The chemical composition including the Rare Earth Elements of the three major glass types of Europe and the Orient used in late antiquity and the Middle Ages     

Karl Hans Wedepohl  Klaus Simon  Andreas Kronz 《Chemie der Erde / Geochemistry》2011,71(3):289-296

Sets of 20 soda ash glasses, 16 soda lime glasses and 23 wood ash glasses mainly from excavations in Europe (additional soda ash glasses from Egypt) were analysed on 61 chemical elements. Average SiO₂ is about 62% in soda glasses and 50% in wood ash glasses. The three groups of glasses contain on average 13% Na₂O, 18% Na₂O and 13% K₂O as fluxes to lower the melting temperature of quartz at their production. The starting materials beside quartz were halophytic plant ash for soda ash glass, trona (Na₃H(CO₃)₂·2H₂O) and lime (clamshells) for soda lime glass and beech ash for wood ash glass. Each of the three major glass types contains specific Rare Earth Element (REE) concentrations mainly contained in quartz and its intergrown minerals. 50 Paleozoic and Mesozoic sandstones from Central Europe represent the quartz composition. The REE pattern of these glasses apparently indicates major compositional stages of the Continental Earth's Crust. The boron to lithium and sodium to potassium ratios as in seawater suggest reactions of materials for soda glass with seawater. Negative Ce anomalies in the three glasses are caused by reactions of quartz with seawater.  相似文献   

Evolution of animal multicellularity stimulated by dissolved organic carbon in early Ediacaran ocean: DOXAM hypothesis     

AKIHIRO KANO  YOKO KUNIMITSU  TETSUHIRO TOGO  CHIDURU TAKASHIMA  FUMITO SHIRAISHI  WEI WANG 《Island Arc》2011,20(2):280-293

Oxygenation of the ocean is presumed to be an important factor stimulating the evolution of multicellular animals. The appearance of the Ediacaran‐type biota (ca 575 Ma) was assigned to the aftermath of the Gaskiers glaciation (ca 580 Ma), when substantial oceanic oxygenation is believed to have started. However, several lines of evidence reveal that at least sponges evolved before this oxygenation. For understanding the first stage of animal evolution, we propose the hypothesis that Dissolved Organic Carbon (DOC) Stimulated the evolution for Animal Multicellularity (DOXAM). Recent geochemical studies of the Ediacaran sedimentary sequences have indicated that a substantial DOC mass was developed in the stratified ocean after the Marinoan glaciation (655–635 Ma), and this was supported by the inorganic and organic carbon isotope profiles of the Doushantuo Formation in South China. The DOC mass was an oxygen consumer in the water column; however, it could have provided a food source for filter‐feeding animals such as sponges and cnidarians, and established a primitive food‐web. Such an ecological structure is recognized in modern deep‐sea coral mounds. Results from the integrated ocean drilling program (IODP) Expedition 307 for a mound in northeastern Atlantic suggested that organic carbon suspended around the density boundary in the water column is the key feature to feed the heterotrophic deep‐sea coral community. Our hypothesis is consistent with the fact that the two most primitive animal phyla (Porifera and Cnidaria) are filter feeders. The evolution of filter feeding ecosystems removed the DOC mass and may have contributed to ocean oxygenation in the terminal Neoproterozoic when animal evolution passed into the second stage, with the appearance of bilaterians.  相似文献   

A multi-method approach for the study of lanthanum speciation in coastal and estuarine sediments     

Parthasarathi Chakraborty  P.V. Raghunadh BabuV.V. Sarma 《Journal of Geochemical Exploration》2011

Two independent analytical methods (sequential extraction and kinetic extraction methods) were applied in order to understand the distribution and speciation of La in the coastal and estuarine sediments from the central east coast of India. Sequential extraction study revealed that La was primarily present as inert complexes (~ 50–60% of the total La) in all the sediments. Amounts of ~ 20–30% of the total La in all the sediments were found to associate with the total organic carbon (TOC) in the sediments. The dissociation rate constants of La–sediment complexes obtained from kinetic extraction studies revealed that the concentration of thermodynamically weak complexes of La gradually increased with the increasing La/TOC ratio in the sediments.  相似文献   

Geochemistry of the Jurassic and Upper Cretaceous shales from the Molango Region,Hidalgo, eastern Mexico: Implications for source-area weathering,provenance, and tectonic setting   总被引：3，自引：0，他引：3  

John S. Armstrong-Altrin  Ramasamy Nagarajan  Jayagopal Madhavaraju  Leticia Rosalez-Hoz  Yong Il Lee  Vysetti Balaram  Adriana Cruz-Martínez  Gladis Avila-Ramírez 《Comptes Rendus Geoscience》2013,345(4):185-202

This study focuses on the Jurassic (Huayacocotla and Pimienta Formations) and Upper Cretaceous (Méndez Formation) shales from the Molango Region, Hidalgo, Mexico. In this article, we discuss the mineralogy, major, and trace element geochemistry of the Mesozoic shales of Mexico. The goal of this study is to constrain the provenance of the shales, which belong to two different periods of the Mesozoic Era and to understand the weathering conditions and tectonic environments of the source region.  相似文献   

