不同温度、羧酸溶液中长石溶解模拟实验   总被引：24，自引：2，他引：22  

向廷生  蔡春芳  付华娥 《沉积学报》2004,22(4):597-602

报道了在100℃、140℃下微斜长石在不同羧酸溶液中的溶解实验数据。通过实验表明1)反应温度增高,可增强溶液中阳离子的活性和迁移性,加快长石溶解的反应速率,促进长石的溶解。2)在强酸性条件下,pH值的变化可影响长石的溶解。但在中等酸性条件下,pH值对长石的溶解影响很小。3)羧酸(乙二酸)可不同程度地促进长石溶解,可通过形成乙二酸络合物的形式,增加离子在溶液中的溶解度。但乙酸络合物的作用不明显。长石溶蚀导致岩石孔隙度变大,并且改善孔喉性质。同时,由于乙二酸络合物的存在,增加了Si在溶液中的溶解度,阻止了石英加大和其它成因SiO₂的生成,有利于次生孔隙和原生孔隙的保存。4)长石溶解使溶液中Al的浓度较高,但由于铝-羧酸络合物的亲油性比亲水性强,故有一部分Al被分配到油相中,这也是目前大多数油田水中Al浓度偏低的主要原因。  相似文献   

Diagenesis impact on a deeply buried sandstone reservoir (Es1 Member) of the Shahejie Formation,Nanpu Sag,Bohai Bay Basin,East China     

M. Kashif  Y. Cao  W. Jian  X. Cheng  P. Sun 《Australian Journal of Earth Sciences》2019,66(1):133-151

Diagenesis has a significant impact on reservoir quality in deeply buried formations. Sandstone units of the Shahejie Formation (Es₁ Member) of Nanpu Sag, Bohai Bay Basin, East China is a typical deeply buried sandstone with large hydrocarbon accumulations. The methodology includes core observations and thin section studies, using fluorescence, scanning electron microscope (SEM), cathodoluminescence (CL), fluid inclusion and isotope and electron probing analysis as well as the numerical determination of reservoir characteristics. The sandstones consist of medium to coarse-grained, slight to moderate sorted lithic arkose and feldspathic litharenite. Porosity and permeability values range from 0.5 to 30% and 0.006 to 7000 mD, respectively. The diagenetic history reveals mixed episodes of diagenesis and deep burial followed by uplift. The main diagenetic events include compaction, cementation alteration, dissolution of unstable minerals and grain fracturing. Compaction resulted in densification and significantly reduced the primary porosity. Quartz, calcite and clay are the dominant pore-occluding cement and occur as euhedral to subhedral crystals. Alteration and dissolution of volcanic lithic fragments and pressure solution of feldspar grains were the key sources of quartz cement whereas carbonate cement is derived from an external source. Clay minerals resulted from the alteration of feldspar and volcanic lithic fragments. Porosity and permeability data predict a good inverse relationship with cementation whereas leaching of metastable grains, dissolution of cement and in some places formation of pore-lining chlorite enhanced the reservoir quality. The best reservoir is thicker sandstone bodies that are medium to coarse-grained, well-sorted sandstone with low primary ductile grains with a minor amount of calcite cement. The present study shows several diagenetic stages in the Es₁ Member, but the overall reservoir quality is preserved.  相似文献   

