基于五种油源的中重度风化溢油的常规鉴定指标的应用效果评估     

贺世杰  王传远  李延太  于洪军  韩彬 《海洋学报(英文版)》2016,35(4):1-8

本文利用采集于我国三大油田的五种原油样品开展了长达210天的溢油风化模拟实验,并依据相对偏差和重复性限数学分析法,进行溢油风化过程分析和诊断比值应用效果评估。研究结果表明:经过210天的风化,溢油鉴定诊断比值发生明显改变;其中来源于萜烷、甾烷和多环芳烃的诊断比值变化率要远低于正构烷烃,可用于中长期风化溢油鉴定。此外,研究发现,在这些有效诊断比值中有4个变化率较小,相对偏差低于5%,保持了较好的稳定性,更适合于重度风化溢油鉴定。  相似文献   

柴北缘布赫特山一带达肯大坂岩群变质岩变形特征、地球化学特征及地质意义     

王洪强  邵铁全  唐汉华  姜开拓 《地质通报》2016,35(9):1488-1496

古元古代达肯大坂岩群为柴北缘构造带的变质结晶基底,是柴北缘造山带的重要组成部分。前人在德令哈以西的鱼卡河—锡铁山—沙柳河一带和大柴旦等地对达肯大坂岩群做了较深入的研究,但对于柴北缘东段的研究还相对薄弱,缺乏东西段的对比研究。通过对布赫特山一带达肯大坂岩群中片麻岩和斜长角闪片岩的岩石学、岩石地球化学、年代学研究和区域对比,认为研究区的岩性、矿物组合、变质程度与德令哈以西鱼卡河—锡铁山—沙柳河一带达肯大坂岩群具有较高的相似性。布赫特山一带达肯大坂岩群主要为一套碎屑岩夹火山岩的岩石组合,变形强烈,其形成环境为岛弧与活动性陆缘的过渡环境,且岩浆来源为壳幔混染。由采集的2件Sm-Nd同位素样品得到了2组等时线年龄分别为2085±14Ma和2027±19Ma。由此可知达肯大坂岩群为古元古代柴北缘地区的变质结晶基底,是柴北缘古元古代造山带的重要组成部分。  相似文献   

安徽滁州地区闪长质岩锆石U-Pb年龄与地球化学:岩石成因和动力学意义     

朱强  胡召齐  施珂  吴礼彬  江来利 《地质通报》2018,37(6):1101-1112

用LA-ICP-MS测得安徽滁州2个闪长玢岩样品中锆石~(206)Pb/~(238)U年龄为126.19±0.44Ma和126.4±0.7Ma,结合前人研究,得出滁州地区岩体的侵位时代应为120~130Ma之间,为早白垩世。岩石地球化学研究显示,Si O_2含量变化范围为56.75%~60.90%,具有高Al_2O_3(14.82%~15.77%)、Mg O(4%)、Sr(750×10~(-6))、Sr/Y(62~110)、La/Yb(20~36),低Y、Yb的特征,同时富集轻稀土元素和大离子亲石元素,亏损高场强元素,Eu异常不明显,属于典型的埃达克质岩。Mg~#值为39~45,K_2O/Na_2O值为0.57~0.96,平均值为0.75,明显低于大别造山带加厚下地壳埃达克岩,Ce/Pb值较低,大多集中在3~5之间,类似于陆壳而明显低于洋壳。研究认为,安徽滁州地区埃达克质岩由拆沉下地壳部分熔融形成,埃达克质岩浆在上升过程中与地幔橄榄岩发生反应,导致熔体Mg O、Cr、Ni等含量增加。早白垩世中国东部地壳伸展减薄导致下地壳拆沉,地幔物质的参与带来铜、金等成矿物质,埃达克质岩可作为该地区重要的找矿标志。  相似文献   

High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating     

Yukio Isozaki  Shinji Yamamoto  Shuhei Sakata  Hideyuki Obayashi  Takafumi Hirata  Ken-ichi Obori  Toshinori Maebayashi  Satoshi Takeshima  Toshikazu Ebisuzaki  Shigenori Maruyama 《地学前缘(英文版)》2018,9(4):1073-1083

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.  相似文献   

Faults in the Baikal region: morphostructural and structure-genetic features (case study of the Buguldeika fault junction)     

A.V. Cheremnykh  A.S. Cheremnykh  A.A. Bobrov 《Russian Geology and Geophysics》2018,59(9):1100-1108

