No Scientific Debate in the Zero‐Valent Iron Literature          下载免费PDF全文

Chicgoua Noubactep 《洁净——土壤、空气、水》2016,44(4):330-332

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山东省韩旺条带状铁矿床地质特征及其成矿地质条件分析          下载免费PDF全文

谭钢  印建平  孙建丁  李旭平  佘宏全 《山东国土资源》2013,29(7):31-35,39

山东省沂源县韩旺铁矿是华北克拉通一大型条带状铁矿床,铁矿层赋存于新太古代泰山岩群雁翎关组上部的变质岩系中。矿体规模较大,断续延伸近8 000m,单矿层厚度一般1～25m。矿体总体呈单斜层状产出,矿石为硅质和铁质相间排列构成的条纹—条带状构造。含矿岩性主要为含磁铁斜长角闪片岩、含磁铁石英角闪片岩及片麻岩类,原岩属于中基性的火山岩和火山沉积岩类。结合近些年来国内外学者在研究前寒武纪BIF铁矿年代学、同位素地球化学与成矿作用方面取得的最新进展,认为韩旺铁矿沉积成矿时代为～2.6Ga,矿床形成于海洋化学沉积环境,成矿物质来源具有明显的火山物质贡献特征,矿床的形成与华北地区太古宙克拉通化形成的稳定沉积环境以及微生物的参与是密不可分的。  相似文献   

羧甲基纤维素稳定纳米铁去除水中六价铬的研究     

姬航  何娴  曹茜  陈家玮 《现代地质》2013,27(6):1484

零价纳米铁(NZVI)具有较高活性,近年受到人们关注并将其应用于地下水污染原位修复,但在实际应用中NZVI易发生氧化与团聚,容易失活。因此尝试运用环境友好型材料对NZVI进行表面改性,选择羧甲基纤维素(CMC)对纳米铁进行表面包覆获得CNZVI,研究不同CMC含量包覆NZVI的分散稳定性和CNZVI对水中六价铬的去除效果。结果表明：经过改性后的CNZVI分散稳定性要明显优于商用纳米铁RNIP,包覆CMC的比例越高,CNZVI的稳定性越好,在较高的CMC包覆比例下,纳米铁不易失活并具有良好的反应活性,对溶液中六价铬有很好的去除效果。  相似文献   

新疆富蕴县蒙库铁矿床赋矿浅粒岩锆石U-Pb年代学研究     

王宇利  孙丰月  李碧乐  张晗  王冠 《地质与资源》2013,22(2):114-119,137

蒙库铁矿床位于阿尔泰山南缘成矿带的麦兹火山-沉积盆地内,矿床主矿体成因类型为与火山作用有关的热水喷流沉积矿床.矿体主要赋存于泥盆系康布铁堡组地层中,主要岩性有浅粒岩、变粒岩及斜长角闪岩,原岩恢复显示为海相火山岩,主要为细碧岩-角斑岩-石英角斑岩,次为流纹岩-凝灰岩,沉积岩为钙质凝灰质砂岩夹结晶灰岩.通过对蒙库铁矿床浅粒岩锆石LA-ICP-MS UPb定年,确定了矿床的形成时代及康布铁堡组地层的形成时代.锆石中Th含量分别为29.5×10^-6~82.7×10^-6和32.1×10^-6~109.3×10^-6,U含量分别为35.7×10^-6~132.1×10^-6和47.6×10^-6~140.6×10^-6,Th/U比值为0.41~1.19和0.51~0.85,为典型岩浆锆石特征.蒙库铁矿浅粒岩的U-Pb年龄分别为397.5±2.5 Ma和389.0±4.7 Ma.结合区域年代学资料,确定康布铁堡组形成于早泥盆世,康布铁堡组下亚组上限为389±4.7 Ma,而蒙库铁矿床主矿体形成时代为397.5±2.5 Ma.  相似文献   

四川省白马钒钛磁铁矿床铁品位分布地质统计学研究     

黄继  肖光莉  刘伟  王欢  向虎 《地质与资源》2012,21(6):566-570

以白马钒钛磁铁矿区及及坪矿段为研究对象,通过对矿体主要区域化变量矿石铁品位半变异函数的分析,建立了相应的半变异函数的球状模型,从而求得主矿体在走向、倾向以及垂直3个方向上的块金值、变程等参数.根据这些参数,求得白马铁矿床及及坪矿段铁品位变化程度系数在走向、倾向与垂直方向均小于0.3,表明矿区成矿作用单一,矿化较均匀,有利于矿山的开采,并且统计得出铁品位属于正态分布,表明下一步用普通克立格法进行估值效果最好,为矿山规划设计和生产提供了理论依据.  相似文献   

Simultaneous determination of iron and manganese in water using artificial neural network catalytic spectrophotometric method   总被引：1，自引：0，他引：1  

Hongwei Ji  Yan Xu  Shuang Li  Huizhen Xin  Hengxia Cao 《中国海洋大学学报(英文版)》2012,11(3):323-330

