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Magnesian skarn-type tin deposits are relatively rare in the world. The Hehuaping cassiterite-sulfide deposit in southern China, having a total reserve of approximately 130,000 t of tin, 50,000 t of lead and 10,000 t of zinc, is identified as such type. The deposit is related to the Late Jurassic (157 Ma) Hehuaping medium- to coarse-grained biotite granite that intruded the Middle Devonian Qiziqiao dolomite Formation and the Tiaomajian sandstone Formation. Four paragenetic stages of skarn and ore formation have been recognized: I. prograde stage, II. retrograde stage, III. cassiterite-sulfide stage and IV. carbonate stage. Alteration zoning between fresh granite and unaltered country rocks can be identified. The skarn are typified by Mg-mineral assemblages of forsterite, spinel, diopside, tremolite, serpentine, talc, and phlogopite. The geochemistry of various skarn minerals shows a gradually decrease of Mg end member and, correspondingly, an increase of Fe- and especially Mn end members along the process of skarn alteration.Tin mineralization developed during the late retrograde stage resulted in cassiterite–magnetite-diopside skarn. However, the deposition of cassiterite occurred predominantly as cassiterite-sulfide veins along fractures and interlayer fracture zones during stage III. The petrogeochemistry of Hehuaping granite, as well as S- and Pb isotopic analyses suggest that the ore-forming elements have a magmatic source originated from the upper crust. The HO isotopic and fluid-inclusion analyses indicate that high-temperature ore-forming fluids in early anhydrous skarn stage (stage I) are also magmatic origin. In comparison, the retrograde fluids are characterized by relatively low salinity (2 to 10 wt.% NaCl equiv) and low temperature (220 to 300 °C), suggesting a mixed origin of meteoric waters with magmatic fluids. The major ore-forming stage III fluids are characterized by lower temperature (170 to 240 °C) and salinity (1 to 6 wt.% NaCl equiv), indicating fluid mixing could be an efficient tin-mineralizing mechanism. Meteoric waters are dominant in stage IV, resulting in a further lowering of temperature (130 to 200 °C) and salinity (0.4 to 1 wt.% NaCl equiv). 相似文献
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石棉纤维粉煤灰水泥加固软土试验研究 总被引：1，自引：0，他引：1
为研究石棉纤维加固软土的效果和机理,改善水泥土的脆性破坏特点,提出将石棉纤维的物理加筋作用与水泥、粉煤灰的化学加固作用相结合,通过对不同纤维掺量(0%~9%)的石棉纤维粉煤水泥复合土进行直剪试验、无侧限抗压强度试验、劈裂试验、扫描电镜试验,进而对石棉纤维加筋水泥土的强度性质和影响机理进行探讨。研究表明,石棉纤维配合水泥与粉煤灰能显著提高软土的强度和稳定性,改善水泥土的破坏形式。水泥粉煤灰配比一定时,石棉纤维增强水泥复合土各强度指标值存在最优掺量,纤维添加量在3%~6%之间,石棉纤维的加筋效果在水泥土中能得到很好的发挥,超过最优掺量则会降低复合土的强度值。 相似文献
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Gejiu is geographically located near Gejiu city, SW China. It is one of the largest tin-polymetallic districts in the world and contains approximately 3 million tons (Mt) of Sn and smaller quantities of Cu, Pb, and Zn. The deposit primarily yields three different types of ore: skarn-hosted ore, basalt-hosted stratiform ore, and carbonate-hosted stratiform ore. Kafang is one of the primary ore deposits in the Gejiu district and is an unusual occurrence hosted in basaltic rocks. Genetic models of the Kafang deposit suggest that it is related either to Anisian (Lower stage of Middle Triassic) Gejiu basalts or to Cretaceous Gejiu granite. In this study, we performed zircon SIMS U–Pb dating, major and trace element analyses, and Sr–Nd–Pb isotopic analyses for the Gejiu basalts and S isotopic analyses for stratiform Cu ore. Our results and previous studies are used to interpret the petrogenesis of the Gejiu basalts and the origin of the basalt-hosted stratiform Cu deposit. The SIMS zircon U–Pb analyses of the Gejiu basalts yield an age of 244.4 Ma. The trace element ratios of the Gejiu basalts are similar to those of ocean island basalt and have positive εNd(t) values (ranging from 0.6 to 2.5) and uniform (87Sr/86Sr)i values (ranging from 0.70424 to 0.70488). These ratios are close to those of the Permian Emeishan flood basalt. Thus, the Gejiu basalts may represent coeval volcanisms within the plate involving remelting of the Emeishan plume head through a stress relaxation process after the main plume event. The Pb and S isotopic compositions of the Gejiu basalts and the stratiform Cu ores indicate that the source of Cu and S is primarily derived from the Gejiu basalts. However, the age of sulfide mineralization (84.2–79.6 Ma) and the age of hydrothermal alteration (85.5–81.9 Ma) are temporally consistent with the age of the Cretaceous granite emplacement (85.5–83.3 Ma). From a petrological and geochemical study, we determine that the Gejiu basalts may have been subjected to pervasive granite-related hydrothermal alteration during the emplacement of granite. These processes increase the K and Mg contents of basalt and probably caused the formation of the Cu ores. Thus, the Kafang stratiform Cu deposit can be considered as a granite-related hydrothermal deposit. 相似文献
