Emplacement Ages and Petrogenesis of the Molybdenum–bearing Granites in the Jinduicheng Area of East Qinling, China: Constraints from Zircon U–Pb Ages and Hf Isotopes     

LI Hongying  WANG Xiaoxi  YE Huishou  YANG Lei 《《地质学报》英文版》2012,86(3):661-679

The Mesozoic porphyry assemblage in the Jinduicheng area is a special molybdenum area in China, the Mo deposits, including the Jinduicheng, Balipo, Shijiawan, Huanglongpu, are distributed. The emplacement age and geochemical features of the granites in the Jinduicheng area can provide essential information for the exploration and development of the porphyry molybdenum deposit. In this study, we report LA–ICP–MS zircon U–Pb age and zircon Hf isotopic compositions of granite porphyries from the Jinduicheng area, and provide insights on the petrogensis and source characteristics of the granites. The results show that the zircon U–Pb ages of the Jinduicheng granite porphyry (143±1 Ma) and the Balipo granite (154±1 Ma), agree well with the Re–Os ages of molybdenite in the Jinduicheng molybdenum polymetallic deposit (139±3 Ma) and the Balipo molybdenum polymetallic deposit (156±2 Ma), indicating that the emplacement of granite porphyries occurred between Late Jurassic and Early Cretaceous. Zircons granite from the Jinduicheng area give the εHf(t) values mainly ranging from ?10 to ?16, and ?20 to ?24, respectively, corresponding to two–stage model ages (tDM2: mainly focused on 1.86–2.0 Ga, and 2.2–2.6 Ga, respectively) of zircons of the granite from the Jinduicheng values. The ore–forming materials are mainly derived from crust, with minor mantle substances. Zircons of the granite from the Balipo area give εHf(t) values ranging from ?18 to ?20, ?28 to ?38, and ?42 to ?44, respectively, corresponding to two–stage model ages (tDM2: mainly focused on 1.88–3.0 Ga, and 3.2–3.90 Ga, respectively). the εHf(t) values of the Jinduicheng porphyry more than that of the Balipo porphyry, and two–stage model ages (tDM2) less than that of the Balipo porphyry, shows that he source of the porphyries originated from ancient lower crustal materials in the Jinduicheng area, and mixed younger components, more younger components contributed for the source of the Jinduicheng porphyry.  相似文献   

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects     

German Velásquez  Anastassia Y. Borisova  Stefano Salvi  Didier Béziat 《Geostandards and Geoanalytical Research》2012,36(3):315-324

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.  相似文献   

Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)   总被引：1，自引：0，他引：1  

Gómez C  Vicente J  Echavarri-Erasun B  Porte C  Lacorte S 《Marine pollution bulletin》2011,62(5):948-955

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.  相似文献   

新疆乌苏5.1级地震前波速比异常震例研究   总被引：7，自引：0，他引：7  

龙海英  聂晓红  唐兰兰 《地震研究》2011,34(2):126-130

利用天山中段数字化地震波资料,采用多台和达法,计算2006年11月23日新疆乌苏5.1级地震前后波速比的变化情况,得到如下结果:(1)在空间分布上,乌苏5.1级地震前,波速比形成一个近似椭圆形低值异常区,且椭圆长半轴约为70 km,短半轴约为55 km,椭圆走向NW,地震就发生在该椭圆区域的西北部边缘;(2)在时间进程...  相似文献   

汶川8.0级地震前后陇南地区地震宏观异常调查及分析          下载免费PDF全文

严武建  朱朝霞  李晓峰  张辉 《地震工程学报》2011,33(1):67-70,90

根据对2008年5月12日汶川8.0级大地震前后(2008年4月1日至7月13日)甘肃省陇南地区及甘南州舟曲县宏观异常的震后现场调查结果,经过资料整理分析和挑选可靠异常现象,对其时空分布特征进行了研究.结果表明,在时间上宏观异常的数量临近地震逐渐增多,在临震前形成峰值;在空间上宏观异常的分布在高烈度区较多.对宏观异常与震源机制关系以及宏观异常对地震预测可能发挥的作用等问题进行了讨论.  相似文献   

