Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems     

S.A. Crosby  G.E. Millward  E.I. Butler  D.R. Turner  M. Whitfield 《Estuarine, Coastal and Shelf Science》1984,19(2):257-270

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.  相似文献   

Chlorinated hydrocarbons in the seawater and surface sediments of Blanca Bay,Argentina     

JoséLuis Sericano  Adan E. Pucci 《Estuarine, Coastal and Shelf Science》1984,19(1):27-51

In order to characterize our study area and to provide reference values to be used in the future to measure the changes produced by an increase in contamination, the concentrations of chlorinated hydrocarbons have been investigated in fifty-one samples of seawater, taken at four different depths: air-sea interface, surface, one metre and bottom waters, and in twenty-three samples of surface sediments from Blanca Bay, Argentina. Of eleven organochlorine compounds we were looking for (α BHC, lindane, heptachlor, δ BHC. aldrin, heptachlor epoxide, dieldrin, o-p′DDD, p-p′DDD, o-p′DDT and p-p′DDT), seven could be detected in seawater and three in surface sediments with the following mean concentrations: α-BHC=48·2 ng l^?1; lindane=54·2 ng l^?1; heptachlor=45·0 ng l^?1; δ BHC=12·5 ng l^?1; aldrin=61·8 ng l^?1 and ΣDDT=67·0 ng l^?1; and δ BHC=3·2 ng g^?1; lindane=4·2 ng g^?1 and heptachlor=1·0 ng g^?1 for seawater, regarding the surface waters, and sediment samples, respectively.Concentration factors among the different water layers were also studied to see if there was any correlation between chlorinated hydrocarbon contents and the water depths from which the samples were taken. As a mean value, the air-sea interface water contains 18 times more of these compounds than that of the water near the bottom. A comparison of the values corresponding to seawater and surface sediments from our study area with those levels measured in samples from other geographic locations is also presented.With the purpose to detect a relationship between chlorinated hydrocarbon concentrations and the contents of particulate matter (PM) on the one hand, and particulate organic material (POM) on the other hand, four groups of samples containing different amounts of PM and POM, respectively were formed. From a comparison of the results obtained, lindane, heptachlor and δ BHC showed a tendency to lower concentrations in those samples containing little PM whereas α BHC and aldrin remained without important changes. No significant correlation was found between organochlorine levels and contents of POM.  相似文献   

The hydrogeothermal basin of Sofia graben (Bulgaria)     

K.?D.?ShterevEmail author 《Environmental Geology》2004,46(5):651-660

Abstract In the Mesozoic basement and Neogene filling of Sofia tectonic graben a non-homogenous system of thermal water reservoirs connected to a united hydrogeothermal basin occurred. The basin contains and reproduces five types of low mineralized thermal waters and four types of mineralized thermal waters with exotic composition. The water temperatures are 30–80(90) ^°C. The total potential of the basin is assessed at 500 l/s thermal waters and 48 MWt thermal power. The utilization of thermal waters in the area of the Bulgarian capital has its roots and traditions in antiquity, and a promising future. The new town plan of Sofia provides construction of 35 centers for developing a versatile and prosperous hydrothermal business.  相似文献   

Trace elements in medium-temperature (40–80 °C) thermal waters from the Mura basin (North-Eastern Slovenia)     

Peter?KraljEmail author 《Environmental Geology》2004,46(5):622-629

Medium-temperature thermal waters in the Mura basin occur in hydrogeological systems different in age, burial depth, temperature, porosity and permeability, and the presence of free carbon dioxide which penetrates through the fractures from pre-Tertiary basement. The waters commonly belong to sodium-bicarbonate hydrogeochemical facies, but may have significantly different amounts of total dissolved solids, including trace elements. Thermal waters occurring in low-permeable, well-compacted and moderately fractured Tertiary sediments older than Upper Pliocene are the richest in trace elements, although their abundance may be very variable from one aquifer to another. The ratios of major alkaline and alkaline earth elements (Na, K, Ca) and trace elements (Li, Rb, Cs, Ba, Sr) commonly show relative enrichment in highly mineralised waters with respect to the waters with lower mineralisation. Rare earth elements (REEs) and Y show only minor fractionation in the highly mineralised waters, whereas in the waters with lower mineralisation strong fractionation of heavy rare earth elements (HREEs) over light rare earth elements (LREEs) occurs, along with a pronounced positive europium anomaly. Positive Th/U ratios are commonly observed, although both actinide elements occur in the range of some hundredths of ppb to some ppb. Trace elements were particularly useful in the study of well cycling in two hydraulically interconnected geothermal wells in the town of Murska Sobota, which produce a mixture of low- and high-mineralised waters.  相似文献   