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《Applied Geochemistry》1993,8(6):529-549
Changes in the distribution of inorganic solutes in a shallow ground water contaminated by crude oil document a series of geochemical reactions initiated by biodegradation of the oil. Upgradient of an oil body floating on the water table, oxidation of oil to carbonic acid dissolves carbonate minerals in the aquifer matrix. In this oxidized zone pH is depressed ∼1 pH unit, and the concentrations of Ca, Mg and HCO3− increase to more than twice that of the native ground water. In the anoxic zone beneath the oil body concentrations of dissolved SiO2, Sr, K, Fe and Mn increase significantly. Here, Fe is mobilized by microbial reduction, pH is buffered by the carbonate system, and silicates weather via hydrolysis and organic-acid-enhanced dissolution. Farther down-gradient the ground water is reoxygenated and Fe precipitates from solution, possibly as iron hydroxide or iron carbonates, while SiO2 precipitates as amorphous silica. Other solutes, such as Mg, are transported more conservatively down-gradient where contaminated and native ground water mix.The observed changes in inorganic aqueous chemistry document changes in water-mineral interactions caused by the presence of an organic contaminant. These organic-initiated interactions are likely present in many contaminated aquifers and may be analogous to interactions occurring in other organic-rich natural waters. 相似文献
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控制路基沉降是公路工程中的一个关键技术问题,而路基沉降与其影响因素之间存在着线性、非线性关系。当输入自变量较多时,用传统神经网络建模容易出现过拟合现象,导致网络模型预测精度较低。针对此问题,本文用遗传算法对神经网络模型的权值和阈值进行优化,同时讨论遗传参数的设定对输出结果的影响。通过对成南高速的实测数据进行仿真,试验结果表明:优化后的BP神经网络具有较高的预测精度,预测效果明显优于传统神经网络模型的输出结果,该预测方法可作为高速公路路基长期沉降预测的一种有效辅助手段。 相似文献
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多块体形状堆石体碾压颗粒破碎数值模拟 总被引：1，自引：0，他引：1
通过6种典型堆石块体的形状近似,分别采用两种接触本构模型建立了多块体形状堆石体离散元数值模型,研究堆石体在碾压荷载作用下的颗粒破碎过程,建立颗粒破碎的量化计算方法,分析碾压前、后堆石级配曲线的变化,讨论接触本构模型和颗粒形状对块体破碎的影响。模拟结果显示,碾压荷载下堆石颗粒以张拉破碎为主,随着碾压遍数的增加,局部开始出现剪切破碎;提出的颗粒破碎量化计算方法,在大粒径范围对粒径变化幅度预测偏大,但级配曲线整体趋势与实测结果比较吻合;相比较于接触连接模型,平行连接模型与现场碾压试验结果更接近。6种块体形状的数值结果显示,随着形状系数的增加,在其他条件不变的情况下颗粒破碎率逐渐降低,其中类长方形块体在碾压荷载作用下颗粒破碎最明显。相比较于纯圆颗粒或者单一非圆颗粒,采用的6种颗粒形状建立的堆石体振动碾压离散元模型,更接近现场实际情况。 相似文献
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总结了超前地质预报的作用和发展现状,分析了超前地质预报认识上的误区和各种探测设备存在的问题。提出了超前地质预报系统的概念,阐述了隧道所在地区地质分析技术、隧道不良地质体超前预报技术、重大施工地质灾害临近警报技术包含的内容。系统的工作步骤为,利用地质分析技术结论以及地质复杂程度分级标准对探测区段的围岩进行地质复杂程度分级,针对不同级别的地质复杂程度,制定与其对应的超前地质预报系统方案,并注意现场工作中动态控制的应用。以厦门海底隧道F3风化深槽为例,对超前地质预报系统的内容及工作步骤进行了应用。提出了超前地质预报系统的发展方向。研究旨在完善超前地质预报工作,使超前地质预报结果在现场施工过程中能真正起到指导性的作用,最大程度地减少地质灾害造成的人员伤亡和财产损失 相似文献
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京石客运专线石家庄明挖隧道工程与既有京广铁路线近距离并行长达5 km,为了摸清列车动载对桩锚支护结构的影响,以及不同锚固形式对动载的响应特点,特在该隧道设立压力分散型锚索试验段,与现场普遍采用的拉力集中型锚索锚固段相对照,进行长期应力、应变量测。在此基础上,对实测数据进行了系统的整理和分析,对比了压力分散型锚索与拉力集中型锚索在应对动载方面的不同特性。研究表明,压力分散型锚索的抗振性能是拉力集中型锚索的5倍,而且具有应力调整时间短、长期抗振性能稳定,预应力损失幅度小、比例低的优点。 相似文献
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This research presents a cheap route procedure for the preparation of a potential adsorbent with superhydrophobic/superoleophillic properties for selective removal of crude oil from water. In this study, expanded polystyrene (EPS) was electrospun to produce beaded fibers in which zeolite was introduced to the polymer matrix in order to impart rough surface to non-beaded fiber. Films of the EPS and EPS/Zeolite solutions were also made for comparative study. The electrospun fibers EPS, EPS/Zeolite and resultant films were characterized using SEM, BET, FTIR and optical contact angle. The fibers exhibited superhydrophobic and superoleophillic wetting properties with water (>1500) and crude oil (00). The selective removal of crude oil presents new opportunity for the re-use of EPS as adsorbent in petroleum/petrochemical industry. 相似文献