Lineament analysis is applied to map the pattern of the Obruchev fault system in the Buguldeika Village area, where several fault zones (Olkhon, Primorsky, Prikhrebtovyi, Buguldeika, and Kurtun) make up a junction. As inferred from the predominant directions of genetically related lineaments, the Olkhon, Primorsky, and Prikhrebtovyi faults originated under NW-SE extension and compression. The extension and compression settings within these zones are reconstructed by analysis of lineaments that have prominent and poor geomorphic expression, respectively. However, the pattern of lineaments well expressed in the surface topography within a weakly deformed block corresponds to reverse slip, while that of poorly pronounced lineaments corresponds to left-lateral strike slip. The study confirms the idea that the latest extension (rifting) stage in the Baikal region reactivated fault zones but did not deform blocks. The blocks store record of residual deformation produced by previous settings of regional compression and shear. The obtained results agree with earlier tectonophysical analysis of faults and fractures in the area and prove the applicability of the suggested approach to map the fault patterns and reconstruct their respective stress settings in areas that underwent multiple deformation events of different ages.  相似文献   

Crust structure of the northeastern Barents Sea basin area     

A.L. Piskarev  A.A. Kireev  V.A. Savin  O.E. Smirnov 《Russian Geology and Geophysics》2018,59(7):803-812

Processing of data from regional geophysical surveys completed in the northern Barents Sea has provided updates to gravity and magnetic databases, structural maps of seismic interfaces, and positions of anomaly sources, which made a basis for 3D density and magnetic models of the crust. The new geological and geophysical results placed constraints on the boundaries between basement blocks formed in different settings and on the contours of deposition zones of different ages in the northeastern Barents Sea. The estimated thicknesses of sedimentary sequences that formed within certain time spans record the deposition history of the region. There is a 20-50 km wide deep suture between two basins of Mesozoic and Paleozoic ages in the eastern part of the region, where pre-Late Triassic reflectors have no clear correlation. The suture slopes eastward at a low angle and corresponds to a paleothrust according to seismic and modeling data. In the basement model, the suture is approximated by a zone of low magnetization and density, which is common to active fault systems. The discovery of the suture has important geological and exploration implications.  相似文献   

内蒙古巴林右旗晚二叠世埃达克质火山岩特征及其地质意义     

杨文鹏  张生旭  姜海洋  刘洪大  隋成禹  孙江军  张俭峰  吕石佳  李新鹏 《地质通报》2018,37(9):1710-1721

内蒙古东南部巴林右旗地区发育晚二叠世埃达克质火山岩,岩石组合为安山岩、粗安岩、英安岩及辉石安山岩,其LA-ICP-MS锆石U-Pb测年结果为256.7±2.7Ma,指示其形成于晚二叠世。地球化学特征显示,该套火山岩属准铝质-弱铝质中钾钙碱性岩石系列,具富Si(SiO_256%)、高Al(Al_2O_315%)、富Na、贫K、高Sr、低Yb和Y等特征,Na_2O/K_2O值为2.33~3.90,Mg~#值为35.3~60.8;稀土元素总量为96.69×10~(-6)~192.4×10~(-6)、轻重稀土元素分馏较明显((La/Yb)_N值为6.27~13.82),具正的Eu(δEu=1~1.67)异常,在原始地幔标准化蛛网图中,富集大离子亲石元素Rb、Ba、U,亏损高场强元素Nb、Ta,为O型(大洋型)埃达克质火山岩地球化学特征。综合区域资料,巴林右旗埃达克质火山岩是残留在地幔中的古亚洲洋残余洋壳部分熔融并受到地幔橄榄岩混染形成的,暗示晚二叠世存在古亚洲洋向华北板块俯冲消亡事件。  相似文献   

Depositional setting,provenance, and tectonic-volcanic setting of Eocene–Recent deep-sea sediments of the oceanic Izu–Bonin forearc,northwest Pacific (IODP Expedition 352)     

Alastair H. F. Robertson  Steffen Kutterolf  Aaron Avery  Alan T. Baxter  Katerina Petronotis  Gary D. Acton 《International Geology Review》2018,60(15):1816-1854

