西藏羌塘西北部干枯沟地区早三叠世晚期碱性岩类的发现     

钟华明  童劲松  鲁如魁  夏军 《地质通报》2006,25(7):806-811

碱性花岗岩分布于西藏羌塘北部的花岗岩带内,岩石K2O Na2O含量达11.27%～12.02%,具高铝、高碱、低铁镁组分的特征,属碱性花岗岩类.地球化学特征表明,该碱性岩形成于后碰撞期.形成该岩体的物质主要来源于加厚陆壳的中下部,反映了研究区古特提斯闭合后经历了陆内造山阶段.霞石正长岩同位素锆石U-Pb年龄为248.7Ma±2.6Ma,相当于早三叠世晚期.碱性花岗岩的出现是西藏西北部古特提斯造山带崩塌开始的岩石学标志.  相似文献   

青海西秦岭地区晚中生代基性火山岩地球化学特征及构造意义   总被引：4，自引：0，他引：4  

范立勇  王岳军  李晓勇 《矿物岩石》2007,27(3):63-72

对青海省同仁县多禾茂地区火山岩进行系统的元素同位素地球化学研究表明:该地区白垩纪地层中发育的中基性火山岩,属于碱性火山岩系,岩石类型主要为玄武岩,该套玄武岩具有低且变化较小的Si O2质量分数(44.98%~48.20%),低MgO的质量分数高,变化较大(8.15%~10.98%),具有较高的Cr(208×10-6~418×10-6)和Ni(166×10-6~231×10-6)质量分数。所有样品都表现出轻稀土富集的右倾平滑分布模式,轻重稀土分异中等,(La/Yb)CN=10.09~27.2,重稀土弱分异,(Gd/Yb)CN=2.92~4.67,Eu异常不明显,Eu*/Eu=0.99~1.04。Ba,Nb-Ta和Th-U不亏损,Rb,K相对亏损,Sr正异常。该区火山岩具有亏损的Sr-Nd同位素组成,Sr-Nd同位素组成变化范围不大[87Sr/86Sr(t)=0.7033~0.7039,εNd(t)=6.13~8.03,t=110 Ma],与Hawaii-OIB的Sr-Nd同位素组成相似。其所有地球化学特征表明该火山岩具有类似OIB的特征,可能是含石榴子石橄榄岩低度部分熔融的产物。结合对西秦岭地质构造背景和演化历史的分析,暗示该地区晚中生代岩浆源区来源于软流圈,其起源可能与岩石圈拆沉作用,软流圈地幔上涌和岩石圈伸展减薄有关,可为秦岭大别造山带中生代岩石圈演化提供了有利的直接证据。  相似文献   

张家口水泉沟碱性杂岩体单颗粒锆石^207Pb／^206Pb年龄分析   总被引：10，自引：1，他引：9  

梁华英  莫测辉 《地球化学》1998,27(1):59-65

用单颗粒锆石铅蒸发－沉积法分析张家口地区赋金水泉沟碱性杂岩体形成时代,保持封闭体系３颗锆石的＾２０７Ｐｂ／＾２０６Ｐｂ值表面年龄在１６０７－１６６７Ｍａ之间,与锆石Ｕ－Ｐｂ法上交点年龄（１７１８±６５）Ｍａ基本一致,水泉沟碱性杂岩体是１６－１７亿前形成的。  相似文献   

Geochemical approach to magmatic evolution of Mt. Erciyes stratovolcano Central Anatolia, Turkey   总被引：1，自引：0，他引：1  

Biltan Kürküoglu  Erdal Sen  Erkan Aydar  Alain Gourgaud  Niyazi Gündogdu 《Journal of Volcanology and Geothermal Research》1998,85(1-4)

Erciyes stratovolcano, culminating at 3917 m, is located in the Cappadocian region of central Anatolia. During its evolution, this Quaternary volcano produced pyroclastic deposits and lava flows. The great majority of these products are calc-alkaline in character and they constitute Kocdag and Erciyes sequences by repeated activities. Alkaline activity is mainly observed in the first stages of Kocdag and approximately first-middle stages of Erciyes sequences. Generally, Kocdag and Erciyes stages terminate by pyroclastic activities. The composition of lavas ranges from basalt to rhyolite (48.4–70.5 wt.% SiO₂). Calc-alkaline rocks are represented mostly by andesites and dacites. Some compositional differences between alkaline basaltic, basaltic and andesitic rocks were found; while the composition of dacites remain unchanged. All these volcanics are generally enriched in LIL and HFS elements relative to the orogenic values except Rb, Ba, Nb depleted alkaline basalt. ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd isotopic composition of the volcanics range between 0.703344–0.703964, 0.512920–0.512780 for alkaline basalts and change between 0.704322–0.705088, 0.512731–0.512630 for alkaline basaltic rocks whereas calc-alkaline rocks have relatively high Sr and Nd isotopic ratios (0.703434–0.705468, 0.512942–0.512600). Low Rb, Ba, Nb content with high Zr/Nb, low Ba/Nb, La/Yb ratio and low Sr isotopic composition suggest an depleted source component, while high Ba, Rb, Nb content with high La/Yb, Ba/Nb, low Zr/Nb and low ⁸⁷Sr/⁸⁶Sr ratios indicate an OIB-like mantle source for the generation of Erciyes alkaline magma. These elemental and ratio variations also indicate that the different mantle sources have undergone different degree of partial melting episodes. The depletion in Ba, Rb, Nb content may be explained by the removal of these elements from the source by slab-derived fluids which were released from pre-collisional subduction, modified the asthenospheric mantle. The chemically different mantle sources interacted with crustal materials to produce calc-alkaline magma. The Ba/Nb increase of calc-alkaline samples indicates the increasing input of crustal components to Erciyes volcanics. Sr and Nd isotopic compositions and elevated LIL and HFS element content imply that calc-alkaline magma may be derived from mixing of an OIB-like mantle melts with a subduction-modified asthenospheric mantle and involvement of crustal materials in intraplate environments.  相似文献   

