The newly discovered Baogudi gold district is located in the southwestern Guizhou Province, China, where there are numerous Carlin-type gold deposits. To better understand the geological and geochemical characteristics of the Baogudi gold district, we carried out petrographic observations, elemental analyses, and fluid inclusion and isotopic composition studies. We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou. Three mineralization stages, namely, the sedimentation diagenesis, hydrothermal (main-ore and late-ore substages), and supergene stages, were identified based on field and petrographic observations. The main-ore and late-ore stages correspond to Au and Sb mineralization, respectively, which are similar to typical Carlin-type mineralization. The mass transfer associated with alteration and mineralization shows that a significant amount of Au, As, Sb, Hg, Tl, Mo, and S were added to mineralized rocks during the main-ore stage. Remarkably, arsenic, Sb, and S were added to the mineralized rocks during the late-ore stage. Element migration indicates that the sulfidation process was responsible for ore formation. Four types of fluid inclusions were identified in ore-related quartz and fluorite. The main-ore stage fluids are characterized by an H2O–NaCl–CO2–CH4 ± N2 system, with medium to low temperatures (180–260 °C) and low salinity (0–9.08% NaCl equivalent). The late-ore stage fluids featured H2O–NaCl ± CO2 ± CH4, with low temperature (120–200 °C) and low salinity (0–7.48% NaCl equivalent). The temperature, salinity, and CO2 and CH4 concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage. The calculated δ13C, δD, and δ18O values of the ore-forming fluids range from − 14.3 to − 7.0‰, −76 to −55.7‰, and 4.5–15.0‰, respectively. Late-ore-stage stibnite had δ34S values ranging from − 0.6 to 1.9‰. These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids, with minor contributions from strata. Collectively, the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou. It is likely that the Baogudi gold district, together with other Carlin-type gold deposits in southwestern Guizhou, was formed in response to a single widespread metallogenic event.
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黔中—渝南沉积型铝土矿的区域成矿模式概括如下:志留纪末的广西运动和泥盆纪末的紫云运动等,可能都是在峨眉地幔柱演化的壳幔相互作用阶段,因地幔柱向地壳大量输送物质和辐射能量,从而引发的地壳升降运动,在此期间,全区大面积抬升,形成长期隆起区;泥盆纪末准平原化;早石炭世岩关期气候湿热,暴露地表的早古生代岩石全面红土化、钙红土化,形成的含三水铝石红土风化壳物质,为沉积型铝土矿提供了物源。修文及息烽—遵义沉积区,于早石炭世大塘期早—中期沉积了铝土矿含矿岩系—九架炉组。绥阳—正安—道真沉积区,在晚石炭世的黄龙组石灰岩沉积并钙红土化之后,于马平期沉积了铝土矿含矿岩系的大竹园组。3个沉积区的铝土矿含矿岩系,都是在以陆相为主的环境中沉积形成的。在成岩阶段,铝土矿中的三水铝石逐渐变质为硬水铝石。由于各沉积区形成含三水铝石红土风化壳的母岩不同,由此沉积而成的铝土矿及其含矿岩系,在化学成分和矿物成分上也就有所差异。 相似文献
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黔中—渝南地区于紫云运动初期的泥盆纪末已准平原化,在石炭纪铝土矿含矿岩系沉积过程中,含矿岩系下段(铁质-粘土岩段)主要为近海湖泊相,含矿岩系上段(铝质岩段)为近海平原相。在这种大环境前提下,经常会受到海泛与强风暴潮的影响与改造,使得主要是陆相环境沉积形成的铝土矿含矿岩系中,含有少量海相大化石(腕足类)和微体生物化石(疑源类和牙形石);另在下段和上段岩矿层间,时夹海相碳酸盐岩透镜体,具明显海相沉积特征。以上表明,黔中—渝南石炭系铝土矿含矿岩系形成环境具有显著的多样性和复杂性,而非单纯的陆相沉积环境所能概括的。 相似文献
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示踪试验是客观认识地下河管道空间结构的有效手段之一,其成果可成为地下河开发利用的重要依据。通过对以食盐为示踪剂,以摩尔法为检测方法得出的巨木地下河出口水质中Cl#体积质量历时曲线的分析,认为该地下河具多支、网络状特点,系统内含水介质以管道、廊道、裂隙及溶潭的组合为特征,具有较强的调蓄能力,具备筑坝成库条件。 相似文献
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Total organic carbon content (TOC), trace element and platinum-group element (PGE) concentrations were determined in the black shales of the Lower Cambrian Niutitang Formation in the Nayong area, Guizhou Province, South China, in order to study the polymetallic Ni–Mo–PGE mineralization. The results demonstrate that numerous elements are enriched in the polymetallic ores compared to those of the nearby black shale, particularly Ni, Mo, Zn, TOC and total PGE, which can reach up to 7.03 wt.%, 8.49 wt.%, 11.7 wt.%, 11.5 wt.