Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution     

Nicolas Domange  Caroline Grégoire  Véronique Gouy  Michèle Tremolières 《Comptes Rendus Geoscience》2004,336(1):49-58

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).  相似文献   

同步辐射软X射线吸收谱与发射谱测定天然针铁矿能带结构     

丁聪  李艳  李岩  鲁安怀 《岩石矿物学杂志》2016,35(2):349-354

天然半导体矿物由于成分、缺陷复杂,传统测试方法如紫外可见漫反射等难以准确测定其禁带宽度.本文以针铁矿为例,通过第一性原理计算得到纯针铁矿及掺Al针铁矿的电子结构.计算结果显示,纯针铁矿导带底与价带顶均由Fe3d与O2p轨道组成,而当含杂质Al时,Al2p与O2p发生杂化参与了价带组成.在此基础上,利用同步辐射X射线氧的K边吸收谱与发射谱对纯针铁矿及天然针铁矿的能带结构进行了测定.结果表明,天然含Al的针铁矿禁带宽度为2.30eV,小于纯针铁矿(2.57eV).本研究提供了一种测定天然氧化物矿物禁带宽度的新方法,为深入研究天然半导体可见光催化活性产生机制提供了理论依据.  相似文献   

固相吸附毒素跟踪技术(SPATT)在浙江南麂海域的应用     

渠佩佩  杨晶晶  徐轶肖  高寒  佟蒙蒙 《海洋与湖沼》2016,47(4):795-803

浙江南麂岛海域是我国近岸贝类的重点养殖区,近年来一直遭受脂溶性贝类毒素(lipophilic shellfish toxins,LSTs)的污染,威胁着人类健康。为了建立有效的食品安全预警方法,本研究利用固相吸附毒素跟踪技术(solid phase adsorption toxin tracking,SPATT)在该海域进行了为期一年的野外监测和LSTs毒素分析。结果表明:7种LSTs毒素在SPATT(DIAION?HP20)中被检出,分别是大田软海绵酸(okadaic acid,OA)、鳍藻毒素-1(dinophysistoxin-1,DTX-1)、虾夷扇贝毒素(yessotoxin,YTX)及其衍生物homo YTX、扇贝毒素-2(pectenotoxin-2,PTX-2)及其衍生物7-epi-PTX2sa和环亚胺毒素(gymnodimine,GYM);有8种毒素在厚壳贻贝(Mytilus galloprovincialis)中被检出,分别是OA、DTX1、homo YTX、PTX2、7-epi-PTX2sa、GYM、原多甲藻酸贝类毒素-3(azaspiracid-3,AZA-3)和虾夷扇贝毒素衍生物45-OH-homo YTX。整体而言,SPATT(HP20)中吸附的毒素种类与贝肉中监测出的毒素种类大体上一致,且两者间OA、DTX1和PTX2的浓度在时间上具有较好的相关性,可见SPATT(HP20)对这些LSTs毒素具有较高的灵敏度,有望作为水体中LSTs毒素的预警监测材料。南麂岛海域LSTs分布特征明显,夏季最高,其次是春秋季,冬季最低,其中2014年夏季贝肉中OA毒素含量高达77.19ng/g贝肉,超出国家限量标准(45ng/g贝肉)比例达11.76%,为浙江南麂海域贻贝的食用安全带来隐患。  相似文献   

Microstructural characteristics of the Whitby Mudstone Formation (UK)     

《Marine and Petroleum Geology》2016

When trying to improve gas productivity from unconventional sources a first aim is to understand gas storage and gas flow potential through the rock by investigating the microstructure, mineralogy and matrix porosity of unfractured shale. The porosity and mineralogy of the Mulgrave Shale member of the Whitby Mudstone Formation (UK) were characterized using a combination of microscopy, X-ray diffraction and gas adsorption methods on samples collected from outcrops. The Whitby Mudstone is an analogue for the Dutch Posidonia Shale which is a possible unconventional source for gas. The Mulgrave shale member of the Whitby Mudstone Formation can microstructurally be subdivided into a fossil rich (>15%) upper half and a sub-mm mineralogically laminated lower half. All clasts are embedded within a fine-grained matrix (all grains < 2 μm) implying that any possible flow of gas will depend on the porosity and the pore network present within this matrix. The visible SEM porosity (pore diameter > 100 nm) is in the order of 0.5–2.5% and shows a non-connected pore network in 2D. Gas adsorption (N2, Ar, He) porosity (pore diameters down to 2 nm) has been measured to be 0.3–7%. Overall more than 40% of the visible porosity is present within the matrix. Comparing the Whitby Mudstone Formation to other (producing) gas shales shows that the rock plots in the low porosity and high clay mineral content range, which could imply that Whitby Mudstone shales could be less favourable to mechanical fracturing than other gas shales. Estimated permeability indicates values in the micro-to nano-darcy range.  相似文献   

