Os水吸收液ICP-MS测量信号强度衰减原因研究     

周利敏  李超  李欣尉  赵鸿  屈文俊  杜安道 《岩矿测试》2018,37(4):431-438

蒸馏法能从样品中有效分离出OsO_4,吸收液直接用于ICP-MS测定,是辉钼矿Re-Os定年的关键技术环节。但实验发现,长时间放置的吸收液中Os信号强度显著降低。根据OsO_4化学性质推测原因在于一是挥发使吸收液Os含量减少,二是还原使+8价Os变成低价态,气态比例降低,若雾化效率不变,进入质谱仪的Os减少,两者都会导致信号降低,但具体影响情况不明,需深入研究。本文利用辉钼矿标准物质制备不同放置时间、酸度和温度的吸收液,对比上述条件对ICP-MS信号强度的影响。实验时将残余吸收液与稀释剂、氧化剂封入Carius管加热蒸馏,测定Os含量。结果表明:吸收液放置时间越长,酸度越低,温度越高,信号降幅越大,幅度达到3.2%~68.6%。室温下放置相同时间,低酸度吸收液的Os保存率高于高酸度吸收液,但Os信号强度低于后者,证明了挥发和还原共同导致信号衰减,且还原是主导原因。本文提出,冷冻(-18℃)可抑制OsO_4挥发,提高酸度(约3.5 mol/L)可减弱OsO_4还原,两者结合抑制信号衰减,提高了蒸馏法的灵活性和适用性。  相似文献   

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD     

Li Q.  Bao Z. 《大地构造与成矿学》2018,(4):699-717

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.  相似文献   

绿色交通目标下集装箱“公转铁”的CO2减排潜力评估     

陶学宗  吴琴  尹传忠 《气候变化研究进展》2019,15(6):660-669

为提高集装箱“公转铁”减排潜力评估结果的准确性,在分析“公转铁”减排原理的基础上,综合考虑空箱调运和重箱运输“门到门”运输链的干线运输、端点装卸、电力设备作业、集卡短驳、公铁中转等排放,引入反映活动类型、设备结构、能源生命周期排放的参数,对作业活动-方式结构-能耗强度-排放因子（ASIF）方法进行改进,建立“公转铁”减排潜力评估框架。以义乌—宁波港域出口集装箱运输为例,通过实地调研和公开文献获取数据,进行实证研究。结果表明,如果忽略必要因素将会导致每TEU运输需求“公转铁”的CO₂减排率被高估0.50~36.73个百分点;最佳“公转铁”情景可减排3.42万t CO₂,相应减排率为13.58%。研究结果可为政府相关部门客观评估“公转铁”的减排潜力、制定有效的“公转铁”政策措施提供理论支持。  相似文献   

温室气体排放的环境库兹涅茨曲线检验与减排路径的冲击动态——基于黑龙江省统计核算数据   总被引：1，自引：0，他引：1  

张滨  吕洁华 《气候变化研究进展》2019,15(1):84-94

基于2001-2015年黑龙江省温室气体排放统计核算数据,对地区GDP与温室气体排放的环境库兹涅茨曲线关系检验呈现倒U型,预期2019年达到理论拐点;通过偏最小二乘回归模型得到4个减排路径的年平均减排效果顺序依次为单位GDP化石能源消费量减少、经济结构调整、人均GDP增长、贸易结构变化;减排路径对应脉冲响应函数的动态冲击效果分别为波动性增排、收敛性减排、发散性减排、转变的排放作用;推动黑龙江省温室气体减排的路径顺序为控制化石能源消费量、优化经济结构、发展低碳经济、调整贸易结构。  相似文献   

Flood insurance arrangements in the European Union for future flood risk under climate and socioeconomic change     

《Global Environmental Change》2019

Flood risk will increase in many areas around the world due to climate change and increase in economic exposure. This implies that adequate flood insurance schemes are needed to adapt to increasing flood risk and to minimise welfare losses for households in flood-prone areas. Flood insurance markets may need reform to offer sufficient and affordable financial protection and incentives for risk reduction. Here, we present the results of a study that aims to evaluate the ability of flood insurance arrangements in Europe to cope with trends in flood risk, using criteria that encompass common elements of the policy debate on flood insurance reform. We show that the average risk-based flood insurance premium could double between 2015 and 2055 in the absence of more risk reduction by households exposed to flooding. We show that part of the expected future increase in flood risk could be limited by flood insurance mechanisms that better incentivise risk reduction by policyholders, which lowers vulnerability. The affordability of flood insurance can be improved by introducing the key features of public-private partnerships (PPPs), which include public reinsurance, limited premium cross-subsidisation between low- and high-risk households, and incentives for policyholder-level risk reduction. These findings were evaluated in a comprehensive sensitivity analysis and support ongoing reforms in Europe and abroad that move towards risk-based premiums and link insurance with risk reduction, strengthen purchase requirements, and engage in multi-stakeholder partnerships.  相似文献   

