Rare earth elements and yttrium in ferromanganese deposits from the South China Sea: distribution, composition and resource considerations     

ZHONG Yi  CHEN Zhong  GONZALEZ Francisco Javier  ZHENG Xufeng  LI Gang  LUO Yun  MO Aibin  XU Antao  WANG Shuhong 《海洋学报(英文版)》2018,37(7):41-54

Ferromanganese nodules and crusts contain relatively high concentration of rare earth elements(REE) and yttrium(REY),with a growing interest in exploitation as an alternative to land-based REY resources.On the basis of comprehensive geochemical approach,the abundance and distribution of REY in the ferromanganese nodules from the South China Sea are analyzed.The results indicate that the REY contents in ferromanganese deposits show a clear geographic regularity.Total REY contents range from 69.1×10~(–6) to 2 919.4×10~(–6),with an average value of 1 459.5×10~(–6).Especially,the enrichment rate of Ce content is high,accounting for almost 60% of the total REY.This REE enrichment is controlled mainly by the sorption of ferromanganese oxides and clay minerals in the nodules and crusts.Moreover,the total REY are higher in ferromanganese deposits of hydrogenous origin than of diagenetic origin.Finally,Light REE(LREE) and heavy REE(HREE) oxides of the ferromanganese deposits in the study area can be classified into four grades: non-enriched type,weakly enriched type,enriched type,and extremely enriched type.According to the classification criteria of rare earth resources,the Xisha and Zhongsha platform-central deep basin areas show a great potential for these rare earth metals.  相似文献   

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

莱州湾和牟平近海夏季小型底栖生物群落组成及环境状况分析     

蒲思潮  史本泽  张光涛  徐奎栋 《海洋科学》2018,42(4):101-111

为探究莱州湾和牟平近海小型底栖生物群落组成及影响因子,作者于2016年7月在这两个海域采集了沉积物样品,并结合沉积环境因子进行了小型底栖生物群落组成分析。结果表明,在莱州湾和牟平近海各仅检获了7个小型底栖生物类群,且莱州湾的小型底栖生物平均丰度和生物量均明显低于牟平近岸海域。莱州湾线虫和桡足类平均丰度分别占小型底栖生物的91.9%和6.3%,牟平近海分别占92.1%和4.2%。对两个海域小型底栖生物群落组成与环境因子进行Pearson相关性分析,结果显示:小型底栖生物丰度与底层水溶解氧含量呈显著正相关;表层小型底栖生物丰度比与沉积物中叶绿素a含量、脱镁叶绿素含量、沉积物有机质含量以及水深呈显著正相关,与中值粒径和底层水温度呈显著负相关。本研究显示,基于不同沉积物类型中的参考比值,线虫和桡足类丰度比值(N/C)可用于莱州湾和牟平近海沉积环境有机污染状况的评估。研究还发现,牟平海域的小型底栖生物丰度和生物量呈现由近岸向外海增加的异常趋势,且小型底栖生物的数量和类群多样性较十年前显著降低,显示沉积环境受到了明显干扰。  相似文献   

