三元体系Li~+,Mg~(2+)∥SO_4~(2-)—H_2O 25℃相关系及溶液物化性质的研究          下载免费PDF全文

李冰  房春晖  王庆忠  李军  宋彭生 《盐湖研究》1993,(3)

研究了三元体系Li~+,Mg~(2+)∥SO_4~(2-)—H_2O在25℃时的相关系和平衡液相的密度、粘度、折光率、电导等物化性质,该体系为简单共饱型,两段溶解度曲线对应于体系的两种原始组份Li_2SO_4·H_2O和MgSO_4·7H_2O的结晶区,无复盐和固溶体形成,亦无脱水作用发生,应用电解质溶液Pitzer模型检测该体系25C的溶解度,并用经验或半经验公式对平衡液相的密度和折光率进行了理论计算,计算值与实验值非常接近。  相似文献   

全波震相分析的应用   总被引：10，自引：0，他引：10  

赵鸿儒  孙进忠等 《地球物理学报》1990,33(1):54-63

全波震相分析法是以弹性波传播理论为基础,以现代数字技术为手段,对地震波进行全面综合分析的理论和方法.它既包括对单一分量震波观测记录中的各种震相的识别、确认和分析,又包括对多分量震波记录的合成、分析和图示.全波震相分析法涉及震源、射线路径、初动、走时、振幅、波形、时域和空域的瞬态谱、质点振动矢量等诸多方面,因而能更全面地揭示地震波场与地下介质之间的关系.本文以实例展示在不同领域的研究中全波震相分析的应用情况.全波震相分析法为实现多种波型的联合应用奠定了理论基础,并提供了新的方法.  相似文献   

The nature and distribution of fluids during amphibolite facies metamorphism, Naxos (Greece)   总被引：1，自引：0，他引：1  

I. S. BUICK  T. J. B. HOLLAND 《Journal of Metamorphic Geology》1991,9(3):301-314

On the basis of fluid inclusion evidence, pervasive influx of deep-seated CO₂-rich fluids has been invoked to account for mid- to upper amphibolite facies (M2_B) metamorphism on the island of Naxos (Cyclades, Greece). In this paper, mineral devolatilization and melt equilibria are used to constrain the composition of both syn- and post-peak-M2_B fluids in the deepest exposed levels of the metamorphic complex. The results indicate that peak-M2_B fluids were spatially and compositionally heterogeneous throughout the high-grade core of the complex, whereas post-peak-M2_B fluids were generally water-rich. The observed heterogeneities in syn-M2_B fluid composition are inconsistent with pervasive CO₂-flushing models invoked by previous workers on the basis of fluid inclusion evidence. It is likely that few CO₂-rich fluid inclusions on Naxos preserve fluids trapped under peak metamorphic conditions. It is suggested that many of these inclusions have behaved as chemically open systems during the intense deformation that accompanied the uplift of the metamorphic complex. A similar process may explain the occurrence of some CO₂-rich fluid inclusions in granulite facies rocks.  相似文献   

精密引潮位展开及某些诠释   总被引：8，自引：2，他引：8       下载免费PDF全文

郗钦文 《地球物理学报》1991,34(2):182-194

作者再次改进了引潮位展开,潮波振幅给到小数后第六位,共3070个潮波.文中论述了引潮位展开的精度,同时给出为了保证潮汐计算的高精度而所需引入的各项改正及其说明.  相似文献   

氧化镍、二氧化钛高压相变及电导率压力效应   总被引：1，自引：0，他引：1       下载免费PDF全文

熊大和  刘顺 《地球物理学报》1994,37(1):120-123

采用金刚石对顶砧压腔静高压技术，对氧化镍、二氧化钛在０-３２ＧＰａ压力范围内的电导率进行了测量．结果表明，电导率－压力关系曲线上的一些特征点与同一物质的高压相交点具有一致性．  相似文献   

东台吉乃尔盐湖卤水的相化学研究（Ⅱ）—冬夏季卤水蒸发实验   总被引：1，自引：0，他引：1       下载免费PDF全文

张宝全  刘铸唐 《盐湖研究》1994,2(3):27-34

为了研究东台吉乃尔盐湖卤水蒸发时的相化学，确定钾、镁和锂盐的结晶特性，在实验室内２５℃等温蒸发实验基础上和自然条件下进行了冬夏季日晒蒸发试验．东台吉乃尔盐湖卤水是由氯化钠饱和的多组分复杂体系构成的．卤水中存在的离子是Ｎａ＋、Ｋ＋、Ｍｇ２＋、Ｌｉ＋、Ｃａ２＋、Ｂ３＋、ＳＯ４２－和Ｃｌ－．试验数据与Ｎａ＋、Ｋ＋、Ｍｇ２＋Ｃｌ－、ＳＯ４２－ＫＨ２Ｏ五元体系介稳平衡数据进行了讨论和比较．Ａｕｔｅｎｒｉｅｔｈ相图被用来表示各数据间的关系和证明冬夏季蒸发时结晶行为的差别．  相似文献   