内陆水体叶绿素a浓度反演的区域化三波段模型研究   总被引：1，自引：0，他引：1  

李方  徐京萍  马荣华  段洪涛  张柏 《遥感学报》2011,15(6):1163-1179

以太湖和石头口门水库为例,建立了一种可直接计算水体叶绿素a浓度的区域化三波段模型。该模型通过对研究水体的光学特性分析,明确三波段组合与叶绿素a浓度间的函数关系参数,不仅可较好指示研究水体叶绿素a浓度水平,而且大大减小了回归算法所带来的模型不确定性。利用高精度、长时间序列的水体光学特性观测数据,建立针对不同研究水体的区域化三波段模型可为实现内陆水体叶绿素a浓度遥感监测业务化运行提供方法借鉴。  相似文献   

Biogeochemistry of dissolved carbon,major, and trace elements during spring flood periods on the Ob River     

Sergey N. Vorobyev  Oleg S. Pokrovsky  Larisa G. Kolesnichenko  Rinat M. Manasypov  Liudmila S. Shirokova  Jan Karlsson  Sergey N. Kirpotin 《水文研究》2019,33(11):1579-1594

Detailed knowledge of the flood period of Arctic rivers remains one of the few factors impeding rigorous prediction of the effect of climate change on carbon and related element fluxes from the land to the Arctic Ocean. In order to test the temporal and spatial variability of element concentration in the Ob River (western Siberia) water during flood period and to quantify the contribution of spring flood period to the annual element export, we sampled the main channel year round in 2014–2017 for dissolved C, major, and trace element concentrations. We revealed high stability (approximately ≤10% relative variation) of dissolved C, major, and trace element concentrations in the Ob River during spring flood period over a 1‐km section of the river channel and over 3 days continuous monitoring (3‐hr frequency). We identified two groups of elements with contrasting relationship to discharge: (a) DIC and soluble elements (Cl, SO₄, Li, B, Na, Mg, Ca, P, V, Cr, Mn, As, Rb, Sr, Mo, Ba, W, and U) negatively correlated (p < 0.05) with discharge and exhibited minimal concentrations during spring flood and autumn high flow and (b) DOC and particle‐reactive elements (Al, Fe, Ti, Y, Zr, Nb, Cs, REEs, Hf, Tl, Pb, and Th), some nutrients (K), and metalloids (Ge, Sb, and Te), positively correlated (p < 0.05) with discharge and showed the highest concentrations during spring flood. We attribute the decreased concentration of soluble elements with discharge to dilution by groundwater feeding and increased concentration of DOC and particle‐reactive metals with discharge to leaching from surface soil, plant litter, and suspended particles. Overall, the present study provides first‐order assessment of fluxes of major and trace elements in the middle course of the Ob River, reveals their high temporal and spatial stability, and characterizes the mechanism of river water chemical composition acquisition.  相似文献   

大伙房水库及浑河1∶2000水下地形测量项目的开展     

邰占宇 《测绘与空间地理信息》2017,40(5)