汶川Ms8.0地震灾害的非对称分布与成因分析          下载免费PDF全文

周庆  张春山  陈献程 《地震学报》2011,33(4):492-504

在汶川Ms8.0地震中,地震灾害在灾区相对于发震断层,呈现各种非对称分布.断层高角度逆冲诱发的崩塌、滑坡的规模与数量在断层上盘区远远高于断层下盘区,在垂直断层方向,高烈度区断层上盘宽度往往大于下盘宽度,上述不对称性反映了逆断层型地震存在加速度峰值的上盘效应;而在破裂的传播方向存在的地震波多普勒效应则造成沿长轴方向东北部...  相似文献   

福建武平地区桃溪群混合岩U-Pb定年及其Hf同位素组成:对桃溪群时代及郁南运动的约束   总被引：4，自引：2，他引：2  

张爱梅  王岳军  范蔚茗  张菲菲  张玉芝 《大地构造与成矿学》2011,35(1):64-72

桃溪群混合岩位于南岭东段武夷山褶皱带南段.本文通过采自桃溪附近帽村-田园两个代表性花岗片麻岩样品进行LA-ICP-MS锆石U-Pb 测年获得494～496Ma的结晶年龄,641～657Ma和799Ma两组继承锆石的206Pb/238U 表观年龄.同时对样品FJ-137进行的Hf同位素测定表明其εHf(t)变化于-2.3...  相似文献   

In Situ Determination of First‐Row Transition Metal,Ga and Ge Abundances in Geological Materials via Medium‐Resolution LA‐ICP‐MS     

Ricardo Arevalo Jr  William F. McDonough  Philip M. Piccoli 《Geostandards and Geoanalytical Research》2011,35(2):253-273

An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising ⁴³Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 10⁰ μg g^?1 and as high as > 10⁴ μg g^?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2s_m). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials.  相似文献   

Uranium and Thorium Concentration and Isotopic Composition in Five Glass (BHVO‐2G,BCR‐2G,NKT‐1G,T1‐G,ATHO‐G) and Two Powder (BHVO‐2, BCR‐2) Reference Materials     

Kathryn A. Matthews  Michael T. Murrell  Steven J. Goldstein  Andrew J. Nunn  Deborah E. Norman 《Geostandards and Geoanalytical Research》2011,35(2):227-234

Here we report uranium and thorium isotopic ratios and elemental concentrations measured in solid reference materials from the USGS (BHVO‐2G, BCR‐2G, NKT‐1G), as well as those from the MPI‐DING series (T1‐G, ATHO‐G). Specifically created for microanalysis, these naturally‐sourced glasses were fused from rock powders. They cover a range of compositions, elemental concentrations and expected isotopic ratios. The U‐Th isotopic ratios of two powdered source materials (BCR‐2, BHVO‐2) were also characterised. These new measurements via multi‐collector thermal ionisation mass spectrometry and multi‐collector inductively coupled plasma‐mass spectrometry can now be used to assess the relative performance of techniques and facilitate comparison of U‐Th data amongst laboratories in the geoscience community for in situ and bulk analyses.  相似文献   

紫菜特征挥发性物质分析   总被引：5，自引：0，他引：5       下载免费PDF全文

胡传明  徐继林  朱建一  严小军  骆其君  杨家新  许璞 《海洋科学》2011,35(5):106-111

应用顶空固相微萃取和气相色谱-质谱联用技术,对坛紫菜(Porphyra haitanensis)、条斑紫菜(Porphyra yezoensis)与其一个突变品系的生长藻体挥发性物质进行分析,共分离鉴定出66种挥发性组分,3个紫菜试样中分别含有36、44和45种.鉴定组分中有21种为紫菜共有挥发性物质,其中8-十七烯和...  相似文献