绿藻水溶性多糖的研究概况和进展   总被引：1，自引：0，他引：1  

李莎兰  洪亮  李诚博  刘晨光 《海洋科学》2016,40(9):145-151

对近年来绿藻多糖的提纯方法、组成结构及应用的研究进展进行了综述。绿藻多糖的提纯需要经过样品的前处理、提取和精制三个步骤,提取方法包括酸提、酶提、加入钙螯合剂提取、微波及超声波辅助提取。绿藻多糖是水溶性的硫酸化杂多糖。从石莼(Ulva)、浒苔(Enteromorpha)、礁膜(Monostroma)、小球藻(Chlorella)、蕨菜(Bracken)及刚毛藻(Bristles)中提取的多糖的化学组成及结构特征各不相同,而且多糖的化学组成和结构特征受提取方式的影响。绿藻多糖的生物相容性、生物可降解性及抗氧化、抗肿瘤、抗凝血、抗炎、免疫调节等多种生物活性使其在食品、医药、化妆品及农业中具有广泛的应用。有关绿藻多糖的精确结构、提纯方法及化学修饰的进一步研究将使绿藻多糖的应用更加广泛。  相似文献   

Apatite Composition of Representative Magnetite‐series and Ilmenite‐series Granitoids in Japan          下载免费PDF全文

Shunso Ishihara  Takeru Moriyama 《Resource Geology》2016,66(1):55-62

Apatites of representative magnetite‐series and ilmenite‐series granitoids were studied in the Japanese Islands. Concentrations of the volatile components F, Cl and SO₃ are differently distributed in apatites of these granitoid series. Apatites are always fluoroapatite. They have weakly higher F content in the ilmenite series than in the magnetite series. In contrast, Cl and SO₃, are significantly concentrated in apatites of the magnetite series compared to the ilmenite series. These characteristics reflect the original concentrations of these components in the host granitic magmas. A high fO₂ seems most important for the S‐concentration as sulfate in apatite of the magnetite series. REE and Y are only erratically high in the studied apatites.  相似文献   

黄铁矿ReOs法测年在胶东金矿中的应用初探          下载免费PDF全文

李洪奎  耿科  禚传源  梁太涛  张玉波 《山东国土资源》2016,32(4):1-6

该次工作为黄铁矿Re-Os法测年在胶东金矿中的首次应用。在大尹格庄金矿中获得了由3件黄铁矿样品组成的(144.8±1.8)Ma等时线年龄,暗示着大尹格庄金矿区可能存在一期晚侏罗世的Au成矿事件。通过对大尹格庄、夏甸、土堆金矿黄铁矿Re-Os同位素年代学的研究,表明黄铁矿的Re-Os同位素特征在胶东金矿中具有一定的复杂性。该文总结了影响黄铁矿Re-Os同位素测年结果的因素,认为在利用该方法进行金矿床定年时,应当将不同期次黄铁矿分别送样,适当拉大采样间距,并尽可能降低实验测试误差,以期获得更精确可靠的年龄。  相似文献   

西藏谢通门地区中侏罗世花岗岩的地球化学特征及时代依据     

王贝  李鹏  刘智贤  程龙  闫磊  王卫军 《地质通报》2016,35(9):1479-1487

西藏谢通门县一带区域上属于冈底斯花岗岩带南亚带,侵入岩极其发育,目前填绘有白垩纪、古近纪和新近纪岩体。通过同位素年代学研究,获得12个锆石的U-Pb同位素年龄数据,在原划归白垩纪、古近纪和新近纪岩体中解体出侏罗纪侵入体,按其岩石类型特征,归并为早侏罗世东热村序列和中侏罗世东嘎乡序列。其中,在约拉嘎莫岩体中获得锆石U-Pb同位素年龄166.9±2.8Ma,时代为中侏罗世巴柔期。  相似文献   

藏南错那淡色花岗岩LA-MC-ICP-MS锆石U-Pb年龄、岩石地球化学及其地质意义   总被引：10，自引：1，他引：9  

王晓先  张进江  闫淑玉  刘江 《地质通报》2016,35(1):91-103

藏南错那淡色花岗岩位于喜马拉雅造山带的东部。对其进行LA-MC-ICP-MS锆石U-Pb定年,结果显示,结晶年龄为17.7±0.3Ma,代表中新世的地壳深熔作用。淡色花岗岩样品具有高的Si O2(74.46%~75.57%)、Al2O3(14.07%~14.64%)和K2O(4.19%~4.85%)含量,高的K2O/Na2O值(1.09~1.31)和A/CNK值(1.15~1.25),富集Rb、Th和U,亏损Ba、Nb、Sr、Zr等元素,显示高的Rb/Sr值(17.75~29.50)和强烈的负Eu异常(δEu=0.18~0.26),属于壳源成因的高钾钙碱性过铝质S型花岗岩。样品具有高的Isr值(0.78982~0.79276)和低的εNd(t)值(-19.5~-18.2),可与大喜马拉雅结晶杂岩(GHC)中的变泥质岩对比,暗示其来自变泥质岩的部分熔融。样品的Isr值较高,而Sr浓度较低,且随着Ba浓度的增加,Rb/Sr值逐渐降低,表明淡色花岗岩是无水条件下白云母部分熔融的产物,部分熔融可能与藏南拆离系(STDS)伸展拆离导致的构造减压有关。错那淡色花岗岩的形成反映了地壳伸展减薄背景下,构造减压导致的中下地壳中含水矿物脱水熔融,并沿STDS上升侵位的动力学过程。  相似文献   