% and 943 ppb, respectively. The elemental enrichment distribution patterns are similar to those in the Zunyi and Zhangjiajie areas except that the Nayong location is exceptionally enriched in Zn. Whereas positive correlations are observed between the ore elements of the polymetallic ores, no such correlations are observed in the black shale. These positively correlated metallic elements are classified into three groups: Co–Ni–Cu–PGE, Zn–Cd–Pb and Mo–Tl–TOC. The geological and geochemical features of these elements suggest that Proterozoic and Early Palaeozoic mafic and ultramafic rocks, dolomites and/or Pb–Zn deposits of the Neoproterozoic Dengying Formation and seawater could be the principal sources for Co–Ni–Cu–PGE, Zn–Cd–Pb, and Mo–Tl–TOC, respectively. Furthermore, the chondrite-normalized patterns of PGEs with Pd/Pt, Pd/Ir and Pt/Ir indicate that PGE enrichment of the polymetallic ores is most likely related to hydrothermal processes associated with the mafic rocks. In contrast, PGE enrichment in the black shale resembles that of the marine oil shale with terrigenous and seawater contributions. Our investigations of TOC, trace elements and PGE geochemistry suggest that multiple sources along with submarine hydrothermal and biological contributions might be responsible for the formation of the polymetallic Ni–Mo–PGE mineralization in the black shales of the Lower Cambrian Niutitang Formation across southern China. 相似文献
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Gejiu is geographically located near Gejiu city, SW China. It is one of the largest tin-polymetallic districts in the world and contains approximately 3 million tons (Mt) of Sn and smaller quantities of Cu, Pb, and Zn. The deposit primarily yields three different types of ore: skarn-hosted ore, basalt-hosted stratiform ore, and carbonate-hosted stratiform ore. Kafang is one of the primary ore deposits in the Gejiu district and is an unusual occurrence hosted in basaltic rocks. Genetic models of the Kafang deposit suggest that it is related either to Anisian (Lower stage of Middle Triassic) Gejiu basalts or to Cretaceous Gejiu granite. In this study, we performed zircon SIMS U–Pb dating, major and trace element analyses, and Sr–Nd–Pb isotopic analyses for the Gejiu basalts and S isotopic analyses for stratiform Cu ore. Our results and previous studies are used to interpret the petrogenesis of the Gejiu basalts and the origin of the basalt-hosted stratiform Cu deposit. The SIMS zircon U–Pb analyses of the Gejiu basalts yield an age of 244.4 Ma. The trace element ratios of the Gejiu basalts are similar to those of ocean island basalt and have positive εNd(t) values (ranging from 0.6 to 2.5) and uniform (87Sr/86Sr)i values (ranging from 0.70424 to 0.70488). These ratios are close to those of the Permian Emeishan flood basalt. Thus, the Gejiu basalts may represent coeval volcanisms within the plate involving remelting of the Emeishan plume head through a stress relaxation process after the main plume event. The Pb and S isotopic compositions of the Gejiu basalts and the stratiform Cu ores indicate that the source of Cu and S is primarily derived from the Gejiu basalts. However, the age of sulfide mineralization (84.2–79.6 Ma) and the age of hydrothermal alteration (85.5–81.9 Ma) are temporally consistent with the age of the Cretaceous granite emplacement (85.5–83.3 Ma). From a petrological and geochemical study, we determine that the Gejiu basalts may have been subjected to pervasive granite-related hydrothermal alteration during the emplacement of granite. These processes increase the K and Mg contents of basalt and probably caused the formation of the Cu ores. Thus, the Kafang stratiform Cu deposit can be considered as a granite-related hydrothermal deposit. 相似文献
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Li Songtao Xia Yong Liu Jianzhong Xie Zhuojun Tan Qinping Zhao Yimeng Meng Minghua Tan Lijin Nie Rong Wang Zepeng Zhou Guanghong Guo Haiyan 《中国地球化学学报》2019,38(4):587-609
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为厘清贵州上二叠统龙潭组煤系地层的物源,以黔西南地区黔普地1井为研究对象,采集了上二叠统龙潭组的岩心进行稀土元素分析。结果表明,龙潭组的稀土总量较高(177.03×10-6～592.58×10-6),轻、重稀土分馏明显,稀土元素配分模式呈轻稀土富集、重稀土相对亏损的右倾型;(La/Sm)_N为2.63～4.72,(Gd/Yb)_N值为1.47～2.218,表明轻稀土分馏较重稀土严重;δEu无异常。研究表明,其形成的构造环境与大陆边缘与大陆弧相近,推测黔普地1井二叠系龙潭组物质来源以玄武岩为主。 相似文献
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