甘肃李坝金矿床的地球化学特征   总被引：2，自引：0，他引：2  

卢宗柳  周奇明  胡云沪 《矿产与地质》2000,14(5):321-324

研究表明,李坝金矿床的物质成分来源于容矿围岩舒家坝组,热液来源于大气降水深循环,属浅成低中温热液矿床。  相似文献   

大兴安岭北部伊列克得组玄武岩的地球化学特征   总被引：20，自引：0，他引：20  

葛文春  林强  李献华  吴福元  孙德有  尹成孝 《矿物岩石》2000,20(3):14-18

大兴安岭北部伊列克得组玄岩类具有富碱（Ｋ２Ｏ＋Ｎａ２Ｏ〉６．３７％）、高Ｋ２Ｏ（２．６２％～３．１１％）,高Ｋ２Ｏ／Ｎａ２Ｏ比值（０．７～０．８）和Ｔｈ／Ｔａ、Ｃｅ／Ｎｂ、Ｔａ／Ｎｂ比值,以及强烈富集大离子亲石元素（ＬＩＬＥ）和轻稀土元素（ＬＲＥＥ）的特征,属于钾玄质系列,低Ｓｒ／Ｎｄ比值（１３～１７．５）的特征类似于洋岛玄武岩,但其Ｔａ／Ｈｆ,Ｔｈ／Ｔａ比值特征及与Ａ型花岗岩共生等特征表明,钾玄  相似文献   

柴达木盆地盐湖K、B、Li资源的成矿地球化学系统          下载免费PDF全文

李建森  蔡进福  樊启顺  山发寿  凌智永  韩元红  张永兴 《盐湖研究》2022,30(3):12-20

柴达木盆地是我国极为重要的K、B、Li盐类资源富集区,承担着建设世界级盐湖产业基地的重任,却存在成矿规律不明确、可采卤水资源找矿效果不显著的瓶颈,盐湖资源面临着严重的可持续发展问题。本文强调将柴达木盆地盐湖作为一个地球化学系统进行探讨,重点梳理了盐湖元素富集机制的核心问题,集成分析了盐湖同位素地球化学所面临的机遇与挑战,并总结提出柴达木盆地盐湖K、B、Li成矿地球化学系统,以服务于盐湖成矿规律研究和资源勘查评价。盐湖成矿地球化学系统是指在地质单元和时空区域的多维系统内,控制成盐元素活化—迁移—富集—保存的多种地球化学过程子系统的总和,是各类地质动力条件、构造成矿要素、气候水文过程及所形成的矿床系列组合的有机整体,并十分注重地球化学在其中的应用。盐湖成矿地球化学系统的提出,可以在一定程度上对研究对象、研究技术方法体系和研究视角进行有效限定,属于盐湖矿床研究的一种思维方法,并有望为盐湖成矿规律研究提供一种科学范式。  相似文献   

THE GEOCHEMISTRY CHARACTERISTICS OF BLUESCHIST IN THE GANGMAR AREA, QIANGTANG BLOCK, TIBET     

Deng Xiguang  Ding Lin  Liu Xiaohan  An Yin  Paul A.Kapp  Michael A.Murphy  Craig E.Manning WT  ”BX 《地学前缘》2000,(Z1)

THE GEOCHEMISTRY CHARACTERISTICS OF BLUESCHIST IN THE GANGMAR AREA, QIANGTANG BLOCK, TIBET  相似文献   

The significance of surface complexation reactions in hydrologic systems: a geochemist's perspective   总被引：3，自引：0，他引：3  