广东从化石岭碱性杂岩的岩石学特征及其地质意义   总被引：7，自引：2，他引：5  

肖振宇  杨学明 《高校地质学报》1998,4(2):133-138

对广东从化石岭碱性杂岩体进行了１：１万地质调查和填图,并进行了详细的岩石力学研究。其结果表明：杂岩体由霞石角闪石正长岩、角闪石正长岩、墨云母正长岩等岩性组成,为Ａ－型花岗岩的分异结晶作用所形成,产于板内引张构造环境,与深大断裂有关。岩体本身已构成霞石正长岩矿床,具有较高的工业利用和经济价值。  相似文献   

牙鲆孵化酶的分离纯化及其部分生物化学性质研究          下载免费PDF全文

史振平  樊廷俊  丛日山  汤志宏  汪小锋  付永锋 《海洋科学》2008,32(11):44-50

利用凝胶过滤柱层析和阴离子交换柱层析技术，从牙鲆（Paralichthys olivaceus）胚胎孵化液中分离纯化出了大小约为34．8ku的牙鲆孵化酶。该酶卵膜裂解的最适反应温度为35℃，最适pH为7．0；对底物酪蛋白的米氏常数Km值为1．53mmol／L。该酶对丝氨酸蛋白酶和胰蛋白酶的特异性抑制剂非常敏感，而对其他蛋白酶抑制剂不敏感，表明该酶极可能是一种丝氨酸蛋白酶类型的胰蛋白酶。此外，该酶可浓度依赖性地被EDTA所抑制，被Cu^2＋所强烈抑制，被Ca^2＋和Mg^2＋所激活，对Zn^2＋则不敏感，表明该酶很可能是一种金属蛋白酶。  相似文献   

准噶尔盆地玛湖凹陷风城组页岩自生长英质矿物的成因机理及其储层改造意义     

郭佩  柏淑英  李长志  雷海艳  徐文礼  张锡婷  文华国 《地质学报》2023,97(7):2311-2331

玛湖凹陷二叠系风城组是近几年准噶尔盆地页岩油接替的主攻领域,但其页岩成岩改造强烈,原始岩性归属尚不明确。X射线粉晶衍射测得风城组页岩黏土矿物含量普遍较低（<10%）,长英质矿物含量较高（60%~80%）。薄片分析发现风城组长英质页岩存在三种类型：① 粉砂级（4~63 μm）长石和石英碎屑含量丰富,为典型的粉砂岩;② 燧石条带和团块发育,为富硅页岩;③ 长英质基质发育,呈非碎屑状,且火山尘及火山玻璃少见,其矿物组成和形态与典型的黏土岩、粉砂岩及沉凝灰岩明显不同。背散射图像和高精度扫描电镜测得该长英质基质由碎屑和自生石英、钾长石和钠长石共同组成,可见黏土矿物、碎屑钾长石和钠长石向自生石英转化,碎屑钾长石向自生钠长石转化。通过调研全球中新生代碱湖沉积中自生硅酸盐矿物组合特征和成岩演化规律,探讨了二叠系风城组“贫”黏土矿物和“富”自生长英质矿物的原因,并提出风城组发育一类“改造长英质页岩”,主要由原始黏土和长石碎屑矿物和火山物质经过多期成岩改造而成。早期高碱（pH>9）沉积和成岩环境增加了SiO2溶解度和元素铝的活性,导致黏土矿物、泥级—细粉砂级长英质碎屑、火山灰等在入湖后发生“溶解、转化”,形成次稳定的硅酸盐矿物,如沸石和含镁蒙皂石,在经历漫长埋藏成岩后进一步转化为更为稳定的石英、钾长石和钠长石。碱湖页岩的成岩改造过程消耗了黏土矿物和火山灰,极大增加了页岩脆性,同时伴生了大量基质溶孔和晶间孔,是一类优质的页岩储层。  相似文献   