云南磷铝石谱学特征研究   总被引：1，自引：0，他引：1  

魏中枢  狄敬如 《岩石矿物学杂志》2018,37(1):169-174

使用电子探针、X射线粉晶衍射仪、傅里叶变换红外光谱仪、激光拉曼光谱仪、紫外可见分光光度计等仪器,对最近在云南发现的一种达到宝石级别的磷铝石进行了化学成分、矿物组成、红外吸收光谱、拉曼光谱、紫外可见吸收光谱等方面的研究。化学成分分析结果表明,该磷铝石的主要化学成分为P和Al,并含有少量的Fe和V;X射线粉晶衍射结果显示,该磷铝石的矿物成分主要为磷铝石,杂质较少;红外光谱与拉曼光谱分析均检出磷酸根基团的特征峰,红外光谱分析还显示有结晶水与结构水的存在;紫外可见吸收光谱在300和420 nm附近的吸收归属于Fe3+,630 nm附近较宽缓的吸收带由Fe3+和V3+共同产生。并将磷铝石与绿松石进行了谱学方面的对比分析,以便更好地区分两者。  相似文献   

Nature and source of the ore-forming fluids associated with orogenic gold deposits in the Dharwar Craton     

Biswajit Mishra  Kamal Lochan Pruseth  Pranjit Hazarika  Sakthi Saravanan Chinnasam 《地学前缘(英文版)》2018,9(3):715-726

Neoarchean orogenic gold deposits, associated with the greenstone-granite milieus in the Dharwar Craton include(1) the famous Kolar mine and the world class Hutti deposit;(2) small mines at HiraBuddini, Uti, Ajjanahalli, and Guddadarangavanahalli;(3) prospects at Jonnagiri; and(4) old mining camps in the Gadag and Ramagiri-Penakacherla belts. The existing diametric views on the source of ore fluid for formation of these deposits include fluids exsolved from granitic melts and extracted by metamorphic devolatilization of the greenstone sequences. Lode gold mineralization occurs in structurally controlled higher order splays in variety of host rocks such as mafic/felsic greenstones, banded iron formations, volcaniclastic rocks and granitoids. Estimated metamorphic conditions of the greenstones vary from lower greenschist facies to mid-amphibolite facies and mineralizations in all the camps are associated with distinct hydrothermal alterations. Fluid inclusion microthermometric and Raman spectroscopic studies document low salinity aqueous-gaseous(H_2O + CO_2 ± CH_4 + NaCl) ore fluids,which precipitated gold and altered the host rocks in a narrow P-T window of 0.7-2.5 kbar and 215-320℃. While the calculated fluid O-and C-isotopic values are ambiguous, S-isotopic compositions of pyrite-precipitating fluid show distinct craton-scale uniformity in terms of its reduced nature and a suggested crustal sulfur source.Available ages on greenstone metamorphism, granitoid plutonism and mineralization in the Hutti Belt are tantamount, making a geochronology-based resolution of the existing debate on the metamorphic vs.magmatic fluid source impossible. In contrast, tourmaline geochemistry suggests involvement of single fluid in formation of gold mineralization, primarily derived by metamorphic devolatilization of mafic greenstones and interlayered sedimentary rocks, with minor magmatic contributions. Similarly, compositions of scheelite, pyrite and arsenopyrite point toward operation of fault-valves that caused pressure fluctuation-induced fluid phase separation, which acted as the dominant process of gold precipitation,apart from fluid-rock sulfidation reactions. Therefore, results from geochemistry of hydrothermal minerals and those from fluid inclusion microthermometry corroborate in constraining source of ore fluid,nature of gold transport(by Au-bisulfide complex) and mechanism of gold ore formation in the Dharwar Craton.  相似文献   

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation     

A.A. Vorontsov  O.Yu. Perfilova  N.N. Kruk 《Russian Geology and Geophysics》2018,59(12):1640-1659

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.  相似文献   

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)     

V.V. Ryabov  O.N. Simonov  S.G. Snisar  A.A. Borovikov 《Russian Geology and Geophysics》2018,59(8):945-961

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.  相似文献   

Petrogenesis of the microcrystalline-dioritic enclaves from Jiuling granitoids in the eastern segment of Jiangnan Orogen and constraints on magma source materials     

《China Geology》2018,1(3):374-391

Numerous dark enclaves with different shapes are found in Jiuling Neoproterozoic granitoids. Precise LA-ICP-MS U-Pb dating was conducted on zircons extracted from two microcrystalline enclave samples, yielding crystallization ages of 822.6±5.8 Ma and 822.2±6.2 Ma, respectively. The consistent ages within analytical errors with the host granitoids suggested that they were the products of the same magmatism. The microcrystalline-dioritic enclaves commonly show plastic forms and contain similar plagioclase megacrysts to the host rocks, and both of the enclaves and host granitoids showed a complex composition and structural imbalance in plagioclases. Furthermore, the apatites with a euhedral acicular shape occurred widely in the microcrystalline-dioritic enclaves. All of these petrographic features above imply magma mixing is involved in their diagenesis. The enclaves and host granitoids show a marked zircon trace element difference and Hf isotopic signatures without correlation in zircon trace element pairs but form their own system between enclaves and host granitoids. Additionally, most of the zircons show extremely high ε_Hf (t) with ε_Hf (t) =3.54–11.94 from the southern samples, and ε_Hf (t) =1.0–9.09 from the central region. Some zircons with the higher ε_Hf (t) are similar to the zircons from the juvenile island arc in the eastern segment of Jiangnan Orogen. Integrated geological and Hf isotopic characteristics suggest microcrystalline-dioritic enclaves were derived from the partial melting process of the Mesoproterozoic crust which enriched juvenile island arc materials and mixed with the granitic magma that remelted from the Mesoproterozoic continental crust which relatively enriched ancient sediments and mixed with the host granitoid in diagenesis.  相似文献