豫南铜多金属贵金属矿床类型及找矿前景     

钟华邦 《矿产与地质》1997,(6):403-405

豫南地区发育着铜多金属及贵金属矿床，在空间上矿化与断裂构造破碎带密切有关，使“矿体、矿群、矿带”呈间距平行展布的特征。矿床可分为产于前寒武纪变质碳酸盐岩系中、产于变质中、基性岩系中和产于燕山期酸性侵入岩体内外接触带中三类铜多金属和贵金属矿床。提出了在围山城、银洞坡、刘山崖和杜家畈矿区外围以及银洞沟—马大庄、河嘴—驼店、犁铧寨—南湾—皇城山和南马畈—柳林等找矿远景区段。  相似文献   

单道扫描电感耦合等离子体发射光谱法测定大洋标准物质中稀土元素     

查立新  刘洪青 《岩矿测试》1997,16(1):23-27

采用单道扫描等离子体发射光谱法测定了大洋多金属结核及深海沉积物中的稀土元素与钪，比较了不同功率下各稀土元素的检测限，研究了低功率下的稳定性，拟定了可靠的样品处理方法。方法经多金属结核及深海沉积物国家标准ＧＢＷ０７３１３、ＧＢＷ０７２４９分析验证，结果与标准值相符。测定精度（ＲＳＤ）在１３％～５３％。已用此法为第２批多金属结核和深海沉积物标准物质提供了定值数据，其结果无剔除值  相似文献   

多金属结核中二氧化锰的测定   总被引：1，自引：0，他引：1  

夏月莲  毛海燕 《岩矿测试》1997,16(3):177-179

用过量的含有Ｈ２ＳＯ４的（ＮＨ４）２Ｆｅ（ＳＯ４）２溶液分解多金属结核的同时，还原了试样中的ＭｎＯ２，然后以Ｋ２Ｃｒ２Ｏ７标准溶液滴定测定了多金属结核中的ＭｎＯ２。就样品分解过程中的加热温度和时间对测定结果的影响及标准溶液的标定等问题进行了讨论，经多次测定，方法重现性好。应用此方法为新研制的多金属结核标准物质提供了ＭｎＯ２的定值数据，其结果与初定值相符，无剔除值，精密度（ＲＳＤ，ｎ＝８）小于０６％。  相似文献   

论湖南柿竹园多金属矿床成岩成矿的化学模式─—与毛景文先生等商榷   总被引：2，自引：0，他引：2  

郑大中  郑若锋 《四川地质学报》1997,(4)

从湖南柿竹园多金属矿床成岩成矿的事实出发，用化学基本定律对其矽卡岩的形成，蚀变及成岩成矿的化学反应方程式进行研讨，建立了比较符合矿床实际与地球化学理论的化学模式。认为地球科学与化学是在相互交叉，相互渗透，相互促进中共同发展的。  相似文献   

粤西金、银矿床成矿规律探讨   总被引：10，自引：0，他引：10  

潘家永  张乾  张宝贵  张玉学  邵树郧 《矿床地质》1996,15(3):257-266

粤西是我国华南的主要金、银矿床集中区，区内金矿床与银（金）多金属矿床具有相间排列的分布规律，即从南到北分为以下５个矿带：廉江地区银（金）多金属矿带、高州—信宜金矿带、罗宁—云浮银（金）多金属矿带、德庆—清远金矿带、连山地区银（金）多金属矿带。本文从区域地层、岩浆岩及成矿作用等方面对粤西金、银矿床区域分布规律进行了探讨，认为影响金、银矿床分布的主要因素是不同区域地层、岩浆岩Ａｕ、Ａｇ含量的差异及金矿床与银（金）多金属矿床成矿作用的差异  相似文献   

湖南柿竹园钨多金属矿床成矿机理的实验研究   总被引：3，自引：1，他引：3  

梁祥济 《矿床地质》1996,15(3):278-286

作者在深入柿竹园钨多金属矿床野外地质工作的基础上，采用矿区燕山期花岗岩和泥盆系灰岩作为试料，在含ｐＨ＝４．０的０．３ＭＮａＣｌ＋０．７ＭＫＦ水溶液的高压釜中持续了１２０小时的交代作用。实验的结果表明了：在４００～７００℃的温度和２５０×１０５～９００×１０５Ｐａ的压力下，形成的交代岩及其钨、锡、钼、铋矿物基本上与矿区的矽卡岩及其矿石矿物共生组合相吻合，揭示了湖南柿竹园矽卡岩型钨多金属矿床成矿的机理  相似文献   

