Field Tracer Tests to Evaluate Transport Properties of Tryptophan and Humic Acid in Karst     

Simon Frank  Nadine Goeppert  Nico Goldscheider 《Ground water》2021,59(1):59-70

The monitoring of water quality, especially of karst springs, requires methods for rapidly estimating and quantifying parameters that indicate contamination. In the last few years, fluorescence-based measurements of tryptophan and humic acid have become a promising tool to assess water quality in near real-time. In this study, we conducted comparative tracer tests in a karst experimental site to investigate the transport properties and behavior of tryptophan and humic acid in a natural karst aquifer. These two tracers were compared with the conservative tracer uranine. Fluorescence measurements were conducted with an online field fluorometer and in the laboratory. The obtained breakthrough curves (BTCs) and the modeling results demonstrate that (1) the online field fluorometer is suitable for real-time fluorescence measurements of all three tracers; (2) the transport parameters obtained for uranine, tryptophan, and humic acid are comparable in the fast flow areas of the karst system; (3) the transport velocities of humic acid are slower and the resulting residence times are accordingly higher, compared to uranine and tryptophan, in the slower and longer flow paths; (4) the obtained BTCs reveal additional information about the investigated karst system. As a conclusion, the experiments show that the transport properties of tryptophan are similar to those of uranine while humic acid is partly transported slower and with retardation. These findings allow a better and quantitative interpretation of the results when these substances are used as natural fecal and contamination indicators.  相似文献   

Improved understanding of dynamic water and mass budgets of high-alpine karst systems obtained from studying a well-defined catchment area     

Simon Frank  Nadine Goeppert  Nico Goldscheider 《水文研究》2021,35(4):e14033

Large areas of Europe, especially in the Alps, are covered by carbonate rocks and in many alpine regions, karst springs are important sources for drinking water supply. Because of their high variability and heterogeneity, the understanding of the hydrogeological functioning of karst aquifers is of particular importance for their protection and utilisation. Climate change and heavy rainfall events are major challenges in managing alpine karst aquifers which possess an enormous potential for future drinking water supply. In this study, we present research from a high-alpine karst system in the UNESCO Biosphere Reserve Großes Walsertal in Austria, which has a clearly defined catchment and is drained by only one spring system. Results show that (a) the investigated system is a highly dynamic karst aquifer with distinct reactions to rainfall events in discharge and electrical conductivity; (b) the estimated transient atmospheric CO₂ sink is about 270 t/a; (c) the calculated carbonate rock denudation rate is between 23 and 47 mm/1000a and (d) the rainfall-discharge behaviour and the internal flow dynamics can be successfully simulated using the modelling package KarstMod. The modelling results indicate the relevance of matrix storage in determining the discharge behaviour of the spring, particularly during low-flow periods. This research and the consequent results can contribute and initiate a better understanding and management of alpine karst aquifers considering climate change with more heavy rainfall events and also longer dry periods.  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

A conversation with Werner Käss (Germany) about his contributions to tracer hydrogeology and characterisation of mineral waters and spas     

Nico Goldscheider  Nadine Goeppert 《Hydrogeology Journal》2009,17(6):1543-1546

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Atomic structures and energies of grain boundaries in Mg2SiO4 forsterite from atomistic modeling     

Omar Adjaoud  Katharina Marquardt  Sandro Jahn 《Physics and Chemistry of Minerals》2012,39(9):749-760

Grain boundaries influence many physical and chemical properties of crystalline materials. Here, we perform molecular dynamics simulations to study the structure of a series of [100] symmetric tilt grain boundaries in Mg₂SiO₄ forsterite. The present results show that grain boundary energies depend significantly on misorientation angle. For small misorientation angles (up to 22°), grain boundary structures consist of an array of partial edge dislocations with Burgers vector $\frac{1}{2}[001]$ associated with stacking faults and their energies can be readily fit with a model which adds the Peach-Koehler equation to the Read-Shockley dislocation model for grain boundaries. The core radius of partial dislocations and the spacing between the partials derived from grain boundary energies show that the transition from low- to high-angle grain boundaries occurs for a misorientation angle between 22° and 32°. For high misorientation angles (32.1° and 60.8°), the cores of dislocations overlap and form repeated structural units. Finally, we use a low energy atomic configuration obtained by molecular dynamics for the misorientation of 12.18° as input to simulate a high-resolution transmission electron microscopy (HRTEM) image. The simulated image is in good agreement with an observed HRTEM image, which indicates the power of the present approach to predict realistic atomic structures of grain boundaries in complex silicates.  相似文献   

Grain boundary and volume diffusion experiments in yttrium aluminium garnet bicrystals at 1,723 K: a miniaturized study     

Katharina?Marquardt  Elena?Petrishcheva  Emmanuel?Gardés  Richard?Wirth  Rainer?Abart  Wilhelm?Heinrich 《Contributions to Mineralogy and Petrology》2011,162(4):739-749

