600) is a peculiar short-period X-ray binary that exhibits extraordinary optical behaviour. The shape of the optical light curve of the system changes drastically from night to night, without any changes in overall brightness. Here we report X-ray observations of UW CrB obtained with XMM–Newton . We find evidence for several X-ray bursts, confirming a neutron star primary. This considerably strengthens the case that UW CrB is an accretion disc corona system located at a distance of at least 5–7 kpc (3–5 kpc above the Galactic plane). The X-ray and Optical Monitor (ultraviolet–optical) light curves show remarkable shape variation from one observing run to another, which we suggest are due to large-scale variations in the accretion disc shape resulting from a warp that periodically obscures the optical and soft X-ray emission. This is also supported by the changes in phase-resolved X-ray spectra.  相似文献   

Heating effects of the matrix of experimentally shocked Murchison CM chondrite: Comparison with micrometeorites     

Naotaka TOMIOKA  Kazushige TOMEOKA  Keiko NAKAMURA‐MESSENGER  Toshimori SEKINE 《Meteoritics & planetary science》2007,42(1):19-30

Abstract— Micrometeorites have been significantly altered or melted by heating, which has been mainly ascribed to aerodynamic drag during atmospheric entry. However, if a major fraction of micrometeorites are produced by impacts on porous asteroids, they may have experienced shock heating before contact with the Earth's atmosphere (Tomeoka et al. 2003). A transmission electron microscope (TEM) study of the matrix of Murchison CM chondrite experimentally shocked at pressures of 10–49 GPa shows that its mineralogy and texture change dramatically, mainly due to shock heating, with the progressive shock pressures. Tochilinite is completely decomposed to an amorphous material at 10 GPa. Fe‐Mg serpentine is partially decomposed and decreases in amount with increasing pressure from 10 to 30 GPa and is completely decomposed at 36 GPa. At 49 GPa, the matrix is extensively melted and consists mostly of aggregates of equigranular grains of Fe‐rich olivine and less abundant low‐Ca pyroxene embedded in Si‐rich glass. The mineralogy and texture of the shocked samples are similar to those of some types of micrometeorites. In particular, the samples shocked at 10 and 21 GPa are similar to the phyllosilicate (serpentine)‐rich micrometeorites, and the sample shocked at 49 GPa is similar to the olivine‐rich micrometeorites. The shock heating effects also resemble the effects of pulse‐heating experiments on the CI and CM chondrite matrices that were conducted to simulate atmospheric entry heating. We suggest that micrometeorites derived from porous asteroids are likely to go through both shock and atmospheric‐entry heating processes.  相似文献   

X-ray observations of 4 Draconis: symbiotic binary or cataclysmic triple?     

Peter J. Wheatley  Koji Mukai †  Domitilla de Martino 《Monthly notices of the Royal Astronomical Society》2003,346(3):855-860

We present the first X-ray observations of the 4 Draconis system, consisting of an M3 III giant with a hot ultraviolet companion. It has been claimed that the companion is itself an AM Her-type binary system, an identification that places strong constraints on the evolution of cataclysmic variables. We find that the X-ray properties of 4 Draconis are consistent with the presence of an accreting white dwarf, but not consistent with the presence of an AM Her system. We conclude that 4 Draconis is therefore most likely a symbiotic binary containing a white dwarf accreting material from the wind of the red giant.
The X-ray spectrum of 4 Draconis is sometimes dominated by partially ionized photoelectric absorption, presumably due to the wind of the red giant. We note that X-ray monitoring of such systems would provide a powerful probe of the wind and mass-loss rate of the giant, and would allow a detailed test of wind accretion models.  相似文献   

A 35 kyr record of organic matter composition and δ13C of n-alkanes in bog sediments close to Lake Baikal: Implications for paleoenvironmental studies     

Ryoshi Ishiwatari  Naoki Fujino  David Brincat  Shuichi Yamamoto  Hikaru Takahara  Koji Shichi  Sergey K. Krivonogov 《Organic Geochemistry》2009,40(1):51-60