不可忽视的汶川大震前奇热奇旱奇涝特异背景剖析   总被引：1，自引：0，他引：1  

李连芳  杨金莲  黄菊梅  吴奇良 《高原地震》2008,20(4):69-75

通过对汶川大震前的21个月和10个月,在川渝地区出现的较长期高温热浪,严重干旱和暴洪（简称奇热奇旱奇涝“三奇”）并使下垫面生态气象出现奇差等大气物理现象的空前异常的分析,发现汶川大震恰处“三奇”中心西部边缘,大震发生在“三奇”后21个月和10个月。在此基础上探讨了他们之间的物理机制,并提出孕震地球物理过程和“三奇”大气物理过程可能存在某种“能”和“力”的交织影响假设。  相似文献   

Biogeochemical investigation in south eastern Andhra Pradesh: the distribution of rare earths, thorium and uranium in plants and soils   总被引：4，自引：0，他引：4  

K. K. Raju  A. N. Raju 《Environmental Geology》2000,39(10):1102-1106

The concentration of rare earth elements (REE), thorium and uranium were determined by inductively coupled plasma mass spectrometry (ICP−MS) in the plant species, Pterocarpus santalinus, P. marsupium and P. dalbergioides, and the soils on which they were growing. Higher concentrations of lanthanum (La), cerium (Ce) were observed in both plants and soils. Large amounts of thorium and uranium were found in the soil. In all tree species, the concentration of REEs were higher in the heartwood than the leaves. The heartwood of P. santalinus accumulated larger quantities of uranium (average concentration of 1.22 ppm) and thorium (mean value of 2.57 ppm) than the other two species. Received: 8 September 1999 · Accepted: 15 December 1999  相似文献   

动物蛋白酶1058水解ti鱼可溶性蛋白质     

朱碧英  翟恩礼 《海洋学研究》2000,18(4):47-51

研究了动物蛋白酶 1 0 58水解鱼是鱼蛋白时 ,酶量、温度、作用时间对鱼是鱼蛋白质水解率和苦味的影响。结果表明 :酶浓度的提高 ,水解时间的延长 ,均使鱼是鱼蛋白水解率明显提高。最适水解温度为 50℃ ,当温度高于 50℃时 ,水解率逐渐下降 ,蛋白酶开始失活。苦味值随水解率提高而增加。用正交试验的方法 ,经综合分析和试验得出 ,该蛋白酶水解鱼是鱼的最佳条件是酶量与底物之比为 1 .5∶ 1 0 0 0 ;温度为 50℃ ;水解时间为 4h。  相似文献   

豫北平原的沙质草地及其畜牧业发展     

赵雪 《中国沙漠》2000,20(Z2):167-170

豫北平原的沙质草地分布于黄河多次泛滥改道冲积形成的沙丘、沙地。其主要类型有:①以白茅、达乌里胡枝子为主的草从草地;②刺槐、杨树等林地下层以藜、白茅、茜草等为主的林下草地;③以碱茅、狗牙根等为主的低湿草地。沙质草地的主要特征为种类组成简单,牧草产量低(<2 000 kg·hm^-2)且利用过度。但多种优良栽培牧草在沙地生长良好,可获较高产量。在沙地开发中,应针对各草地类型采取相应措施改造为人工、半人工草地。同时应结合沙地多种林木、果树和经济作物种植,建设农牧林复合经营的系统。畜牧业开发应以产业化为主导,发展适应市场需求的优良畜种,实行适度规模经营。  相似文献   

西方超越人类的地理学研究进展   总被引：4，自引：0，他引：4  

卢薇  尹铎  朱竑 《地理学报》2019,74(10):2178-2191

随着现代科技发展与社会环境变化,人类与非人类的边界日益模糊,这使得以往研究中未能引起足够重视的非人类生命与物质逐渐引起学者们的关注。21世纪以来,在西方地理学界兴起的“回归唯物主义”思潮中,超越人类的地理学（MTHG）应运而生,并成为探索人类与非人类共同构成的世界的重要途径之一。通过对298篇相关期刊论文及著作的分析发现,超越人类的地理学主张“关系本体论”,其产生受到行动者网络理论、生物哲学与非表征理论的深刻影响,现有研究议题聚焦于新动物地理学与自然保护、城市社会文化与生态政治、物质性与商品经济、身体与生命健康、气候变化与环境问题等方面。本文通过梳理超越人类的地理学的理论源起并剖析各议题的经典研究案例,以期为中国地理学研究提供新的视域。  相似文献   

山东省微山郗山地区稀土矿成矿规律探讨          下载免费PDF全文

兰君 《山东国土资源》2019,35(6)

近年来,在鲁西峄城凸起南西部郗山地区的稀土矿勘探工作取得了飞速进展。该区发育有较强的航空放射性异常,分别为г-22-61、г-22-62和г-22-63三个次级放射性异常,г-22-63异常对应已知的郗山稀土矿。以往工作表明,该稀土矿床具"岩体和构造"联合控矿的特征,即稀土矿体受控于中生代燕山期郗山杂岩体与各种类型的(构造)接触带;其成矿时代为早白垩世(110～119Ma),与鲁西地区其他稀土矿形成时代基本一致;稀土矿成矿物质主要来源于富集地幔,成矿流体为高浓度、中高温流体,成矿流体来源于碱性岩浆分异。放射性异常较强的地段进行稀土矿找矿工作最为有利。  相似文献