Yb-Y inter-diffusion along a single grain boundary of a synthetic yttrium aluminium garnet (YAG) bicrystal has been studied using analytical transmission electron microscopy (ATEM). To investigate the diffusion, a thin-film containing Yb as the diffusant was deposited perpendicular to the bicrystal grain boundary by pulsed laser deposition (PLD). Structural properties and their change with time in both the diffusant source and the grain boundary are reported. The diffusion profiles are incorporated in a numerical diffusion model, which is applied to determine the grain boundary diffusion coefficient, D _gb , at 1.723 K it is equal to 3 × 10⁻¹⁵ m²/s. We find that grain boundary diffusion is 4.85 orders of magnitude faster than volume diffusion, which was determined from the same diffusion experiment. This result is discussed in the context of special versus general grain boundaries. Finally, we successfully tested the capability of synchrotron-based nano-X-ray fluorescence analysis to map micro-chemical patterns in two dimensions with sub-micrometre resolution.  相似文献   

IFKIS-Hydro: an early warning and information system for floods and debris flows     

Hans Romang  Massimiliano Zappa  Nadine Hilker  Matthias Gerber  François Dufour  Valérie Frede  Dominique Bérod  Matthias Oplatka  Christoph Hegg  Jakob Rhyner 《Natural Hazards》2011,56(2):509-527

IFKIS-Hydro is an information and warning system for hydrological hazards in small- and medium-scale catchments. The system collects data such as weather forecasts, precipitation measurements, water level gauges, discharge simulations and local observations of event-specific phenomena. In addition, IFKIS-Hydro incorporates a web-based information platform, which serves as a central hub for the submission and overview of data. Special emphasis is given to local information. This is accomplished particularly by human observers. In medium-scale catchments, discharge forecast models have an increasing importance in providing valuable information. IFKIS-Hydro was developed in several test regions in Switzerland and the first results of its application are available now. The system is constantly extended to additional regions and may become the standard for warning systems in smaller catchments in Switzerland.  相似文献   

The international atlas of Mars exploration: The first five decades,by Philip J. Stooke. Cambridge University Press, 2012, $140, hardback,ISBN:9780521765534.     

Nadine G. Barlow 《Meteoritics & planetary science》2013,48(2):318-319

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Identification of maars and similar volcanic landforms in the West Eifel Volcanic Field through image processing of DTM data: efficiency of different methods depending on preservation state     

Nadine Seib  Jonas Kley  Georg Büchel 《International Journal of Earth Sciences》2013,102(3):875-901

The West Eifel Volcanic Field comprises 98 maars, tuff rings, and scoria rings of volcanoes younger than 700 ka. Digital Terrain Models (DTMs) allow to automatically measure morphologic parameters of volcanic edifices such as slope angles, diameters, elevations, floor, and slope surface areas. Based on their morphological characteristics, we subdivided the West Eifel volcanoes into five morphometric groups which reflect different stages of erosion. Group I, II, and IV comprise clear ring-shaped structures. The difference between these groups is that a tephra ring is well preserved in Group I, partially preserved in Group II and absent in Group IV. The original shapes of Group III maars have been lost more substantially than in Groups I, II, or IV, but they nevertheless retain a negative shape (a depression) and have characteristic channel systems, which can be used as search criteria. Maar-diatremes of Group V are eroded down to their feeder pipes and form hills. In order to locate potential volcanic depressions that are likely to be maar volcanoes, we defined common search criteria such as circular negative landforms or particular drainage system patterns for all groups except the least well-preserved Group V. These criteria were taken as the basis for further processing of the DTM data. The first processing step consisted of constructing a residual relief calculated as the difference between a filtered (smoothed) topographic surface and the original DTM data. This identifies local topographic features. We propose a method for regulating the degree of smoothing which is based on filtering of local maxima according to their distance from a surface constructed from local minima. The previously defined search criteria for Groups I to IV such as specific ranges of curvature, slope, circularity, density of the drainage network were then applied to the residual relief in order to extract maar shapes. Not all criteria work equally well for all morphological groups. Combinations of multiple search criteria therefore yield the best results and efficiently identify most known maars. They also separate some probable new, hitherto unrecognized maars from a large number of other local depressions. We also compared the erosional state of maars to their absolute ages. Published estimates of erosion rates for maars in the French Massif Central suggest a general trend of erosion rates decreasing with time elapsed since eruption. However, this cannot explain the strongly varying ages for maars of the same morphometric group (i.e., similar preservation state) in the West Eifel Volcanic Field. The spatial distribution of the morphometric groups shows some regularity. For example, strongly eroded maars are concentrated in the Gerolstein area (where maar density is highest), whereas most well-preserved maars are located east of the Eifel North–South Depression (ENSD). Most maars affected by fluvial erosion lie near the Kyll and Kleine Kyll streams. These observations suggest differential recent uplift of the West Eifel Volcanic Field, with stronger uplift occurring west of the ENSD.  相似文献   

Greater India Basin Hypothesis and A Two-Stage Cenozoic Collision Between India and Asia     

Douwe VAN HINSBERGEN  Lippert Peter  Dupont-Nivet Guillaume  McQuarrie Nadine  Doubrovine Pavel  Spakman Wim  Torsvik Trond 《《地质学报》英文版》2013,87(Z1):15-15

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