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961.
Opencast mining alters surface and subsurface hydrology of a landscape both during and post‐mining. At mine closure, following opencast mining in mines with low overburden to coal ratios, a void is left in the final landform. This final void is the location of the active mine pit at closure. Voids are generally not infilled within the mines' lifetime, because of the prohibitive cost of earthwork operations, and they become post‐mining water bodies or pit lakes. Water quality is a significant issue for pit lakes. Groundwater within coal seams and associated rocks can be saline, depending on the nature of the strata and groundwater circulation patterns. This groundwater may be preferentially drawn to and collected in the final void. Surface runoff to the void will not only collect salts from rainfall and atmospheric fallout, but also from the ground surface and the weathering of fresh rock. As the void water level rises, its evaporative surface area increases, concentrating salts that are held in solution. This paper presents a study of the long term, water quality trends in a post‐mining final void in the Hunter Valley, New South Wales, Australia. This process is complex and occurs long term, and modelling offers the only method of evaluating water quality. Using available geochemical, climate and hydrogeological data as inputs into a mass‐balance model, water quality in the final void was found to increase rapidly in salinity through time (2452 to 8909 mg l−1 over 500 years) as evaporation concentrates the salt in the void and regional groundwater containing high loads of salt continues to flow into the void. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
962.
Desert pavements (DPs) are critical for maintaining ecological stability and promoting near-surface hydrological cycling in arid regions. However, few studies have focused on eco-hydrological processes of DPs in the ecological systems of fluvial fans. Although DP surfaces appear to be barren and flat, we found that the surfaces are characterized by surface mosaic patterns of desert pavement (mosaic DP) and bare ground (mosaic BG). We investigated the effects of mosaic DP on water infiltration and vegetation distribution at six sites in fluvial fans (one on a hillside and five within the sectors of fans) along a southwest belt transect in northern Linze County, in the central Hexi Corridor (China). We found significant differences in mosaic DP between the hillside and sector sites in terms of pavement thickness and vesicular horizon thickness (Av thickness), particle composition, and bulk density, although significant differences were absent for mass soil water content, gravel coverage, and surface gravel size. The mosaic DP inhibited water infiltration by the pavement layer, where the sorptivity (S), initial infiltration rate (iint), steady-state infiltration rate (isat) and infiltration time (T) averaged 1.19 cm/min-0.5, 0.64 cm/min, 0.13 cm/min and 12.76 min, respectively. Where the pavement layer was scalped, the S, iint, and isat increased by 0.27 cm/min-0.5, 0.52 cm/min, and 0.40 cm/min, respectively, and the T reduced by 7.42 min. Water infiltration was mainly controlled by the pavement layer thickness (+), Av thickness (−), surface gravel coverage (−), fine earth (+) and fine gravel (−) in the pavement layer. The DP surfaces only had a sparse covering of shrubs, but an abundance of herbs. Few shrubs were present on the mosaic DP, but a greater number of shrubs and herbs grew on the mosaic BG. It can be concluded that DPs can maintain vegetation stability for different surface mosaic patterns. This study deepens our understanding of the eco-hydrological cycle of DP landscapes in arid regions.  相似文献   
963.
The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the 87Sr/86Sr, δ13CDIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
964.
Urban expansion and the scarcity of water supplies in arid and semiarid regions have increased the importance of urban runoff to localized water resources. However, urban catchment responses to precipitation are poorly understood in semiarid regions where intense rainfall often results in large runoff events during the short summer monsoon season. To evaluate how urban runoff quantity and quality respond to rainfall magnitude and timing, we collected stream stage data and runoff samples throughout the 2007 and 2008 summer monsoons from four ephemeral drainages in Tucson, Arizona. Antecedent rainfall explained 20% to 30% of discharge (mm) and runoff ratio in the least impervious (22%) catchment but was not statistically related to hydrologic responses at more impervious sites. Regression models indicated that rainfall depth, imperviousness and their combined effect control discharge and runoff ratios (p < 0.01, r2 = 0.91 and 0.75, respectively). In contrast, runoff quality did not vary with imperviousness or catchment size. Rainfall depth and duration, time since antecedent rainfall and event and cumulative discharge controlled runoff hydrochemistry and resulted in five specific solute response patterns: (i) strong event and seasonal solute mobilization (solute flush), (ii) event chemostasis and strong seasonal flush, (iii) event chemostasis and weak seasonal flush, (iv) event and seasonal chemostasis and (v) late seasonal flush. Our results indicate that hydrologic responses of semiarid catchments are controlled by rainfall partitioning at the event scale, whereas wetting magnitude, frequency and timing alter solute stores readily available for transport and control temporal runoff quality. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
965.