We characterized the compositions of organic compounds in a Cheremushka bog sediment core (deposited over the last 35 kyr), located at the eastern coast of Lake Baikal, to obtain basic information about the terrestrial organic matter (OM) which contributed to Lake Baikal sediments. The bog sediment was analyzed for the molecular composition of n-alkanes, lignin phenols and n-C₂₄ to C₃₀ alkanoic acids, as well as the carbon isotopic composition of plant wax derived n-C₂₇ to C₃₃ alkanes.Concentrations of lignin phenols [vanillyl (V) plus syringyl (S) phenols] normalized to total organic carbon (TOC) in the Holocene are twice those for the last glacial maximum (LGM), while concentrations of TOC-normalized n-C₂₄ to C₃₀ alkanoic acids do not change markedly in this period. Thus, the ratio of lignin phenols to n-C₂₄ to C₃₀ alkanoic acids increases from the LGM to the Holocene. This result is essentially consistent with pollen analysis indicating an expansion of woody plants in the Holocene and a prevailing herb-abundant environment for the LGM. The δ¹³C values of n-C₂₇ to C₃₃ alkanes (e.g. ?29‰ to ?33‰ for C₃₁) indicate the presence of C₃-dominant plants throughout the core.The contribution of terrestrial OM to Lake Baikal sediments was estimated using the biomarkers, on the assumption that the OM in the bog sediments is a representative of the terrestrial OM around the lake. Hence, the estimation using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters indicates that 11–24% of the TOC in the Academician Ridge sediments is land-derived for both the Holocene and the LGM, which is similar to the estimates from C/N values of bulk OM. However, the estimates for terrestrial OM using the n-C₂₇ to C₃₃ alkane parameter are generally higher than those using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters. The difference is thought to be associated with the difference in source and behavior of these biomarkers.  相似文献   

Long-term precipitation and stream discharge records at seven forested experimental watersheds along a latitudinal transect in Japan: Jozankei,Kamabuchi, Takaragawa,Tsukuba, Tatsunokuchi-yama,Kahoku and Sarukawa     

Takanori Shimizu  Koji Tamai  Ikuhiro Hosoda  Shoji Noguchi  Yuji Kominami  Toshio Abe  Kenzo Kitamura  Ushio Kurokawa  Delphis F. Levia  Tayoko Kubota  Naoki Kabeya  Shin'ichi Iida  Tatsuhiko Nobuhiro  Shinji Sawano  Sho Iwagami  Akira Shimizu  Yoshio Tsuboyama 《水文研究》2021,35(10):e14376

This data note introduces a database of long-term daily total precipitation and stream discharge data for seven forested watersheds in Japan that have been continuously monitored by the Forestry and Forest Products Research Institute. Three of the watersheds started data collection in the 1930s. Forest cover across the sites ranges from cool to warm temperate regions with the latitude spanning from 31 to 44° N and annual precipitation ranging from 1200 to 3000 mm yr⁻¹. The effects of vegetation change via clearcutting, thinning and forest fire (among other stressors) on stream discharge can be analysed from the long-term observation sites. Moreover, this multi-site dataset allows for inter- and intra-site comparisons of annual water loss (difference of annual precipitation and stream discharge). These long-term datasets can provide comprehensive insights into the effects of climate change and other stressors on forested ecosystems, not only in Japan but across a spectrum of forest types, if combined with other long-term records from other forested watersheds across the world.  相似文献   

The interanual rainfall variability in Indonesia corresponding to El Niño Southern Oscillation and Indian Ocean Dipole     

Hendrawan I Gede  Asai Koji  Triwahyuni Andhit  Lestari Diah Valentina 《海洋学报(英文版)》2019,38(7):57-66

The Impact of the Indian Ocean Dipole(IOD) and the El Ni?o Southern Oscillation(ENSO) event for Indonesian rainfall has been investigated for the period from 1950 to 2011. Inter-annual change of IOD and ENSO indices are used to investigate their relationship with Indonesian rainfall. By using the wavelet transform method, we found a positive significant correlation between IOD and Indonesian rainfall on the time scale of nearly 2.5–4 years.Furthermore, the positive significant correlation between ENSO(sea surface temperature anomaly at Ni?o3.4 area indices) and Indonesian rainfall exists for shorter than 2 years and between 5.5 to 6.5-year time scales.  相似文献   

