Measurement of trace nitrate concentrations in seawater by ion chromatography with valve switching     

杜娟  法芸  郑岳  李学兵  杜芳林  杨海燕 《中国海洋湖沼学报》2014,32(3):732-736

An ion chromatographic method with a valve switching facility was developed to determine trace nitrate concentrations in seawater using two pumps, two different suppressors, and two columns. A carbohydrate membrane desalter was used to reduce the high concentrations of sodium salts in samples. In this method, trace nitrate was eluted from the concentrator column to the analytical columns, while the matrix flowed to waste. Neither chemical pre-treatment nor sample dilution was required. In the optimized separation conditions, the method showed good linearity （R〉0,99） in the 0.05 and 50 mg/L concentration range, and satisfactory repeatability （RSD〈5%, n=6）. The limit of detection for nitrate was 0.02 mg/L. Results showed that the valve switching system was suitable and practical for the determination of trace nitrate in seawater.  相似文献   

Use of tetracycline hydrochloride and alizarin complexone for immersion marking black rockfish Sebastes schlegelii     

吕红健  张秀梅  付梅  席丹  高天翔 《中国海洋湖沼学报》2014,32(4):810-820

We tested the utility of chemical marking techniques in the juvenile black rockfish Sebastes schlegelii. Juveniles(30–40 mm total length) were immersed in a range of tetracycline hydrochloride(TC) solutions at concentrations ranging from 300 to 500 mg/L, and alizarin complexone(ALC) solutions at concentrations ranging from 200 to 400 mg/L in filtered sea water(salinity of 30) for 24 h, respectively. Otoliths(sagittae, asteriscus), scales, fin rays(dorsal, pectoral, ventral, anal, and caudal fin rays), and fin spines(dorsal, ventral, and anal fin spines) were sampled and used to detect fl uorescent marks after a 60-day growth experiment. With the exception of 300 mg/L TC, acceptable marks were produced in the otoliths and fin spines by all concentrations of TC and ALC. In particular, we observed clearly visible marks in the sagittae, asteriscus, and fin spines under normal light at concentrations of 200–400 mg/L, 250–400 mg/L, and 250–400 mg/L ALC, respectively. Scales and fin rays had acceptable marks at much higher concentrations(≥350 mg/L TC, ≥250 mg/L ALC for scales and ≥350 mg/L TC, ≥300 mg/L ALC for fin rays). The best mark quality(i.e., acceptable marks were observed in all sampled structures after immersion marking) were obtained following immersion in TC at between 350–500 mg/L, and ALC between 300–400 mg/L. In addition, there was no significant difference in survival and growth of TC and ALC marked fish compared to their controls up to 60 days post-marking( P 0.05).  相似文献   

海水酸化会削弱鲨鱼的感官功能     

胡德良  Jennifer Balmer 《气候变化研究进展》2014,(5)

<正>一般说来,海洋肉食动物鲨鱼在很大程度上靠嗅觉寻找分散于广阔环境中的猎物。然而,研究人员不久前在Global Change Bilolgy杂志在线版上报道说:根据预测,随着全球海洋的变化,鲨鱼这种久经历练的捕猎能力可能会受到损害。由于人类活动释放到大气中的二氧化碳被海水吸收,海水的酸度变得越来越大。以前的研究表明,富含二氧化碳的酸性海水可能会削弱珊瑚礁鱼类嗅  相似文献   

The Soil Moisture and Net Primary Production Affected by CO_2 and Climate Change Using a Coupled Model          下载免费PDF全文

PENG Jing  DAN Li 《大气和海洋科学快报》2014,(4):269-274

In this paper, a coupled model was used to estimate the responses of soil moisture and net primary production of vegetation （NPP） to increasing atmospheric CO2 concentration and climate change. The analysis uses three experiments simulated by the second-generation Earth System Model （CanESM2） of the Canadian Centre for Climate Modelling and Analysis （CCCma）, which are part of the phase 5 of the Coupled Model Intercomparison Project （CMIP5）. The authors focus on the magnitude and evolution of responses in soil moisture and NPP using simulations modeled by CanESM, in which the individual effects of increasing CO2 concentration and climate change and their combined effect are separately accounted for. When considering only the single effect of climate change, the soil moisture and NPP have a linear trend of 0.03 kg m^-2 yr^-1 and-0.14 gC m^- 2 yr^-2, respec- tively. However, such a reduction in the global NPP results from the decrease of NPP at lower latitudes and in the Southern Hemisphere, although increased NPP has been shown in high northern latitudes. The largest negative trend is located in the Amazon basin at -1.79 gC m^-2 yr^-2. For the individual effect of increasing CO2 concentration, both soil moisture and NPP show increases, with an elevated linear trend of 0.02 kg m^-2 yr^-1 and 0.84 gC m^-2 yr^-2, respectively. Most regions show an increasing NPP, except Alaska. For the combined effect of increasing atmospheric CO2 and climate change, the increased soil moisture and NPP exhibit a linear trend of 0.04 kg m^2 yr^-1 and 0.83 gC m^2 yr^-2 at a global scale. In the Amazon basin, the higher reduction in soil moisture is illustrated by the model, with a linear trend of-0.39 kg m^-2 yr^-1, for the combined effect. Such a change in soil moisture is caused by a weakened Walker circulation simulated by this coupled model, compared with the single effect of increasing CO2 concentration （experiment M2）, and a consequence of the reduction in NPP is also shown in this area, with a linear trend of-  相似文献   