C. Koretsky 《Journal of Hydrology》2000,230(3-4):127-171

Complexation reactions at the mineral–water interface affect the transport and transformation of metals and organic contaminants, nutrient availability in soils, formation of ore deposits, acidification of watersheds and the global cycling of elements. Such reactions can be understood by quantifying speciation reactions in homogeneous aqueous solutions, characterizing reactive sites at mineral surfaces and developing models of the interactions between aqueous species at solid surfaces. In this paper, the application of thermodynamic principles to quantify aqueous complexation reactions is described. This is followed by a brief overview of a few of the methods that have been used to characterize reactive sites on mineral surfaces. Next, the application of empirical and semi-empirical models of adsorption at the mineral–water interface, including distribution coefficients, simple ion exchange models, and Langmuir and Freundlich isotherms is discussed. Emphasis is placed on the limitations of such models in providing an adequate representation of adsorption in hydrological systems. These limitations arise because isotherms do not account for the structure of adsorbed species, nor do they account for the development of surface charge with adsorption. This is contrasted with more sophisticated models of adsorption, termed ‘surface complexation models’, which include the constant capacitance model, the diffuse layer model, the triple layer model and the MUSIC model. In these models, speciation reactions between surface functional groups and dissolved species control the variable surface charge build-up and the specific adsorption properties of minerals in aqueous solutions. Next, the influence of mineral surface speciation on the reactivity of adsorbed species and on far from equilibrium dissolution rates of minerals is discussed. Finally, the applicability of microscopic models of surface complexation to field-scale systems is explored and the need to integrate sophisticated surface chemical and hydrological modeling approaches is stressed.  相似文献   

胶东金矿区高钾-钾质脉岩地球化学与俯冲-壳幔作用研究   总被引：4，自引：2，他引：2  

孙景贵  胡受奚  凌洪飞 《岩石学报》2000,16(3)

胶东金矿区与金矿成矿伴生的脉岩为一套高钾 -钾质脉岩。根据地质、岩相学及与金矿化的时空关系 ,将主要岩石类型划分为煌斑岩、安山玢岩、英安玢岩类 ,它们分别形成与金矿化早期、同期和晚期 ;主要元素成分以富碱高钾、低钛为特征 ,成分变异具同源岩浆结晶分异演化的一般规律 ,早期以辉石和橄榄石、中晚期以角闪石和斜长石为主的矿物相分离结晶控制岩浆的演化 ;岩石明显富 Ba、Sr、Rb、K、L REE等大离子元素、强烈亏损 Cr、Ni及相对亏损 Th、Nb、Ti、Y等高场强元素元素 ,体现初始岩浆起源于富集地幔源区 ;大量的挥发组分及强烈的富集 Ba、Sr及低的 Sr/ Nd比值 ,指示源区为以俯冲陆源沉积为主、有玄武质洋壳参与的脱水、脱气等作用交代早期地幔楔形成的富集地幔源 ,初始岩浆是在中生代印支期形成的富集地幔向燕山期亏损方向演化的特定阶段发生低程度熔融形成 (熔融程度为 6 %～ 8% ) ;就位环境的不同是导致石英脉岩型与蚀变岩型矿区脉岩成岩作用有一定差别的主要原因  相似文献   

中国大陆科学钻探工程主孔地下流体特征及与地震活动的关系初步研究   总被引：9，自引：0，他引：9  

孙青  李圣强  罗立强 《地震》2005,25(1):15-21

收集了中国大陆科学钻探主孔工程(CCSD)主孔中117～2045 m深度地下流体某些组分(He、 Ar、 CO₂、 CH₄)的浓度资料和2001年7月1日至2002年4月30日时间段内钻孔周围500 km范围内震级M_L≥1.0地震目录资料, 对其流体资料进行日均值处理、 差分分析和最大相关系数处理。 由日均值浓度看出地震前后He、 Ar、 CO₂、 CH₄浓度存在明显异常; 最大相关系数分析表明, CH₄和CO₂组分两者相关性好, 最大相关系数平均值为0.95, 均方差为0.08, 说明两者可能具有相同的来源。 CH₄和CO₂浓度日均值最大相关系数在地震前后出现明显的异常波动。 主孔中的地下流体特征及与周围地震活动的对应关系揭示大陆科学钻探主孔中的地下流体异常与区内地震活动可能存在一定关系。  相似文献   