高温与冻融循环对水热炭和生物炭吸附污染物的影响     

关俊杰  刘雨嫣  刘思源  陈家玮 《现代地质》2021,35(4):931-939

将农林废弃物通过不同碳化方式制备成水热炭或生物炭,用于土壤改良和环境污染修复,是当前研究和应用的热点领域。由于受到不同自然条件的长期影响,如环境温度变化,水热炭和生物炭会发生老化作用,从而影响其对污染物的吸附能力,因此,评估老化作用对碳化材料吸附能力的影响是一个重要的科学问题。采用高温和冻融循环2种加速老化方式模拟自然界中的温度变化,对稻壳和玉米秸秆水热炭、生物炭进行老化培养,通过元素分析仪、傅里叶红外光谱分析仪、扫描电子显微镜等手段对老化前后水热炭、生物炭样品的物化性质进行分析,通过批实验对比研究2种新鲜炭材料对Cd(II)及莠去津的吸附能力及吸附稳定性,并研究了30、60、90次老化循环后生物炭和水热炭吸附能力的变化。结果表明,生物炭对Cd(II)和莠去津有良好的吸附稳定性,而水热炭对莠去津的吸附稳定性较差。2种老化作用均使水热炭、生物炭表面含氧官能团增加,从而增强了水热炭、生物炭对Cd(II)和莠去津的吸附能力。在高温和冻融环境中,随着老化时间的持续,生物炭比水热炭更容易受到环境的影响。研究相关成果对于水热炭和生物炭合理应用于不同环境的污染修复具有试验参考价值。  相似文献   

Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana          下载免费PDF全文

Jason M. Mailloux  Kiona Ogle  Carol D. Frost 《水文研究》2014,28(4):2361-2381

The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the ⁸⁷Sr/⁸⁶Sr, δ¹³C_DIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Structural, curvature and electronic properties of Rh adsorption on armchair single-walled carbon nanotube     

杨培芳  吴锋民  滕波涛  刘莎  蒋健中 《海洋学报(英文版)》2010,29(9)

This paper systematically studies the rolling effects of the (n, n) single-wall carbon nanotubes (SWCNT) with different curvatures on Rh adsorption behaviours by using density functional theory. The outside charge densities of SWCNTs are found to be higher than those inside, and the differences decrease with the increase of the tube radius. This electronic property led to the discovery that the outside adsorption energies are higher than the inside ones, and that the differences are reduced with the increase of the tube radius. Partial density of states and charge density difference indicate that these strong interactions induce electron transfer between Rh atoms and SWCNTs.  相似文献   

浅淡奇石及其文化渊源     

艾宪森  柏鉴清 《山东国土资源》2000,(1)

介绍了我国奇石观赏的起源和发展进程 ,对我国石文化传统和各发展阶段的石文化特点进行了探讨  相似文献   

H~+对Cu~(2+)—Me~(2+)二元体系吸附的影响规律研究     

Li Xuqian 《吉林大学学报(地球科学版)》1989,(4)

土壤对重金属离子的吸附容量严格受H~+浓度的控制。本文通过试验探讨了H~+ 对Cu~(2+)——Pb~(2+),Cn~(2+)——Zu~(2+),Cu~(2+)——Hg~(2+)系统中Cu~(2+)吸附量的影响规律。当pHpH时,Cu~(2+)吸附量随pH值增大而减小。对于酸性土,pH=6.5(初始值)或7.0(平衡值),对碱性土,pH=5.5(初始值)或7.8(平衡值)。在pHpH_(ZPC)时,吸附模式具有完全不同的形式。  相似文献   

Influence of fluid chemistry on shear-wave attenuation and velocity in sedimentary rocks   总被引：2，自引：0，他引：2  

Dung Vo-Thanh 《Geophysical Journal International》1995,121(3):737-749

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