主要介绍了大伙房水库及浑河水下地形测量项目开展的工作要点与作业流程,着重对实际测绘过程中发现的问题及处理方法进行了系统的论述。  相似文献   

A STUDY OF RAPID DECAY TYPHOONS IN OFFSHORE WATERS OF CHINA     

郑峰  曾智华  雷小途  陈联寿  杨涛  朱景 《热带气象学报(英文版)》2017,23(4):471-480

On the basis of NCEP/NCAR reanalysis data and yearbooks of CMA tropical cyclones, statistical analysis is performed for 1949—2013 offshore typhoons subjected to rapid decay(RD). This analysis indicates that RD typhoons are small-probability events, making up about 2.2% of the total offshore typhoons during this period. The RD events experience a decadal variation, mostly in the 1960 s and 1970 s(maximal in the 1970 s), rapidly decrease in the 1980 s and 1990 s and quickly increase from 2000. Also, RD typhoons show remarkable seasonal differences: they arise mainly in April and July-December, with the prime stage being in October-November. The offshore RD typhoons occur mostly in the South China Sea(SCS) and to a lesser extent in the East China Sea(ECS); however, none are observed over the Huang Sea and Bo Sea.Composite analysis and dynamic diagnosis of the RD typhoon-related large-scale circulations are performed.Physical quantities of the composite analysis consist of 500-h Pa height and temperature fields, vapor transfer, vertical wind shear(VWS), density of core convection(DCC), and high-level jet and upper-air outflow of the typhoon. The results suggest that(1) at the 500-h Pa height field, the typhoon is ahead of a westerly trough and under the effects of its passing trough;(2) at the temperature field, the typhoon is ahead of a temperature trough, with an invading cold tongue present;(3) at the vapor transfer field, water transfer into the RD typhoon is cut off; and(4) at higher levels, the related jet weakens and the outbreak of convection becomes attenuated in the typhoon core. In addition, VWS bears a relation to the RD typhoon; in particular, strong VWS favors RD occurrence.The differences in RD events between the SCS and ECS show that for the RD, the VWS of the ECS environmental winds is markedly stronger in comparison with its SCS counterpart. The cold advection invading into the typhoons is more intense in the SCS than in the ECS, and the low-level vapor transfer and high-level outflow are weaker in the SCS RD typhoons.Data analysis shows that sea surface temperature(SST), VWS, and DCC can be employed as efficient factors to predict RD occurrence. With appropriate SST, VWS, and DCC, a warning of RD occurrence can be given 36, 30-36,and 30 h, respectively, in advance. These values suggest that atmospheric SST responses lag. Owing to this time lag,the prediction of RD typhoons is possible.  相似文献   

Seasonal Study of Methane and Nitrous Oxide in the Coastal Waters of the Southern Baltic Sea   总被引：2，自引：0，他引：2  

H.W. Bange  S. Dahlke  R. Ramesh  L.-A. Meyer-Reil  S. Rapsomanikis  M.O. Andreae 《Estuarine, Coastal and Shelf Science》1998,47(6):807-817

Atmospheric and dissolved methane (CH₄) and nitrous oxide (N₂O) were measured in the unique coastal ecosystem of theBoddenwaters, including the western Oder estuary, (southern Baltic Sea) during five campaigns between 1994 and 1997. The CH₄saturations, ranging from 105–15 500%, showed great spatial and temporal variability with maximum values in September and minimum values in December. The N₂O saturations were in the range of 91–312% with a maximum in March. Enhanced concentrations of both gases were observed only in the western Oder estuary near the mouth of the Peene River. Thus, we conclude that the distributions of CH₄and N₂O in the investigatedBoddenwaters are, directly or indirectly, linked to the Peene River runoff and not to the Oder River. Our estimate of the annual CH₄emissions from theBoddenwaters to the atmosphere indicates a significant contribution (c. 17%) to the overall CH₄emissions from the Baltic Sea. In contrast, theBoddenwaters represent only a small source for atmospheric N₂O.CH₄production rates estimated from sediment slurry experiments revealed a significant spatial variability and indicated that methanogenic activity was related to acetate consumption in the surface sediment layer. Sedimentary CH₄production might depend on different amounts of accumulation of organic material.  相似文献   

福建近海五种主要捕捞作业适宜捕捞力量的研究   总被引：1，自引：0，他引：1  

卢振彬  颜尤明 《台湾海峡》1998,17(1):104-109

本文根据福建省定置、拖、围、刺、钓五种捕捞作业在本省近海的捕捞力量和渔获量,并以１９９４年单位功率的渔捞效率为基准进行逐年捕捞力量的标准化,应用Ｓｃｈａｅｆｅｒ和Ｆｏｘ两同电脑分别估算它们的ｆＭＳＹ和ＭＳＹ。结果两处在算的ｆＭＳＹ和ＭＳＹ的平均值是：定置网为８．９０尤明等３７．４１万ｔ;推网为５５．８８万ＫＷ,３５．５１万ｔ;为桃围网为７．１２万ＫＷ,１０．０６万ｔ;刺网为１５．１９万ＫＷ,９．５  相似文献