多金属结核的沉积物地球化学场     

杨慧宁  陈永志  沈桂梅 《岩石矿物学杂志》1996,15(4):307-315

远洋沉积物是多金属结核赖以生长的场所，本文系统地研究了沉积物中主要成矿元素水成组分在不同地球化学场和不同沉积阶段的地球化学特征，以及水成组分的含量比与成矿作用的相互关系。研究表明，Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ都是一些比较活泼的元素，它们共处于多金属结核、沉积物和大洋水的统一体系中，当结核形成时，Ｍｎ、Ｆｅ、Ｎｉ、Ｃｕ在结核与沉积物中的含量呈负相关，而Ｃｏ含量呈正相关。研究区东部结核以富含Ｍｎ、Ｎｉ、Ｃｕ贫Ｆｅ、Ｃｏ为特征，其伴生沉积物相对贫Ｍｎ、Ｎｉ、Ｃｕ、Ｃｏ，而富Ｆｅ，可称之为贫化的地球化学场。研究区西部结核富含Ｆｅ、Ｃｏ而贫Ｍｎ、Ｎｉ、Ｃｕ，其伴生沉积物则相应贫Ｆｅ，而富Ｍｎ、Ｎｉ、Ｃｕ、和Ｃｏ，可称之为富化的地球化学场。可以看出，贫化的沉积物地球化学场，恰恰是寻找富矿结核的最佳场所。早中新世以来的沉积物，根据水成组分的含量或含量比，也可相应于结核的形成分为三大沉积阶段，其中的第Ⅱ阶段具有贫化的地球化学特征，是多金属结核形成的最有利时期  相似文献   

Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden   总被引：7，自引：2，他引：7  

Zhixun Lin  Roger B. Herbert Jr. 《Environmental Geology》1997,33(1):1-12

This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite). Received: 28 October 1996 · Accepted: 24 February 1997  相似文献   

Electrokinetic remediation of metal contaminated glacial tills   总被引：2，自引：0，他引：2  

K.R. Reddy  A.B. Shirani 《Geotechnical and Geological Engineering》1997,15(1):3-29

This paper presents the results of an experimental investigation which studied the feasibility of using the electrokinetic process to remediate contaminated clays of glacial origin, otherwise known as glacial tills. An overview of the electrokinetic phenomena, as well as previously performed laboratory and field investigations, is first presented. The methodology of the electrokinetic experiments which were conducted to investigate the removal of metals from a glacial till is then described. A total of 16 experiments were conducted using glacial till samples obtained from a project site near Chicago. Sodium and calcium were used as the surrogate cationic metallic contaminants. These experiments demonstrated that ion transport during the electrokinetic process occurs due to both electro-osmosis and electromigration, but that due to electromigration is significantly higher than that due to electro-osmosis. Unlike other clays such as kaolinite, the glacial till used for this investigation possessed high buffering capacity because of its high carbonate content which prevented the acid front migration from the anode to the cathode during the electrokinetic process. The ion removal efficiency of the electrokinetic process was found to increase when: (1) the voltage gradient applied to the soil was increased, (2) the initial concentration of the contaminants was increased, and (3) the duration of the treatment process was increased. The ion removal efficiency was also greater for smaller ions which possess less ionic charge and when the ions existed independently in the soil as compared to when they coexisted. This investigation suggests that the electrokinetic process has significant potential for remediating glacial tills contaminated with metals. However, the properties of Na and Ca are not representative of contaminants, such as heavy metals, so further investigations are needed.  相似文献   

关于银山矿床成矿作用的几个问题——兼与《江西银山铜铅锌金银矿床》的作者商榷     

张德会 《地质论评》1997,43(5):490-497

银山多金属矿床是一个特大型火山—潜火山热液矿床,具有复杂的多期多阶段的成矿作用和有序的成矿分带。成矿作用主要为火山—潜火山热液作用,但在此之前,还经历了一期由韧脆性剪切带形成而引起的动力变质热液作用。根据矿体与3个旋回潜火山岩体的时空关系,火山—潜火山热液成矿作用又可分为两个成矿期和5个成矿阶段。矿床地质地球化学研究表明成矿作用在空间上具有定向迁移的特点,结合流体动力学计算机数值模拟认为定向迁移的根本原因是构造岩浆脉动和隐伏岩体形态产状。笔者认为,矿区深部可能有隐伏岩体,但对隐伏的斑岩铜矿床不应抱很大希望  相似文献