动能歧视模式ICP-MS测定地球化学样品中14种痕量元素   总被引：5，自引：4，他引：1  

徐进力  邢夏  唐瑞玲  胡梦颖  张鹏鹏  白金峰  张勤 《岩矿测试》2019,38(4):394-402

应用传统ICP-MS法测定勘查地球化学样品中Ag、Cd等痕量元素,基体效应和多原子离子干扰严重,准确测定的难度较大。本文基于当前ICP-MS消除干扰技术,分析了ICP-MS标准模式(STD)及动能歧视模式(KED)测定地球化学样品中Ag、Cd等14种痕量元素的有效性,通过比较这两种模式的测定效果,在此基础上确定了各元素的有效测定模式。结果表明:在KED模式下,基体元素如Zr、Nb氧化物的产率降低,基本上消除了Zr、Nb氧化物对痕量元素Ag、Cd的多原子离子干扰。KED模式提高了信噪比,降低了方法检出限,如Ag、Cd的检出限分别为0. 004mg/kg、0. 005mg/kg,其他12种元素的检出限也低于多目标地球化学调查76种元素分析方案中的检出限。测定痕量元素的准确度显著优于STD模式。实验中采用简单的硝酸-氢氟酸-高氯酸消解样品,残渣用王水复溶,结合KED模式下优选出干扰较小的同位素作为测定同位素,以Rh作为内标校正仪器产生的信号漂移,将样品溶液稀释至1000倍,基体效应降低至最小。本方法经国家一级标准物质的验证,测定结果与认定值相符,可为勘查地球化学提供高质量数据。  相似文献   

渤中凹陷CFD18-2油田高岭石胶结作用及其对储层物性的影响     

陈思芮  曲希玉  王冠民  王清斌  曹英权 《吉林大学学报(地球科学版)》2019,49(5):1235-1246

为探究成岩作用过程中所形成的次生黏土矿物对储层物性的影响,借助偏光显微镜及扫描电镜的镜下分析,并结合储层物性等数据,对渤中凹陷附近沙垒田凸起东南部CFD18-2油田东三段高岭石的特征、类型、成因及其对储层物性的影响进行了研究。研究结果表明：1）研究区高岭石为有机酸溶蚀长石形成的自生高岭石,呈现典型的"手风琴状"及"蠕虫状",常充填于粒间孔、长石次生溶孔及碳酸盐胶结物溶孔中并形成良好的晶间孔隙。2）研究区主要发育两期高岭石,第一期主要充填于早期碳酸盐胶结物溶孔中,呈微小"蠕虫状";第二期充填于铁方解石与铁白云石胶结物溶孔中,部分高岭石具碱性溶蚀特征,且第二期高岭石与晚期伊利石共生。3）研究区东三段储层具备一定的渗流能力,使长石溶蚀形成的"副产物"被流体带走;但在破坏性成岩作用下,储层渗流能力会逐渐变差,最终使得"副产物"堆积于孔隙,降低储层物性。4）高岭石及同期硅质胶结物对储层物性的影响是一把"双刃剑",当高岭石及硅质的体积分数低于6.81%时,长石溶蚀有利于改善储层物性;当高岭石及硅质的体积分数高于6.81%时,则不利于储层物性的改善。  相似文献   

Interplay of S and As in Mekong Delta sediments during redox oscillations   总被引：1，自引：1，他引：0  

Van T.H.Phan  Fabrizio Bardelli  Pierre Le Pape  Raoul-Marie Couture  Alejandro Fernandez-Martinez  Delphine Tisserand  Rizlan Bernier-Latmani  Laurent Charlet 《地学前缘(英文版)》2019,10(5):1715-1729

The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam).  相似文献   

Numerical modeling of three‐phase dissolution of underground cavities using a diffuse interface model     

H. Luo  F. Laouafa  J. Guo  M. Quintard 《国际地质力学数值与分析法杂志》2014,38(15):1600-1616

Natural evaporite dissolution in the subsurface can lead to cavities having critical dimensions in the sense of mechanical stability. Geomechanical effects may be significant for people and infrastructures because the underground dissolution may lead to subsidence or collapse (sinkholes). The knowledge of the cavity evolution in space and time is thus crucial in many cases. In this paper, we describe the use of a local nonequilibrium diffuse interface model for solving dissolution problems involving multimoving interfaces within three phases, that is, solid–liquid–gas as found in superficial aquifers and karsts. This paper generalizes developments achieved in the fluid–solid case, that is, the saturated case [1]. On one hand, a local nonequilibrium dissolution porous medium theory allows to describe the solid–liquid interface as a diffuse layer characterized by the evolution of a phase indicator (e.g., porosity). On the other hand, the liquid–gas interface evolution is computed using a classical porous medium two‐phase flow model involving a phase saturation, that is, generalized Darcy's laws. Such a diffuse interface model formulation is suitable for the implementation of a finite element or finite volume numerical model on a fixed grid without an explicit treatment of the interface movement. A numerical model has been implemented using a finite volume formulation with adaptive meshing (e.g., adaptive mesh refinement), which improves significantly the computational efficiency and accuracy because fine gridding may be attached to the dissolution front. Finally, some examples of three‐phase dissolution problems including density effects are also provided to illustrate the interest of the proposed theoretical and numerical framework. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