New biostratigraphical, geochemical, and magnetic evidence is synthesized with IODP Expedition 352 shipboard results to understand the sedimentary and tectono-magmatic development of the Izu–Bonin outer forearc region. The oceanic basement of the Izu–Bonin forearc was created by supra-subduction zone seafloor spreading during early Eocene (c. 50–51 Ma). Seafloor spreading created an irregular seafloor topography on which talus locally accumulated. Oxide-rich sediments accumulated above the igneous basement by mixing of hydrothermal and pelagic sediment. Basaltic volcanism was followed by a hiatus of up to 15 million years as a result of topographic isolation or sediment bypassing. Variably tuffaceous deep-sea sediments were deposited during Oligocene to early Miocene and from mid-Miocene to Pleistocene. The sediments ponded into extensional fault-controlled basins, whereas condensed sediments accumulated on a local basement high. Oligocene nannofossil ooze accumulated together with felsic tuff that was mainly derived from the nearby Izu–Bonin arc. Accumulation of radiolarian-bearing mud, silty clay, and hydrogenous metal oxides beneath the carbonate compensation depth (CCD) characterized the early Miocene, followed by middle Miocene–Pleistocene increased carbonate preservation, deepened CCD and tephra input from both the oceanic Izu–Bonin arc and the continental margin Honshu arc. The Izu–Bonin forearc basement formed in a near-equatorial setting, with late Mesozoic arc remnants to the west. Subduction-initiation magmatism is likely to have taken place near a pre-existing continent–oceanic crust boundary. The Izu–Bonin arc migrated northward and clockwise to collide with Honshu by early Miocene, strongly influencing regional sedimentation.  相似文献   

辽东半岛大金山花岗岩体SHRIMP U-Pb年龄、元素地球化学和Hf同位素特征及地质意义     

杨佳林  顾玉超  杨凤超  李东涛  鞠楠  贾宏翔 《地质论评》2018,64(6):1541-1556

辽东半岛早白垩世时期受到强烈的构造—岩浆作用使岩石圈构造环境由挤压造山向伸展减薄转变,前人对其成因有所争议。本文通过锆石SHRIMP U- Pb测年、原位Lu- Hf同位素和主量、微量、稀土元素测试对辽东半岛大金山花岗岩体进行了系统研究,结果显示：大金山花岗岩体结晶年龄为~ 124Ma,侵位于早白垩世岩浆活动的高峰期。岩石地球化学特征显示大金山花岗岩属弱过铝质~过铝质岩石,经历了高程度的结晶分异过程,富集Rb、Th、U、K等大离子亲石元素（LILE）,亏损P、Ti等高场强元素（HFSE）,中等Eu负异常,为I型花岗岩。TW003样品εHf(t)值为-25.8~ -14.2,tDM2为2093~2805Ma,岩浆物质来源于新太古代—古元古代下地壳火成岩的部分熔融。根据年代学和岩石地球化学研究认为大金山花岗岩是古太平洋板块向欧亚大陆板块俯冲所形成的活动大陆边缘弧花岗岩,辽东半岛早白垩世的伸展环境是受板块俯冲造山后伸展作用和下地壳拆沉作用的联合制约。  相似文献   

丹霞山世界地质公园蜂窝状洞穴特征及成因分析   总被引：1，自引：0，他引：1  

陈留勤  李馨敏  郭福生  李鹏程  李余亮  刘鑫 《地质论评》2018,64(4):895-904

蜂窝状洞穴以其精致的形貌和众说纷纭的成因吸引着科研人员和普通大众的兴趣。丹霞山世界地质公园蜂窝状洞穴主要产于晚白垩世丹霞组二段(锦石岩段)风成砂岩的崖壁上。本文以园区长老峰锦石岩寺和睡美人禄意堂两处蜂窝状洞穴为研究对象,通过野外实地调查,了解洞穴生长环境,定量统计分析其形态特征,并采集砂岩样品进行显微镜下观察,探讨洞穴形成与盐风化作用的关系。研究表明:蜂窝状洞穴所在的岩性主要为中—细粒长石岩屑砂岩,发育大型高角度交错层理,渗透性较好;洞穴开口均向下朝向锦江,有利于来自锦江河流的湿润水汽较长时间地保持在小洞内部;洞穴开口基本服从泰森多边形分布。因此,碎屑颗粒相对比较均匀的风成砂岩为丹霞山蜂窝状洞穴的发育提供了重要的岩石基础,锦江河流为盐风化提供了必要的湿润水汽和盐分。在初始发育阶段,从岩壁上最适合盐风化作用的若干个点开始形成细小的坑洼,逐步向同层位扩张。单个小洞穴由于盐风化作用,洞穴内部风化速率大于洞穴开口边缘,导致蜂窝状洞穴内部空间扩大较快。然后,蜂窝状洞穴的发育突破纹层的限制,逐步加大、变深而呈泰森多边形规则分布。最终,随着洞穴加深,在重力、风力的影响下,蜂窝状洞穴隔壁减薄失稳,洞穴消亡。  相似文献