Geochemical characteristics of REY,Li, Ga trace elements in the No. 9 coal seam of the Daheng mine,Ningwu coalfield,Shanxi Province,China     

Jin-xi Wang  Zhi-heng Fu  Ya-fan Hu  Zhen Yang  Jia-liang Ma  Yu-zhuang Sun 《China Geology》2021,4(2):266-273

To understand the geochemical characteristics of the No.9 coal in the Daheng Mine of the Ningwu coalfield, the trace element analysis was conducted through X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). The sedimentary environment was discussed according to the element geochemical parameters. The results show that Li, Ga, Hf, Zr, Nb, Th, and Ta are slightly enriched in the No. 9 coal of Daheng Mine. The average value of the rare earth elements and yttrium (∑REY) in coal here is 144.20 μg/g (excluding parting), which is higher than the average value of ∑REY in the world ’s coal and China ’s coal. The light rare earth elements (LREY) are enriched. The content of Eu was 0.12–2.10 μg/g with an average of 0.57 μg/g, and the Eu is obviously negatively abnormal. Most of the trace elements in the coal are positively correlated with the ash content, which shows that the occurrence of these trace elements is related to inorganic minerals. The results of sequential chemical extraction experiments show that rare earth elements mainly exist in coal in the form of aluminosilicate. The value of the Sr/Ba and the content of S reflect that the coal-forming environment was influenced by seawater. The values of V/Cr and Ni/Co reflect that the peat swamp is in an anaerobic environment and a strongly reducing environment during the coal-forming period.  相似文献   

Assessment of the oil source-rock potential of the Pedregoso Formation (Early Miocene) in the Falcón Basin of northwestern Venezuela     

Jean Carlos Montero-Serrano  Manuel Martínez  Armelle Riboulleau  Nicolas Tribovillard  Gonzalo Márquez  José Vicente Gutiérrez-Martín 《Marine and Petroleum Geology》2010

The early Miocene Pedregoso Formation is one of the numerous formations rich in organic matter within the stratigraphic record of the Urumaco Trough, in the central area of the Falcón Basin. Due to its lithological characteristics and stratigraphic position, this formation is of great interest regarding the basin's petroliferous systems. The evaluation of various inorganic and organic geochemical parameters indicates that the organic matter is primarily of marine origin, deposited in a marine carbonate environment typical of reefal systems, under oxic-to-dysoxic conditions. The low variability in the TOC concentrations and in the distributions of the biomarkers extracted from the samples suggests that the paleoenvironmental conditions and the organic-matter supply remained approximately constant throughout the sedimentation of this unit. The Pedregoso type-II organic matter (marine origin) and initial organic richness value (∼1.8%) suggest that this unit has probably generated hydrocarbons within the Urumaco Trough. However, present-day thermal maturity parameters reveal that the Pedregoso organic matter is overmature (dry gas window), indicating that this unit is only capable to generate gas. In addition, the geothermal gradient, maturity parameters, and the maximum paleotemperature estimated in this study suggest that the Pedregoso Formation reached a maximum burial depth the ∼6.5 km, consistent with the value obtained from data of stratigraphic thickness in the Urumaco Trough. This implies that the thermal anomaly that affected the basin during the Late Eocene–Early Miocene did not reach the central part of the basin, and therefore, the organic matter maturation in this unit is due to the sedimentary burial.  相似文献   

西秦岭柴家庄、八卦山和天子山花岗岩体地球化学特征   总被引：3，自引：0，他引：3       下载免费PDF全文

毕明波  李永军  杨俊泉 《甘肃地质》2006,15(1):42-46

柴家庄、八卦山和天子山花岗岩体空间上紧密共生,岩性均为二长花岗岩,岩石具富硅、过铝、贫钙的地球化学特征,属钙碱性系列。3个岩体的大离子亲石元素蛛网图和稀土元素配分曲线相关性均较好。3个岩体受印支晚期断裂构造控制,成岩时代相近,是同源岩浆演化不同期次的产物,应统称为柴家庄—八卦山—天子山岩浆带。  相似文献