A new analytical method using Back-Propagation (BP) artificial neural network and kinetic spectrophotometry for simultaneous determination of iron and magnesium in tap water, the Yellow River water and seawater is established. By conditional experiments, the optimum analytical conditions and parameters are obtained. Levenberg-Marquart (L-M) algorithm is used for calculation in BP neural network. The topological structure of three-layer BP ANN network architecture is chosen as 15-16-2 (nodes). The initial value of gradient coefficient μ is fixed at 0.001 and the increase factor and reduction factor of μ take the default values of the system. The data are processed by computers with our own programs written in MATLAB 7.0. The relative standard deviation of the calculated results for iron and manganese is 2.30% and 2.67% respectively. The results of standard addition method show that for the tap water, the recoveries of iron and manganese are in the ranges of 98.0%-104.3% and 96.5%-104.5%, and the RSD is in the range of 0.23%-0.98%; for the Yellow River water (Lijin district of Shandong Province), the recoveries of iron and manganese are in the ranges of 96.0%-101.0% and 98.7%-104.2%, and the RSD is in the range of 0.13%-2.52%; for the seawater in Qingdao offshore, the recoveries of iron and manganese are in the ranges of 95.3%-104.8% and 95.3%-104.7%, and the RSD is in the range of 0.14%-2.66%. It is found that 21 common cations and anions do not interfere with the determination of iron and manganese under the optimum experimental conditions. This method exhibits good reproducibility and high accuracy in the determination of iron and manganese and can be used for the simultaneous determination of iron and manganese in tap water and natural water. By using the established ANN- catalytic spectrophotometric method, the iron and manganese concentrations of the surface seawater at 11 sites in Qingdao offshore are determined and the level distribution maps of iron and manganese are drawn.  相似文献   

山东张宝庄铁矿水文地质特征研究     

邢业江  聂佩孝 《山东国土资源》2012,28(4):30-32

张宝庄铁矿矿床位于当地侵蚀基准面以下,呈似层状,倾角多在45°以上,埋深20～888m。对矿区3个主要含水层及其之间的水力联系进行分析,这3个含水层分别为第四纪全新世冲洪积孔隙水含水层、基岩风化裂隙水含水层和泰山岩群变质岩构造裂隙水含水层,各含水层之间水力联系较弱。另外还研究了矿床充水因素、预测矿床正常涌水量和最大涌水量,在此基础上划分该矿区水文地质条件为中等类型。  相似文献   

安丘-莱州地区低缓磁异常带铁矿找矿前景分析          下载免费PDF全文

苏旭亮  王刚  王春  程东江  李鑫 《山东国土资源》2012,28(12):24-27,31

平度市胜合铁矿处于安丘-莱州铁矿成矿带中段,为新发现的低品位铁矿床。矿床分布于低缓航磁异常区,产于古元古代粉子山群小宋组地层中,属沉积变质型成因。该区找矿的突破,是安丘-莱州铁成矿带弱航磁异常中找矿的一个典型,对今后安丘-莱州地区低缓磁异常的找矿起到一定启示作用。  相似文献   

Enhancing the Sustainability of Household Fe0/Sand Filters by Using Bimetallics and MnO2     

Chicgoua Noubactep  Sabine Caré  Brice Donald Btatkeu K.  Charles Péguy Nanseu‐Njiki 《洁净——土壤、空气、水》2012,40(1):100-109

Filtration systems containing metallic iron as reactive medium (Fe⁰ beds) have been intensively used for water treatment during the last two decades. The sustainability of Fe⁰ beds is severely confined by two major factors: (i) reactivity loss as result of the formation of an oxide scale on Fe⁰ and (ii) permeability loss due to pore filling by generated iron corrosion products. Both factors are inherent to iron corrosion at pH > 4.5 and are common during the lifespan of a Fe⁰ bed. It is of great practical significance to improve the performance of Fe⁰ beds by properly addressing these key factors. Recent studies have shown that both reactivity loss and permeability loss could be addressed by mixing Fe⁰ and inert materials. For a non‐porous additive like quartz, the threshold value for the Fe⁰ volumetric proportion is 51%. Using the Fe⁰/quartz system as reference, this study theoretically discusses the possibility of (i) replacing Fe⁰ by bimetallic systems (e.g., Fe⁰/Cu⁰), or (ii) partially replacing quartz by a reactive metal oxide (MnO₂ or TiO₂) to improve the efficiency of Fe⁰ beds. Results confirmed the suitability of both tools for sustaining Fe⁰ bed performance. It is shown that using a Fe⁰:MnO₂ system with the volumetric proportion 51:49 will yield a filter with 40% residual porosity at Fe⁰ depletion (MnO₂ porosity 62%). This study improves Fe⁰ bed design and can be considered as a basis for further refinement and detailed research for efficient Fe⁰ filters.  相似文献   

鄂东南程潮铁矿床花岗质岩和闪长岩的岩体时代、成因及地质意义——锆石年龄、地球化学和Hf同位素新证据   总被引：5，自引：0，他引：5  

姚磊  谢桂青  吕志成  赵财胜  王建  郑先伟  何哲峰  李伟 《吉林大学学报(地球科学版)》2013,43(5):1393-1422

利用LA-ICP-MS锆石U-Pb法测得程潮矿区花岗岩成岩年龄为（128.8±0.5） Ma,石英二长斑岩成岩年龄为（128.3±0.5） Ma,闪长岩成岩年龄为（140.0±0.3） Ma,辉绿玢岩成岩年龄为(125.5±0.5) Ma,皆形成于早白垩世。地球化学分析结果显示：花岗质岩为高钾准铝质I型系列;闪长岩和辉绿玢岩为高钾钙碱性系列。各岩体的稀土元素总量较高,轻稀土强烈富集,轻、重稀土元素分异明显,无明显的负铕异常。花岗质岩的微量元素以富集Rb、Th、U、La等元素,贫Ba、Nb、Sr等元素为特点。闪长岩和辉绿玢岩具有相似的微量元素特征,表现为K、La、Nd富集和Ta、Nb、Sr、P、Ti亏损的特点。根据岩体的锆石Hf同位素组成和地球化学特征可知,程潮矿区各岩体可能是岩石圈地幔在部分熔融过程中,混入了不同数量古老下地壳物质的产物。矿区花岗质岩的成岩年龄与程潮Fe矿床的成矿年龄相近,暗示其与矿体有着密切的联系。  相似文献