白令海大型底栖动物群落结构及其空间分布格局     

林和山  刘坤  王建军  黄雅琴  李众  林俊辉  何雪宝  张舒怡  牟剑锋  王雨  邢炳鹏 《海洋学报(英文版)》2018,37(6):72-81

Due to its unique geological location, the Bering Sea is an ideal place to investigate the water exchange and ecosystem connectivity of the Pacific Ocean–Arctic Ocean and subarctic–Arctic region. Based on a number of summer surveys(July to September, 2010, 2012 and 2014), macrobenthic communities and their spatial-temporal patterns are exhibited for the majority of the Bering Sea(53°59′–64°36′N). The results show that the macrobenthic communities were dominated by northern cold-water species and immigrant eurythermic species, and the communities assumed a dispersed and patchy distribution pattern. Polychaetes(Scoloplos armiger), crustaceans(Ceradocus capensis) and sea urchins(Echinarachnius parma) were the main dominant groups in the shallow shelves; the sea star(Ctenodiscus crispatus) and the brittle star(Ophiura sarsii) were the main dominant groups in the continental slope; whereas small polychaetes(Prionospio malmgreni) dominated the basin area. Sediment type, water depth, and currents were the major factors affecting the structure and spatial distribution of the macrobenthic communities. Compared with other seas, the shallow areas of the Bering Sea showed an extremely high-standing biomass. In particular, the northern shelf area(north of St. Lawrence Islands and west of 170°W),which is primarily controlled by Anadyr Water, is an undersea oasis. In contrast, a deficiency in the downward transport of particulate organic carbon has resulted in a desert-like seabed in the basin area. By comparing our results to previous studies, we found that macrobenthic communities of the Bering Sea have undergone significant structural changes in recent decades, resulting in a decrease in abundance and an increase in biomass.In addition, populations of amphipods and bivalves in the northern shelves have decreased significantly and have been gradually replaced by other species. These changes might be associated with advanced seasonal ice melting,changes in organic carbon input, and global warming, indicating that large-scale ecosystem changes have been occurring in the Bering Sea.  相似文献   

南海土台风强度变化特征分析          下载免费PDF全文

薛淑君 《海洋学研究》2018,36(3):1-16

南海土台风,是在南海局地形成的热带气旋的统称。本文选用1949—2014年CMA-STI 整编的“热带气旋最佳路径数据集”,对研究区域范围(5°～22.5°N、105°～120.5°E)的南海土台风强度及强度变化特征进行了探讨。结果表明:(1)南海土台风强度随时间的变化曲线呈近似对称的“漏斗状”,即强度从弱—强—弱的变化,在最大强度前后6 h时域内强度变化最显著,夏季台风强度变化比冬季快。(2)土台风强度存在1个增强中心,位于海南岛以东的南海北部近海区域,在中国华南沿岸陆区则减弱明显;台风增强/减弱区域随着季节变化而南北移动,夏季主要在北部近海/近岸区域18°~23°N附近,冬季随台风活动南移至10~18°N附近靠近西部近海/近岸区域,且冬季的平均减弱速率较夏季大。(3)东向移动的土台风最大强度一般比西向移动的强,其中夏季东移台风平均强度最大,冬季西移台风强度最小;夏季东移台风最大强度前后强度变化最快,冬季西移台风变化最慢;夏季西移台风强度分布呈北强南弱、东移台风强度呈东北向带状分布,冬季东、西移台风强度分布皆呈西强东弱,这种空间分布差异,主要是台风移动路径随季节变化而形成的。(4)海上活动时间的长短与台风最大强度的大小、变化幅度成正比。海上活动时间较短的台风,以西行路径为主,强度的分布较均匀,平均强度较弱,增强/减弱中心较多而小,增强/减弱速率较慢;反之,海上活动时间较长的台风,以东行路径居多,强度的分布呈多中心状,平均强度较强,增强/减弱中心较集中且广阔,增强/减弱速率较快。  相似文献   

环渤海湾海洋资源环境承载力定量研究     

严淑青  朱庆林  余静  刘楠楠  张宇龙  安太天  唐泓淏 《海洋湖沼通报》2018,(6):46-53

环渤海湾地区经济发展迅速但开发利用过度,生态问题突出。本文以社会环境学理论、系统论、可持续发展理论等为基础,建立了环渤海湾海洋资源环境承载力评价指标体系,利用单项评价法,以地级市为基本单位对环渤海湾地区的海洋资源环境承载力进行评价。结果表明滨州市的海洋资源环境承载力较好,其次为唐山市和天津市,沧州市的海洋资源环境承载力较弱。  相似文献   