Nonequilibrium thermodynamics of pressure solution     

F. K. Lehner  J. Bataille 《Pure and Applied Geophysics》1984,122(1):53-85

This paper is concerned with the thermodynamic theory of solution and precipitation processes in wet crustal rocks and with the mechanism of steady pressure-solution slip in contact zones, such as grain-to-grain contacts, fracture surfaces, and permeable gouge layers, that are infiltrated by a mobile aqueous solution phase. A local dissipation jump condition at the phase boundary is fundamental to identifying the thermodynamic force driving the solution and precipitation process and is used here in setting up linear phenomenological relations to model near-equilibrium phase transformation kinetics. The local thermodynamic equilibrium of a stressed pure solid in contact with its melt or solution phase is governed by Gibbs's relation, which is rederived here, in a manner emphasizing its independence of constitutive assumptions for the solid while neglecting surface tension and diffusion in the solid. Fluid-infiltrated contact zones, such as those formed by rough surfaces, cannot generally be in thermodynamic equilibrium, especially during an ongoing process of pressure-solution slip, and the existing equilibrium formulations are incorrect in overlooking dissipative processes tending to eliminate fluctuations in superficial free energies due to stress concentrations near asperities, defects, or impurities. Steady pressure-solution slip is likely to exhibit a nonlinear dependence of slip rate on shear stress and effective normal stress, due to a dependence of the contact-zone state on the latter. Given that this dependence is negligible within some range, linear relations for pressure-solution slip can be derived for the limiting cases of diffusion-controlled and interface-reaction-controlled rates. A criterion for rate control by one of these mechanisms is set by the magnitude of the dimensionless quantityk/2C _pD, wherek is the interfacial transfer coefficient, is the mean diffusion path length,C _p is the solubility at pressurep, andD is the mass diffusivity.  相似文献   

陕西略阳煎茶岭镍矿床成矿及矿石变质过程的地球化学研究     

Zhang Benren Chen Dexing Hu Yikeng 《地球科学》1986,(4)

矿床中存在着岩浆离熔成因的磁黄铁矿-镍黄铁矿矿石和热液改造成因的黄铁矿-针镍矿-辉镍矿矿石。研究证明现在矿石中存在的硫化物均为较低温度条件下的变质产物,并且矿物组合的更替不仅同温度变化有关,同时还受体系中氧逸度和硫离子活度的控制。矿物组合的地球化学分析表明,现有Fe-Ni-S体系低温（<300℃）相平衡图解之间存在着矛盾的原因可能是忽略了氧化-还原条件的影响。  相似文献   

台湾琉球地区Lg波的震相特征     

陆南栋  傅建武 《华南地震》1995,15(1):30-37

根据浙闽台站记录的台湾琉球近震资料，研究了该区Ｌｇ波的组成及各震相的基本特征。研究表明，该区Ｌｇ波由多个速度不同的波群组成，在Ｌｇ１和Ｌｇ２两种波中可以分出Ｌｇ′１、Ｌｇ″１；和Ｌｇ′２、Ｌｇ″２四种震相，不同震区各震相的记录特征明显不同，鲜明地反映出地壳结构由大陆型向海洋型过渡的特点。此外，还对波列中的未知震相、影响震相记录特征的其它因素，以及震相标注和Ｌｇ波走时表等问题进行了讨论。  相似文献   

北京重力地球潮参数和重力仪力学特性的测定          下载免费PDF全文

郑金涵  刘克人  刘端法 《地球物理学报》1995,38(4):487-493

根据北京白家疃测站８台ＧＥＯ潮汐重力仪对比观测的资料，采用标准线性体流变模型模拟重力仪及记录系统的力学特性，计算各台仪器的格值改正系数、主潮汐波的振幅衰减系数和相位滞后；确定北京重力地球潮的振幅因子δ和相让滞后为δ（Ｍ_２）＝１．１７８４，δ（Ｏ_１）＝１．１８０４，δ（Ｍ_２）／δ（Ｏ_１）＝０．９９８３，（Ｍ_２）＝０．０７°，（Ｏ_１）＝０．１０°．  相似文献