Verifying Fossil-Fuel Carbon Dioxide Emissions Forecasted by an Artificial Neural Network with the GEOS-Chem Model          下载免费PDF全文

WANG Yi-Nan  Lü Da-Ren  LI Qian  PAN Yu-Bing 《大气和海洋科学快报》2014,(5):377-381

In this study, the authors developed an en- semble of Elman neural networks to forecast the spatial and temporal distribution of fossil-fuel emissions （ff） in 2009. The authors built and trained 29 Elman neural net- works based on the monthly average grid emission data （1979-2008） from different geographical regions. A three-dimensional global chemical transport model, God- dard Earth Observing System （GEOS）-Chem, was applied to verify the effectiveness of the networks. The results showed that the networks captured the annual increasing trend and interannual variation of ff well. The difference between the simulations with the original and predicted ff ranged from -1 ppmv to 1 ppmv globally. Meanwhile, the authors evaluated the observed and simulated north-south gradient of the atmospheric CO2 concentrations near the surface. The two simulated gradients appeared to have a similar changing pattern to the observations, with a slightly higher background CO2 concentration, - 1 ppmv. The results indicate that the Elman neural network is a useful tool for better understanding the spatial and tem- poral distribution of the atmospheric C02 concentration and ft.  相似文献   

不同辐射背景下大西洋热盐环流下沉区混合层深度变化     

李菁楠  陈学恩 《海洋与湖沼》2014,45(4):676-684

基于政府间气候变化专门委员会(Intergovernmental Panel on Climate Change,IPCC)4种最新辐射强迫情景,利用ECHAM5/MPI-OM(European Centre Hamburg Model 5/Max Planck Institute Ocean Model)气候模式输出的1850—2300年逐月混合层深度、海表面温度、海表面盐度数据,分析大西洋热盐环流下沉区混合层深度的变化情况。结果表明:随辐射强迫增加,热盐环流下沉区混合层深度下降,混合层深度振荡周期在格陵兰-冰岛-挪威海(Greenland Sea–Iceland Sea–Norwegian Sea,GIN)海域减小,在拉布拉多海(Labrador Sea,LAB)海域变化不大;与GIN海域相比,LAB海域混合层深度对辐射强迫变化更敏感;两海区温度对混合层深度的影响时间较长,混合层深度对盐度的变化反应迅速;混合层深度变化的主导因素在LAB海域中为盐度,而在GIN海域,低辐射强迫下温度主导混合层深度变化,中高辐射强迫下温度与盐度共同起主导作用。  相似文献   

The distribution of chlorophyll a and its influencing factors in different regions of the Bering Sea     

KANG Jianhu  CHEN Xingqun  ZHANG Ming 《海洋学报(英文版)》2014,33(6):112-119

The distribution of chlorophyll a(Chl a) and its relationships with physical and chemical parameters in different regions of the Bering Sea were discussed in July 2010. The results showed the seawater column Chl a concentrations were 13.41–553.89 mg/m2 and the average value was 118.15 mg/m2 in the study areas. The horizontal distribution of Chl a varied remarkably from basin to shelf in the Bering Sea. The regional order of Chl a concentrations from low to high was basin, slope, outer shelf, inner shelf, and middle shelf. The vertical distribution of Chl a was grouped mainly from single-peak type in basin, slope, outer shelf, and middle shelf, where the deep Chl a maxima(DCM) layer was observed at 25–50 m, 30–35 m, 36–44 m, and 37–47 m, respectively. The vertical distribution of Chl a mainly had three basic patterns: standard single-peak type, surface maximum type, and bottom maximum type in the inner shelf. The analysis also showed that the transportation of ocean currents may control the distribution of Chl a, and the effects were not simple in the basin of the Bering Sea. There was a positive correlation between Chl a and temperature, but no significant correlation between Chl a and nutrients. The Bering Sea slope was an area deeply influenced by slope current. Silicate was the factor that controlled the distribution of Chl a within parts of the water in the slope. Light intensity was an important environmental factor in controlling seawater column Chl a in the shelf, where Chl a was limited by nitrate rather than phosphate within the upper water. Meanwhile, there was a positive relationship between Chl a and salinity. Algal blooms broke out at Sta. B6 of the southwestern St. Lawrence Island and Stas F6 and F11 in the middle of the Bering Strait.  相似文献   