池塘养殖刺参安全度夏技术研究          下载免费PDF全文

刘锡胤  周文江  贺加贝  张晓明  陈伟  黄华  张岚 《海洋开发与管理》2018,35(2):103-108

文章概述夏季池塘养殖刺参死亡症状和灾情特点,分析刺参死亡原因主要包括池水盐度骤降、池水温度升高、池水pH值下降、池水分层、有机污染和刺参自身原因。在此基础上,提出池塘养殖刺参安全度夏的技术措施,主要包括科学合理选择养殖地址、规范池塘建设、做好度夏前准备工作、水质管理、及时清除水草和大型藻类、采取降温措施以及补充营养等,涉及大量具体操作方法,具有科学性和实用性。  相似文献   

基于多源数据的山东省围填海造地特点及发展趋势研究          下载免费PDF全文

安国强 《海洋开发与管理》2018,35(3):15-20

文章基于文献资料分析、官方数据汇总、国产高分辨率资源卫星遥感影像信息提取以及发展趋势研判等方法,对改革开放以来山东省全海域范围内围填海造地的历史发展、现状特征、发展趋势及其对生态环境的影响进行了分析和总结,并提出相关的政策建议。研究表明:改革开放以来,山东省围填海造地累计已超过4.58万hm~2。21世纪以来围填海造地进入快速增长时期,尤其是2010年以来,全省围填海造地又掀起了一次新的热潮,其面积和速度都远远超过了历史水平。鉴于围填海造地对环境和生态的巨大影响,文章提出了加强管理、严格环境影响评价、引入生态环境补偿机制以及建立分级填海评估制度和年度监测机制等建议。  相似文献   

渤海海峡跨海通道建设对城市经济联系的影响分析          下载免费PDF全文

狄乾斌  马洁 《海洋开发与管理》2018,35(3):102-108

渤海海峡跨海通道建设将极大改变环渤海乃至整个东部沿海的交通格局,势必对其目标城市大连、烟台带来直接的经济影响,同时也会对辽东半岛、山东半岛乃至东北、华北和华东不同尺度地区的经济联系产生深远影响。文章选取山东省17个和辽宁省14个地级市的地区的生产总值、城市人口以及城市间的最短时间距离等指标,测度渤海海峡跨海通道建成前后,对山东、辽宁两省区域城市经济联系的影响。研究表明:渤海海峡跨海通道建成后,对大连、烟台间的经济联系强度有显著提高,各城市经济联系度的平均增幅明显不同;同时,受距离衰减规律的影响,两省的城市分别以大连、烟台为中心,根据距离远近及城市自身发展程度分为4个层次,经济联系强度由内向外逐层次减弱;从整体上看,渤海通道的建设对带动两省城市之间的经济联系度都有大幅度提升。  相似文献   

南海IODP 349航次基底玄武岩中碳酸盐岩脉的岩石学特征*     

许佳锐  陈毅凤  王宝云 《热带海洋学报》2018,37(6):63-73

国际大洋发现计划(International Ocean Discovery Program, IODP)349航次在南海东部次海盆和西南次海盆残留扩张脊附近的U1431和U1433站位首次钻取基底玄武岩, 通过对16块基底玄武岩内的碳酸盐岩脉薄片镜下观察以及激光拉曼光谱分析, 揭示碳酸盐矿物为方解石和文石, 为典型的洋壳低温热液蚀变次生矿物。U1431站位碳酸盐岩脉为独立的方解石脉、文石脉交替出现; 而U1433站位则存在方解石脉、文石脉和方解石-文石共生脉三种情况。此外, U1431站位在基底~42.1m处出现了平行的方解石脉和文石脉, 揭示U1431存在不同来源热液的多期活动, 即可能存在多次或多阶段不同的热液注入。U1431和U1433站位的碳酸岩脉中, 文石的矿物集合体形状基本一致, 呈块状、纤维状和放射纤维状; 而方解石存在差异, U1431的方解石以斑块状、块状、粒状和纤维状出现, 而U1433的方解石仅出现块状。U1431站位的碳酸盐岩脉的丰度明显高于U1433站位。这些均揭示U1431站位的低温热液活动强, 而U1433站位则相对弱。两个站位的热液活动不同很可能是由于区域地质环境的差异造成——U1431附近的巨大海山为其提供了热液补给, 而U1433远离热液的补给/渗漏点。  相似文献