屈曲约束支撑滞回曲线模型和刚度方程的建立   总被引：3，自引：0，他引：3  

李国强  胡宝琳 《地震工程与工程振动》2007,27(2):26-31

针对屈曲约束支撑,本文根据其反复荷载作用下的滞回特征,提出了一种滞回模型,并建立了屈曲约束支撑的弹塑性刚度方程。根据这种模型编制程序模拟绘制了屈曲约束支撑的滞回曲线,将模拟计算曲线与试验所得曲线进行对比,对比结果表明本文所提模型是准确、有效的。  相似文献   

高层隔震建筑设计中隔震支座受拉问题分析   总被引：11，自引：0，他引：11  

程华群  刘伟庆  王曙光 《地震工程与工程振动》2007,27(4):161-166

高层建筑由于高宽比相对较大,倾覆效应明显,当采用隔震技术时,有可能使隔震支座出现拉应力,而通常使用的叠层橡胶隔震支座抗拉能力不强。因此,隔震支座受拉问题成为隔震技术在高层建筑中推广应用的主要障碍之一。本文提出了避免隔震支座受拉的上部结构布置原则及隔震层优化设计方法,并对目前隔震支座拉应力计算方法提出了改进建议。本文的研究工作可为工程设计提供借鉴,为隔震设计相关规范的修订提供依据。  相似文献   

主动变刚度-阻尼系统预测最优控制的理论与试验研究     

谭平  阎维明  周福霖 《地震工程与工程振动》2007,27(4):139-146

介绍了一种具有自主知识产权的新型开关控制型半主动控制系统——主动变刚度.阻尼(AVS.D)系统的减振控制机理,建立了AVS.D结构振动控制体系的运动方程。为了合理补偿AVS.D系统实时控制过程中不可避免地存在着的控制时滞,本文提出一种预测最优控制算法,推导了其开关控制律。为了检验AVS.D系统的减震控制效果及预测最优控制算法的有效性,我们设计研制出AVS.D装置,编制了AVS.D系统预测最优控制的实时控制软件,在某单层钢框架模型上进行了AVS.D系统的模拟地震振动台试验,比较了不同控制方式时的减震效果。研究结果表明,本文所提出的预测最优控制算法是非常有效的,可推广应用于所有开关控制型半主动控制系统。AVS.D系统具有反应放大功能,经济可靠、安全有效,可望有较好的工程应用前景。  相似文献   

某边坡变形破坏机理的数值分析   总被引：3，自引：0，他引：3  

黄建南  叶明理 《工程地质学报》2007,15(6):779-783

某花岗岩矿岩土体主要有填土、粉质粘土、淤泥及淤泥质土、含泥中粗砂、粘土、残积砂质粘土,其下为花岗岩基岩。边坡最大高度75m,其中残积土层以上的土质边坡高度约50m。本文运用有限元强度折减法对该边坡的稳定性进行了研究,得出了潜在的破坏模式及各个滑动部分的安全系数。分析结果表明,本边坡存在3个潜在滑动面,其中两个为浅层滑动面,另一个为深层滑动面。两个浅层滑动面的稳定系数在1.13～1.17,处于临界状态。深层滑动面稳定性系数在1.29,目前尚处在相对稳定状态。根据分析结果,提出了如下加固措施:（1）对滑坡体进行削坡处理;（2）在其滑动面下方设置抗滑台阶;（3）采用预应力锚索框架梁结合肋柱进行加固处理。  相似文献   

Performance of pile-restrained flexible floating breakwaters     

Ioanna Diamantoulaki  Demos C. Angelides  George D. Manolis 《Applied Ocean Research》2008,30(4):243-255

The overall performance of pile-restrained flexible floating breakwaters is investigated under the action of linear monochromatic incident waves in the frequency domain. The aforementioned floating breakwaters undergo only vertical structural deflections along their length and are held in place by means of vertical piles. The total number of degrees of freedom equals the six conventional body modes, when the breakwater moves as a rigid body, plus the extra bending modes. These bending modes are introduced to represent the structural deflections of the floating breakwater and are described by the Bernoulli–Euler flexible beam equation. The number of bending modes introduced is determined through an appropriate iterative procedure. The hydrostatic coefficients corresponding to the bending modes are also derived. The numerical analysis of the flexible floating breakwaters is based on a three-dimensional hydrodynamic formulation of the floating body. A parametric study is carried out for a wide range of structural stiffness parameters and wave headings, to investigate their effect on the performance of flexible floating breakwaters. Moreover, this performance is compared with that of the corresponding pile-restrained rigid floating breakwater. Results indicated that the degree of structural stiffness and the wave heading strongly affect the performance of flexible floating breakwaters. The existence of an “optimum” value of structural stiffness is demonstrated for the entire wave frequency range.  相似文献