Short term variability of Particle fluxes and its relation to variability in sea surface temperature and chlorophylla field detected by Ocean Color and Temperature Scanner (OCTS) off Sanriku, northwestern North Pacific in the spring of 1997     

Toshiro Saino  Shaoling Shang  Yoshihisa Mino  Koji Suzuki  Hideaki Nomura  Sei-ichi Saitoh  Hideo Miyake  Toshiyuki Masuzawa  Koh Harada 《Journal of Oceanography》1998,54(5):583-592

A sediment trap experiment was carried out in conjunction with an over flight of Ocean Color Temperature Scanner (OCTS) on board Advanced Earth Observing Satellite (ADEOS) at 40°N, 143°E off Sanriku in April to May 1997. Short term variability of particle fluxes was examined at depths of 450 m and 600 m from April 6 to May 1 with a sampling interval of two days, and at 450 m with one day interval from 2nd to 10th May. Daily averaged mass flux at 450 m and 600 m was 815 mg m⁻²d⁻¹ and 862 mg m⁻²d⁻¹, respectively. A sharp increase in mass flux was observed during the period from April 26 to April 29 with the highest mass flux of 8 g m⁻²d⁻¹. About 85% of the total mass flux for the entire duration (26 days) was collected within these 4 days. Trapped material during the peak flux period was mainly composed of diatoms dominated byThalassiosira spp. and resting spores ofChaetoceros spp. This suggested that the peak flux was the result of (a) diatom bloom(s) in the euphotic column. Current meter records at 420 m showed that on April 26 and 27, the period when the peak flux was observed, the southwestward current had diminished in strength and changed its direction northwestward. Low current speeds appeared to have enhanced trap efficiency to help form the peak flux. A time series of OCTS Intensive-LAC (Local Area Coverage: Region B) images from mid-March to early May was examined todetect phytoplankton bloom(s). In the March 26th Chl image, high concentration region was restricted to the southwest off Cape Erimo, but spread around the warm core ring (WCR) 93A by April 10. East of the WCR93A, high Chl concentration remained steady until May, but to the west of the WCR93A, Chl decreased rapidly before the 19th of April. From this observation we suspect that the peak flux observed at the end of April originated from a bloom, which ceased on the 17th or 18th of April, in the region north of 40°N and west of 143°E. Taking the current meter records into account, the source region for the trapped material is most likely around southwest of the Cape Erimo.  相似文献   

Chlorophyll-specific absorption coefficients and pigments of phytoplankton off Sanriku, northwestern North Pacific   总被引：4，自引：0，他引：4  

Koji Suzuki  Motoaki Kishino  Kousei Sasaoka  Sei-Ichi Saitoh  Toshiro Saino 《Journal of Oceanography》1998,54(5):517-526

The variety in shape and magnitude of thein vivo chlorophyll-specific absorption spectra of phytoplankton was investigated in relation to differences in pigment composition off Sanriku, northwestern North Pacific. Site-to-site variations of the absorption coefficients,a _ph ^* (λ), and pigment composition were clearly observed. At warm-streamer stations, higher values ofa _ph ^* (440) anda _ph ^* (650) were found with relatively high concentrations of chlorophyllb (a green algae marker). At stations located in the Oyashio water (cold streamer),a _ph ^* (440) values were lower and fucoxanthin (a diatom marker) concentrations were higher, compared to the other stations. The peak in the absorption spectra at the Oyashio stations was shifted toward shorter wavelengths, which was probably due to the presence of phaeopigments. In a Kuroshio warm-core ring, the magnitude ofa _ph ^* (440) was in between those at the warm-streamer and Oyashio stations, and the diagnostic pigment was peridinin (a dinoflagellate marker). These findings indicated that major differences in phytoplankton absorption spectra of each water mass were a result of differences in the phytoplankton pigment composition of each water mass, which was probably related to the phytoplankton community.  相似文献   

Post‐depositional alteration of shallow‐marine tsunami‐induced sand layers: A comparison of recent and ancient tsunami deposits,Onagawa Bay,northeastern Japan          下载免费PDF全文

Koji Seike  Genki Kobayashi  Kazuhiro Kogure 《Island Arc》2017,26(2)

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