Asim Biswas  Bing Cheng Si 《水文研究》2012,26(24):3669-3677
There are various factors governing the spatial and temporal variability of soil water storage including soil properties, topography and vegetation. Some factors act locally, whereas others act nonlocally, which means that a factor measured at one location has effect on soil water storage at another location. The objective of this study was to examine the effects of local and nonlocal controls of soil water storage in a hummocky landscape using cyclical correlation analysis. Soil water storage, soil properties and terrain indices were measured along a 128‐point transect of 576 m long from the semiarid, hummocky, prairie pothole region of North America. There are large coefficients of determination (r2) between soil water storage and sand content (r2 = 0.32–0.53), organic carbon content (r2 = 0.22–0.56), depth to carbonate layer (r2 = 0.13–0.63), wetness index (r2 = 0.25–0.45) and other variables at the measurement scale at different times, indicating strong local effects from these variables. The correlation coefficients were also calculated by physically shifting the spatial series of soil water storage with respect to that of controlling factors. The shifting improves the correlation between the spatial series, and the length of shifting indicated the difference in the response of soil water to its controlling factors. For example, the value of r2 increased more than eightfold (r2 = 0.47–0.64) after shifting the spatial series of soil water storage by 54 m, almost equal to the average length of existing slope, compared with the very weak correlation (r2 = 0.02–0.08) at the measurement scale. This indicated the nonlocal effect from the relative elevation. The identification of nonlocal effects from factors improves the prediction of soil water storage. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
966.
There are several methods for determining the spatial distribution and magnitude of groundwater inputs to streams. We compared the results of conventional methods [dye dilution gauging, acoustic Doppler velocimeter (ADV) differential gauging, and geochemical end‐member mixing] to distributed temperature sensing (DTS) using a fibre‐optic cable installed along 900 m of Ninemile Creek in Syracuse, New York, USA, during low‐flow conditions (discharge of 1·4 m3 s?1). With the exception of differential gauging, all methods identified a focused, contaminated groundwater inflow and produced similar groundwater discharge estimates for that point, with a mean of 66·8 l s?1 between all methods although the precision of these estimates varied. ADV discharge measurement accuracy was reduced by non‐ideal conditions and failed to identify, much less quantify, the modest groundwater input, which was only 5% of total stream flow. These results indicate ambient tracers, such as heat and geochemical mixing, can yield spatially and quantitatively refined estimates of relatively modest groundwater inflow even in large rivers. DTS heat tracing, in particular, provided the finest spatial characterization of groundwater inflow, and may be more universally applicable than geochemical methods, for which a distinct and consistent groundwater end member may be more difficult to identify. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
967.
Abstract

Knowledge of the hydrochemical dynamics of the trace metal manganese (Mn) in upland catchments is required for water quality management. Stream water Mn and other solutes and flow were monitored in two upland catchments in northern England with different soils: one dominated by peat (HS7), the other by mineral soils (HS4). Maximum Mn concentrations occurred at different times in the two catchments: in summer baseflow at HS4 and during late summer storm events at HS7. A two-component chemical mixing model was used to identify the hydrological processes controlling Mn concentrations in stream water. This approach was more successful for HS4 than HS7, probably because of different processes of Mn release in the two catchments and also difficulties in selecting conservative solutes. Factor analysis of the stream water chemistry data set for each catchment was more useful in identifying the controls on Mn release into runoff. The factors indicate that the main source of Mn at HS4 is the hydrological pathway supplying summer baseflow, whereas at HS7 Mn is released during the rewetting of dried peat soils. Manganese concentrations in stream water in upland catchments appear to depend on soil type and antecedent moisture conditions. This has implications for the design of sampling strategies in upland catchments and also for managing the quality of water supplies from such areas.  相似文献   
968.
