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81.
Distributions and seasonal variations of dissolved carbohydrates in the Jiaozhou Bay,China 总被引:1,自引:0,他引:1
Surface seawater samples were collected in the Jiaozhou Bay, a typical semi-closed basin located at the western part of the Shandong Peninsula, China, during four cruises. Concentrations of monosaccharides (MCHO), polysaccharides (PCHO) and total dissolved carbohydrates (TCHO) were measured with the 2,4,6-tripyridyl-s-triazine spectroscopic method. Concentrations of TCHO varied from 10.8 to 276.1 μM C for all samples and the ratios of TCHO to dissolved organic carbon (DOC) ranged from 1.1 to 67.9% with an average of 10.1%. This result indicated that dissolved carbohydrates were an important constituent of DOC in the surface seawater of the Jiaozhou Bay. In all samples, the concentrations of MCHO ranged from 2.9 to 65.9 μM C, comprising 46.1 ± 16.6% of TCHO on average, while PCHO ranged from 0.3 to 210.2 μM C, comprising 53.9 ± 16.6% of TCHO on average. As a major part of dissolved carbohydrates, the concentrations of PCHO were higher than those of MCHO. MCHO and PCHO accumulated in January and July, with minimum average concentration in April. The seasonal variation in the ratios of TCHO to DOC was related to water temperature, with high values in January and low values in July and October. The concentrations of dissolved carbohydrates displayed a decreasing trend from the coastal to the central areas. Negative correlations between concentrations of TCHO and salinity in July suggested that riverine input around the Jiaozhou Bay had an important effect on the concentrations of dissolved carbohydrates in surface seawater. The pattern of distributions of MCHO and PCHO reported in this study added to the global picture of dissolved carbohydrates distribution. 相似文献
82.
This paper presents the closed‐form solutions for the elastic fields in two bonded rocks induced by rectangular loadings. Each of the two bonded rocks behaves as a transversely isotropic linear elastic solid of semi‐infinite extent. They are completely bonded together at a horizontal surface. The rectangular loadings are body forces along either vertical or horizontal directions and are uniformly applied on a rectangular area. The rectangular area is embedded in the two bonded rocks and is parallel to the horizontal interface. The classical integral transforms are used in the solution formulation, and the elastic solutions are expressed in the forms of elementary harmonic functions for the rectangular loadings. The stresses and displacements in the rocks induced by both the horizontal and vertical body forces are also presented. The numerical results illustrate the important effect of the anisotropic bimaterial properties on the stress and displacement fields. The solutions can be easily implemented for numerical calculations and applied to problems encountered in rock mechanics and engineering. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
83.
Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana 下载免费PDF全文
The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the 87Sr/86Sr, δ13CDIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
84.
The variability of water chemistry on a daily scale is rarely addressed due to the lack of records. Appropriate tools, such as typologies and dimensionless indicators, which permit comparisons between stations and between river materials, are missing. Such tools are developed here for daily concentrations (C), specific fluxes or yields (Y) and specific river flow (q). The data set includes 128 long‐term daily records, for suspended particulate matter (SPM), total dissolved solids (TDS), dissolved and total nutrients, totalling 1236 years of records. These 86 river basins (103–106 km2) cover a wide range of environmental conditions in semi‐arid and temperate regions. The segmentation—truncation of C–q rating curves into two parts at median flows (q50) generates two exponents (b50inf and b50sup) that are different for 66% of the analysed rating curves. After segmentation, the analysis of records results in the definition of nine major C–q types combining concentrating, diluting or stable patterns, showing inflexions, chevron and U shapes. SPM and TDS are preferentially distributed among a few types, while dissolved and total nutrients are more widely distributed. Four dimensionless indicators of daily variability combine median (C50, Y50), extreme (C99, Y99) and flow‐weighted (C*, Y*) concentrations and yields (e.g. C99/C50, Y*/Y50). They vary over two to four orders of magnitude in the analysed records, discriminating stations and river material. A second set of four indicators of relative variability [e.g. (Y*/Y50)/(q*/q50)], takes into account the daily flow variability, as expressed by q*/q50 and q99/q50, which also vary over multiple orders of magnitude. The truncated exponent b50sup is used to describe fluxes at higher flows accounting for 75% (TDS) to 97% (SPM) of interannual fluxes. It ranges from ? 0·61 to + 1·86 in the database. It can be regarded as the key amplificator (positive b50sup) or reductor (negative b50sup) of concentrations or yields variability. C50, Y50, b50sup can also be estimated in discrete surveys, which provides a new perspective for quantifying and mapping water quality variability at daily scale. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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地下水逸出氡和溶解氡观测系统的合理设计 总被引:2,自引:0,他引:2
本文依据大量观测事实并参考前人所做的工作,对地下水中逸出氡和溶解氡观测系统合理设计进行了深入细致的分析和讨论。研究结果表明,观测系统设计中应注意的主要问题是观测井口装置中主支管空间位置的合理设计、逸出气“集气腔”的大小以及气体(包括自由气体和逸出气体)与液体的分离程度等。根据上述几点并结合井孔自身的不同条件,本文设计出了两种比较合理的井口装置模型,该模型的设计对今后逸出氡和溶解氡观测系统的改造和完善具有现实意义。 相似文献
88.
本文通过热力学的计算方法,确定了测老庙盆地水中铀的存在形式,分析了铀在水中的迁移规律和沉淀条件。并应用饱和指数的找矿机理,对测老庙盆地的找矿前景提出了水文地球化学依据。 相似文献
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本文提出比值R分析计算方法,用其求解时间序列数据矩平差和标准差结构的分形,目的的于判定地震预报指标,作为实例,宁夏区和同心区的地震频度,最大震级,以及同心地办水氡观测数据的比值R随时间的分形变化进行了初步分析,证明本方法能为我国提供可信的震情信息。 相似文献