La3+ 离子掺杂钨酸铅单晶的微结构缺陷     

黄彦林  赵韧  赵连泽  朱文亮 《矿物学报》2006,26(1):84-88

钨酸铅晶体是一种非化学计量化合物,缺陷丰富,蕴含着利用掺杂产生新效应和开发新功能的广泛可能性。探讨了不同浓度La3 掺杂对于钨酸铅晶体发光性能的影响,如热释光、X射线激发发光、光致发光等。La3 掺杂有效地抑制了陷阱中心,使发光受到强烈的抑制,在高浓度掺杂的钨酸铅中,激发机制有所改变,通过XPS测试的结果分析了不同浓度La3 掺杂机制。低浓度掺杂中,La3 取代Pb2 ,形成缺陷复合体[2(La3Pb ).-(VPb)″];高浓度掺杂晶体中,La3 离子不但占据Pb2 位置,而且也会占据W6 位置(La3W ),产生La3 的自补偿机制,形成La3 的自补偿对[(La3W )-(La3Pb ).]-(VO)..或缺陷聚集体[3(LaP3b ).-(La3W )]。  相似文献   

含部分晶须的钛酸锂的制备及其性能表征     

邓昭平  倪师军  李思平  夏新蕊  王鹏威 《矿物岩石》2006,26(4):98-100

L i4T i5O12是一种循环性能好、有很好的充放电平台、理论比容量较大、不与电解液反应的新型负极材料,研究探索以偏钛酸和碳酸锂为主要原料制备含部分晶须的尖晶石型晶型L i4T i5O12的一种方法。通过此工艺在1 000℃煅烧8 h后在样品中约20%的晶须出现,晶须的直径≤0.5μm,晶须的长度约为7μm。  相似文献   

BP人工神经网络在青藏铁路南段地壳稳定性定量评价中的应用   总被引：1，自引：1，他引：0  

周春景  吴珍汉  石广仁 《地质科技情报》2007,26(3):79-85

将BP人工神经网络方法引入区域构造活动性、区域地壳稳定性研究领域,对青藏铁路南段沿线的构造活动性进行定量分析.选用断层运动速率、地震震级、温泉温度及剪切应变4个关键影响因子作为BP人工神经网络的输入向量,构造活动强度(α)作为输出向量,以α为定量判据,将全区划分为相对稳定区(α＜0.22)、较不稳定区(α≈0.22～0.38)、不稳定区(α≈0.38～0.69)、极不稳定区或强烈构造活动区(α≥0.69).在青藏铁路南段沿线划分出格仁错、崩错、当雄-羊八井、错那湖、唐古拉山口南、聂荣东北、聂荣西北、雅鲁藏布江断裂沿线、萨迦等不稳定区,在不稳定区内部进一步划分出申扎、蓬错、尼木、桑雄、羊八井5个极不稳定区.  相似文献   

铵(氮)在岩石和矿物中地球化学行为研究进展     

谢建成  杨晓勇 《地质找矿论丛》2007,22(1):1-8

地壳中的氮大都以NH4 储存在矿物中.由于成岩时含氮有机物质的分解作用,氮广泛分布在沉积岩和低级变质岩中;在岩浆岩和变质岩中,氮主要以NH4 存在于含钾硅酸盐(长石和云母类)中;岩浆岩的δ(15N)值和氮浓度明显地不同于沉积物和变沉积岩,主要是由于有机物的缺乏.具有明显铵含量的火成岩主要是含钾矿物的深成岩.因而NH4 可以作为一个"示踪元素"而用于成矿作用等方面的研究.文章还提出了未来的研究方向.  相似文献   

Comparison of ecophysiological characteristics between introduced and indigenous mangrove species in China   总被引：2，自引：1，他引：1  

Luzhen Chen  Nora F.Y. Tam  Jianhui Huang  Xueqin Zeng  Xiangli Meng  Cairong Zhong  Yuk-shan Wong  Guanghui Lin   《Estuarine, Coastal and Shelf Science》2008,79(4):644-652

Due to its rapid growth, the introduced mangrove species Sonneratia apetala from Bangladesh has been widely used in mangrove restoration in southeastern China since 1985. As an indigenous mangrove species in Hainan, China, Sonneratia caseolaris was also planted in Guangdong Province for afforestation purposes. Both species have developed well in their new habitats, but their ecophysiological differences with the native mangrove species have not been studied. In this study, leaf gas exchange, water and nitrogen use efficiencies of two Sonneratia species were compared with those of selected native mangrove species (Avicennia marina, Aegiceras corniculatum, Kandelia candel, and Excoecaria agallocha) in Hainan and Shenzhen. The introduced S. apetala maintained lower carbon assimilation rate (A) and photosynthetic nitrogen use efficiency (PNUE) than the indigenous S. caseolaris. In Shenzhen, the two introduced Sonneratia had comparable photosynthetic rates and water use efficiency (WUE) with the native mangrove species, except that PNUE in S. caseolaris was significantly higher than in the native mangrove species. The two Sonneratia species showed significant overlap in PNUE and long-term WUE. Photosynthetic parameters derived from leaf photosynthetic light–response curves and A–C_i curves also suggested lower carbon assimilation capacities for the introduced Sonneratia than for the native mangrove species in both study sites. The lower light compensation point (LCP) of two introduced Sonneratia in both study sites also indicated a better adaptation to a low light regime than the native mangrove species. The results of photosynthetic capacities indicated that the introduced mangrove species have little competitive advantage over local native mangrove species in their respective new habitats.  相似文献   