埋藏环境下碳酸盐岩建设性成岩作用类型、特征及其意义   总被引：1，自引：0，他引：1  

陈荣坤 《现代地质》1993,7(1):40-49

本文通过对南方中扬子地区和北方鄂尔多斯盆地西缘的寒武系、奥陶系埋藏成岩作用的详细研究,认为:（1）埋藏破裂、裂隙作用虽然能使岩石孔隙度有所增加。但更重要的是连通原已存在的孔隙。从而提高岩石的孔隙度和渗透率:（2）埋藏白云化作用形成的晶间孔、缝、晶内孔、晶间溶孔等是油气储集的一种最有利的空间;（3）与构造作用相关的埋藏溶解作用和深部埋藏作用能形成有意义的油气储集场所。上述3冲作用相互叠加时。岩石的孔隙度和渗透率将急剧提高。本文提出鄂尔多斯北缘和东缘奥陶系是油气勘探的战略远景区。同时首次提出了识别埋藏白云石化作用和埋藏溶解作用的标志和际准。  相似文献   

论煤田滑动构造与底板突水的关系--以肥城矿区为例   总被引：1，自引：1，他引：0  

孙立进  刘明雷  施龙青 《煤田地质与勘探》1999,27(6):44-46

肥城矿区内重力滑动构造的基本特点是具有多层次性、多期性、小规模性和形式多样性。滑动构造加强了含水层之间的水力联系,降低了煤层底板的隔水能力,促进了岩石的应力溶蚀作用,复杂了水网络,减少了煤田深部不。  相似文献   

天山乌鲁木齐河融雪和河川径流的水文化学过程   总被引：12，自引：3，他引：9  

刘凤景 Willi.  M 《冰川冻土》1999,21(3):213-219

研究结果表明, 含 Ｃａ Ｃ Ｏ３矿物的溶解作用在乌鲁木齐河源区居主导地位 尽管融雪径流的 “离子脉冲”作用可以释放峰值强度达 ３～４ 倍的 Ｓ Ｏ２４ 和 Ｎ Ｏ－３ 流, 并且引起了总控断面河川径流与之相像的“离子脉冲”现象,但河川径流仍然呈现弱碱性;河源区强烈的含 Ｓ矿物的氧化溶解作用,产生大量的 Ｈ＋ ,被含 Ｃａ Ｃ Ｏ３矿物的溶解作用所缓冲, 未引起河川径流的酸化乌鲁木齐河以冰川站为界, 以上地区的水文化学过程为矿物的侵蚀－ 溶解过程,以下则发生部分矿物的沉淀,如 Ｃａ Ｃ Ｏ３的沉淀 Ｃａ Ｃ Ｏ３ 的沉淀作用一定程度上又增强了河流的酸缓冲力   相似文献   

纤维水镁石在氨基酸水溶液中的电化学及溶解作用研究   总被引：6，自引：1，他引：5  

李国武  董发勤  万朴  彭同江  宋功宝 《矿物学报》1999,19(3):286-292

在模拟人体温度３７℃条件下,进行水镁石纤维粉尘与氨基酸作用的实验研究,测定在７２ｈ内溶液过程中ｐＨ值的电导率的变化,结果表明,纤维矿物在氨基酸中发生了有机配合作用,并且中性氨基酸对矿物的溶解能力最强。  相似文献