河北矾山超钾质岩浆氧逸度及含水性特征的磷灰石地球化学记录     

舒小超  孟凡巍  陶瑞  王坤 《地质学报》2023,97(12):4101-4116

产于华北克拉通北缘的晚三叠世矾山超钾质碱性岩杂岩体主要由单斜辉石岩和辉石正长岩等组成,以发育内生磷灰石-磁铁矿矿床而闻名。本文选取矾山杂岩体中的磷灰石为研究对象,通过测试磷灰石的主微量元素及原位Sr-Nd同位素组成以探讨母岩浆的氧逸度及含水性特征。研究表明,矾山磷灰石以轻稀土元素富集、重稀土元素亏损为特征,显示出缺乏显著Ce异常的“右倾”的稀土配分型式,且具有较低的Ga含量及较高的δEu值,暗示杂岩体具有较高的岩浆氧逸度,这也得到了磷灰石Mn氧逸度计的支持。所有磷灰石以高Sr、低Y为特征,具有较高的Sr/Y(>30)和La/Yb(>90)比值,且Sr/Y与La/Yb存在明显的正相关关系,表明矾山超钾质岩浆具有较高的含水量。矾山磷灰石的原位Sr-Nd同位素投点位于地幔序列,明显偏离地壳趋势。母岩浆的“氧化且富水”特征是矾山杂岩体得以发生磷灰石-磁铁矿矿化的重要因素,其主要与板片俯冲过程中蚀变洋壳对岩石圈地幔的交代作用有关。通过对比矾山杂岩体与全球范围内其他地质环境中磷灰石的成分数据,发现具有“高Sr、低F、少Cl”特征的磷灰石可作为识别超钾质碱性岩杂岩体(及其相关金属矿床)的...  相似文献   

Cenozoic high-K alkaline magmatism and associated Cu–Mo–Au mineralization in the Jinping–Fan Si Pan region,southeastern Ailao Shan–Red River shear zone,southwestern China–northwestern Vietnam     

《Journal of Asian Earth Sciences》2014

The Jinping–Fan Si Pan (JFP) Cenozoic magmatic and Cu–Mo–Au metallogenic belt in the southeastern part of the Ailao Shan shear zone host the Tongchang, Chang′an, Habo, and Chinh Sang Cu–Mo–Au deposits. These deposits form an integrated epithermal-porphyry regional mineralization system associated with 40–32 Ma high-K alkaline magmatism. The magmatic rocks in the belt have relatively low TiO₂ (<0.73 wt%), P₂O₅ (<0.29 wt%), and FeO^* (<4.99 wt%), and high Na₂O (2.86–4.75 wt%) and K₂O (4.01–7.98 wt%). They also have high contents of incompatible trace elements, and are enriched in LILE (Rb, Ba, K, Sr) and LREE. They have marked Nb, Ta, Ti and P depletion in primitive mantle-normalized spidergrams, and plot close to the EMII mantle field in the Sr–Nd isotopic diagram. These characteristics are similar to those of the Eocene high-K alkaline rocks along the northern Ailao Shan belt, eastern Tibet plateau. The sulfur and lead isotope analyses of sulfide minerals from both the ores and related magmatic rocks confirm the involvement of a magmatic ore fluid. The Cenozoic alkaline intrusions and Cu–Mo–Au mineralization in the JFP were formed prior to the initiation of left-lateral shearing along the Ailao Shan shear zone. The magmas appear to have been derived from enriched mantle, possibly with mixing of materials from the buried Tethyan oceanic lithosphere, and/or crust.  相似文献   

Geochemical characteristics and geological implication of Zijinshan alkaline rocks in Lin County in the west of North China Craton     

GUO Xiyun 《中国地质调查》2014,7(5):66-76

The Zijinshan rocks in Lvliang area of Shanxi Province, are one of the famous alkaline plutons in China. The petrography and petrogeochemistry of the main rocks of the rock mass were studied to explore the material source and geological significance of Zijinshan alkaline rock mass. The results show that Zijinshan rocks of all stages show characters of low silicon, rich alkali and high potassium, which indicates zijinshan rocks belong to potassium alkaline rocks. These rocks demonstrate a high degree of fractionation and are characterized by the richness of LREE and the poorness of HREE, without obvious Eu anomaly. The trace element pattern exhibits the enrichment of large ion lithophile elements, such as Rb, Ba, K and Sr, and relative depletion of high field strength elements, such as Th, Nb, Ta, La, Ce, Nd, P and Ti. The magma of Zijinshan rocks comes from a deeper source and is closely related to the enriched mantle. The mechanism of magma evolution is mainly partial melting and it may be inter-contamination of continental crust materials. Combined with the characteristics of alkaline and partial alkaline rocks of same age in many places in Shanxi, the authors deduce that the alkaline magma activity in the middle of North China during the Early Cretaceous is closely to the destruction of North China Craton under the background of the subduction of Pacific plate.  相似文献