Spatiotemporal aspects of silica buffering in restored tidal marshes     

Sander Jacobs  Eric Struyf  Tom Maris  Patrick Meire 《Estuarine, Coastal and Shelf Science》2008

Losses of pelagic diatom production resulting from silica limitation have not only been blamed for toxic algal blooms, but for the reduction in ability of coastal food webs to support higher trophic levels. Recent research has shown the importance of advective seepage water fluxes of dissolved silica (DSi) from freshwater marshes to pelagic waters during moments of riverine Si-limitation. In this study, we investigated the potential impact of recently installed new tidal areas along the Schelde estuary, located in former polder areas and characterized by so-called controlled reduced tidal regimes (CRT). Nine mass-balance studies were conducted in a newly constructed CRT in the freshwater Schelde estuary. During complete tidal cycles both DSi and amorphous silica (ASi) concentrations were monitored at the entrance culverts and in different habitats in the marsh. A swift DSi-delivery capacity was observed despite the shifted spatiotemporal frame of exchange processes compared to reference marshes. As silica-accumulating vegetation is not yet present, and difference with reference marshes’ deliveries is surprisingly small, we indicate diatomaceous debris and phytoliths to be the main silica source. Although further research is necessary on the driving forces of the different processes involved, restoration of former agricultural areas under CRT-regime provide the potential to buffer silica in the estuary.  相似文献   

Factors controlling dissolved silica in coral reef surface water of Urasoko Bay, Ishigaki Island, Japan     

Kazuo Abe 《Journal of Oceanography》2008,64(6):961-967

From August 2006 to August 2007, the concentrations of dissolved silica (Si(OH)₄) were monitored in the surface water of Urasoko Bay and the mouth of the stream that runs into the bay. Urasoko Bay is located on the northern coast of Ishigaki Island, Okinawa, Japan, which is in a subtropical area of the North Pacific Ocean and is surrounded by a relatively poorly developed fringing reef. Added to these samples were freshwater from the upstream area and brackish water that exudes at the beach site, which were collected from April to June 2007. Rainwater samples were also collected during the study period. The concentration of Si(OH)₄ generally decreased from upstream to the bay site, and, on clear days, Si(OH)₄ data from all study sites (the bay, beach, stream mouth, and upstream) plotted against salinity fell on a single straight line. When the influence of rainwater was, the results were scattered below the straight line, which suggests dilution by rainwater with a much lower Si(OH)₄ concentration. These findings show that offshore seawater, rainwater, and upstream freshwater regulate the concentration of Si(OH)₄ in the surface water of Urasoko Bay.  相似文献   

地下卤水中镭的富集与测定方法研究     

魏伟  康兴伦  江雪艳  于志刚  杜金洲  张卫国 《海洋科学》2008,32(11):1-4

以自配人工卤水,采用硫酸钡（镭）共沉淀法富集其中的镭,同时用γ谱仪同步测量^226Ra和^228Ra的含量。不同pH和共沉淀剂作用下的化学及放化回收率计算表明,该方法操作简单,回收率高,适用于地下卤水及其它水体较高含量^226Ra、^228Ra的同步测定。用该方法测定的莱州湾地下卤水^226Ra和^228Ra含量分别为0．341Bq／L和1．615Bq／L,远高于海水中镭的含量。  相似文献   

加蓬G4-188区块钻井技术实践认识     

石强 《海洋地质译丛》2008,(1):82-87

加蓬G4-188区块是一个新的海外勘探区块,在钻井过程中遇到了井壁垮塌、气侵、井斜控制困难等诸多难题,影响了钻井施工的速度。针对这些难题,实施了解决G4-188区块钻井施工难点的各项技术措施,为G4-188区块后续钻井施工提供了有益的技术支持。  相似文献   

合作原则对大学英语四六级听力测试对话的指导   总被引：1，自引：0，他引：1  

黄舒 《成都信息工程学院学报》2008,23(3):349-353

听力理解在英语四六级考试中占有重要的比例,提高听力水平既是教学的要求也是通过大学英语四六级考试的关键。因此在分析近年来大学英语四六级听力理解对话部分的难点的基础上,提出合作原则及相关理论对解答听力理解对话部分具有指导作用。  相似文献