近50年春季沙尘活动及其对PM_(10)质量浓度的影响     

余予  孟晓艳  刘娜  张志富  任芝花  王瑞斌 《高原气象》2014,(4)

利用中国北方847个地面气象台站观测的天气现象,从沙尘日数的时空分布、变化趋势等方面对1961 2012年中国北方春季沙尘活动进行了分析。结果表明,中国西北部的沙漠地带是春季沙尘暴和扬沙的多发和频发区。除个别台站,绝大部分北方站点的沙尘暴日数、起沙日数均呈显著下降趋势。1961 2012年中国北方区域平均的春季沙尘暴日数、起沙日数变化趋势分别为-1.2 d·(10a)-1和-2.3 d·(10a)-1,下降趋势显著。另外,沙尘暴的影响范围也逐步缩小。通过分析大气环境监测的PM10质量浓度(ρPM10)日平均值数据表明,发生沙尘时,北京、石家庄、济南、兰州、西宁的日空气质量易超标。ρPM10日平均值与沙尘持续时间呈显著正相关,即沙尘持续时间越长,ρPM10日平均值增幅越大。  相似文献   

The Characteristics of Atmospheric Ice Nuclei Measured at Different Altitudes in the Huangshan Mountains in Southeast China简   总被引：3，自引：0，他引：3  

JIANG Hui  YIN Yan  YANG Lei  YANG Shaozhong  SU Hang  and CHEN Kui 《大气科学进展》2014,31(2):396-406

The concentration of ice nuclei （IN） and the relationship with aerosol particles were measured and analyzed using three 5-L mixing cloud chambers and a static diffusion cloud chamber at three altitudes in the Huangshan Mountains in Southeast China from May to September 2011.The results showed that the mean total number concentration of IN on the highest peak of the Huangshan Mountains at an activation temperature （Ta） of-20℃C was 16.6 L-1.When the supersaturation with respect to water （Sw） and with respect to ice （Si） were set to 5％,the average number concentrations of IN measured at an activation temperature of-20℃C by the static diffusion cloud chamber were 0.89 and 0.105 L-1,respectively.A comparison of the concentrations of IN at three different altitudes showed that the concentration of IN at the foot of the mountains was higher than at the peak.A further calculation of the correlation between IN and the concentrations of aerosol particles of different size ranges showed that the IN concentration was well correlated with the concentration of aerosol particles in the size range of 1.2-20 μtm.It was also found that the IN concentration varied with meteorological conditions,such as wind speed,with higher IN concentrations often observed on days with strong wind.An analysis of the backward trajectories of air masses showed that low IN concentrations were often related to air masses travelling along southwest pathways,while higher IN concentrations were usually related to those transported along northeast pathways.  相似文献   

The Southern Annular Mode (SAM) in PMIP2 simulations of the last glacial maximum     

Seong-Joong KIM  L Junmei  Baek-Min KIM 《大气科学进展》2014,31(4):863-878

The increasing trend of the Southern Annular Mode （SAM） in recent decades has influenced climate change in the Southem Hemisphere （SH）.How the SAM will respond increased greenhouse gas concentrations in the future remains uncertain.Understanding the variability of the SAM in the past under a colder climate such as during the Last Glacial Maximum （LGM） might provide some understanding of the response of the SAM under a future warmer climate.We analyzed the changes in the SAM during the LGM in comparison to pre-industrial （PI） simulations using five coupled ocean-atmosphere models （CCSM,FGOALS,IPSL,MIROC,HadCM） from the second phase of the Paleoclimate Modelling Intercomparison Project （PMIP2）.In CCSM,MIROC,IPSL,and FGOALS,the variability of the simulated SAM appears to be reduced in the LGM compared to the PI simulations,with a decrease in the standard deviation of the SAM index.Overall,four out of the five models suggest a weaker SAM amplitude in the LGM consistent with a weaker SH polar vortex and westerly winds found in some proxy records and model analyses.The weakening of the SAM in the LGM was associated with an increase in the vertical propagation of Rossby waves in southern high latitudes.  相似文献