The growing concern for health‐related problems deriving from pollutants leaching is driving national and international administrations to support the development of tools for evaluating the effects of alternate management scenarios and identifying vulnerable areas. Cropping systems models are powerful tools for evaluating leachates under different environmental, social, and management conditions. As percolating water is the transport vehicle for pollutants transport in soil, a reliable evaluation of water balance models is a fundamental prerequisite for investigating pesticides and nitrate fate. As specific approaches for the evaluation of multi‐layer evolution of state variables are missing, we propose a fuzzy‐based, integrated indicator (ISWC: 0, best; 1, worst) for a comprehensive evaluation of soil water content (SWC) simulations. We aggregated error metrics with others quantifying the homogeneity of errors across different soil layers, the capability of models to reproduce complex dynamics function of both time and soil depth, and model complexity. We tested ISWC on a sample dataset where the models CropSyst and CERES‐Wheat were used to simulate SWC for winter wheat systems. ISWC revealed that, in the explored conditions, the global assessment of the two models' performances allowed identification of CropSyst as the best (average ISWC = 0·441, with a value of 0·537 obtained by CERES‐Wheat), although each model prevailed for some of the metrics. CropSyst presented the highest accuracy (average agreement module = 0·400), whereas CERES‐Wheat's accuracy was slightly worse, although achieved with a simplified modelling approach (average Akaike Information Criterion = − 230·44), thereby favouring large‐area applicability. The non‐univocal scores achieved by the models for the different metrics support the use of multi‐metric evaluation approaches for quantifying the different aspects of water balance model performances. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
969.
The lower coastal plain of the Southeast USA is undergoing rapid urbanisation as a result of population growth. Land use change has been shown to affect watershed hydrology by altering stream flow and, ultimately, impairing water quality and ecologic health. However, because few long‐term studies have focused on groundwater–surface water interactions in lowland watersheds, it is difficult to establish what the effect of development might be in the coastal plain region. The objective of this study was to use an innovative improvement to end‐member mixing analysis (EMMA) to identify time sequences of hydrologic processes affecting storm flow. Hydrologic and major ion chemical data from groundwater, soil water, precipitation and stream sites were collected over a 2‐year period at a watershed located in USDA Forest Service's Santee Experimental Forest near Charleston, South Carolina, USA. Stream flow was ephemeral and highly dependent on evapotranspiration rates and rainfall amount and intensity. Hydrograph separation for a series of storm events using EMMA allowed us to identify precipitation, riparian groundwater and streambed groundwater as main sources to stream flow, although source contribution varied as a function of antecedent soil moisture condition. Precipitation, as runoff, dominated stream flow during all storm events while riparian and streambed groundwater contributions varied and were mainly dependent on antecedent soil moisture condition. Sensitivity analyses examined the influence of 10% and 50% increases in analyte concentration on EMMA calculations and found that contribution estimates were very sensitive to changes in chemistry. This study has implications on the type of methodology used in traditional forms of EMMA research, particularly in the recognition and use of median end‐member water chemistry in hydrograph separation techniques. Potential effects of urban development on important hydrologic processes (groundwater recharge, interflow, runoff, etc.) that influence stream flow in these lowland watersheds were qualitatively examined. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
970.
Abstract

Abstract The aim of this study was to estimate the uncertainties in the streamflow simulated by a rainfall–runoff model. Two sources of uncertainties in hydrological modelling were considered: the uncertainties in model parameters and those in model structure. The uncertainties were calculated by Bayesian statistics, and the Metropolis-Hastings algorithm was used to simulate the posterior parameter distribution. The parameter uncertainty calculated by the Metropolis-Hastings algorithm was compared to maximum likelihood estimates which assume that both the parameters and model residuals are normally distributed. The study was performed using the model WASMOD on 25 basins in central Sweden. Confidence intervals in the simulated discharge due to the parameter uncertainty and the total uncertainty were calculated. The results indicate that (a) the Metropolis-Hastings algorithm and the maximum likelihood method give almost identical estimates concerning the parameter uncertainty, and (b) the uncertainties in the simulated streamflow due to the parameter uncertainty are less important than uncertainties originating from other sources for this simple model with fewer parameters.  相似文献   
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