南水北调中线突发水污染事件的快速预测          下载免费PDF全文

龙岩  徐国宾  马超  李有明 《水科学进展》2016,27(6):883-889

依据南水北调中线干渠资料,开展了正常输水情况下串联明渠内可溶污染物浓度分布规律数值模拟研究。采用数值模拟、数学归纳和统计分析方法,提出表征污染物输移扩散特征的峰值输移距离、污染带长度和峰值浓度的快速预测公式;通过示范工程验证了快速预测公式的可行性。结果表明:①串联明渠内,峰值输移距离随渠道流速减小而减小,并且污染带长度增加值随明渠内流速减小而减小,但是峰值浓度随明渠流速减小而增加;②快速预测公式计算结果与现场试验实测结果的误差均不到15%,证明了快速预测公式的合理性和可行性。这些研究结果为南水北调中线工程突发可溶性水污染事件应急预警方案的制定提供了科学依据。  相似文献   

海洋上层暖水在热带气旋迅速增强中的作用:基于台风威马逊(1409)的个例研究   总被引：5，自引：1，他引：4  

孙佳  左军成  凌征  闫运伟 《海洋学报(英文版)》2016,35(3):63-68

在登陆海南岛之前,台风威马逊在南海北部从热带风暴级别迅速增强成为超强台风。观测数据的分析结果显示,海洋上层的异常暖水在威马逊的迅速增强过程中扮演了重要的角色。威马逊期间,南海北部的海表面温度相比于气候态海表面温度暖很多。这部分异常暖水为威马逊提供了更多的能量,从而导致了威马逊的迅速增强。数值模拟结果进一步证明,南海北部的暖水在台风威马逊的迅速增强过程中起重要作用。如果没有这团异常暖水的影响,威马逊只增强25 hPa,仅为有暖水影响条件下增强程度的58.1%。  相似文献   

Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy          下载免费PDF全文

Atsuyuki Ohta  Ran Kubota 《Geostandards and Geoanalytical Research》2016,40(1):117-134

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).  相似文献   

基于重力及重力梯度数据的位场偏移成像     

田明阳  吴燕冈  张爽  颜鸿群  张瑞森 《世界地质》2018,37(1):218

为了验证位场偏移快速成像方法的有效性以及对比基于重力和重力梯度数据的偏移成像的效果,笔者利用MATLAB编写了重力及重力梯度数据位场偏移成像的算法,并进行了模型正演计算,发现基于梯度数据的偏移成像的横向分辨率、抗噪性和抗背景场能力好于重力数据的偏移成像,并且能够较好的确定模型的中心埋深。将此方法应用于葫芦岛市黑鱼沟的某铅锌矿洞的深度计算中,验证了该方法的有效性。  相似文献   

长江口和浙江近岸海域表层沉积物中颗粒磷的形态分布和影响因素     

姚华波  张朝晖  金海燕  陈建芳 《海洋学研究》2022,40(4):73-81

研究长江口和浙江近岸海域的水团流向、缺氧程度、潮汐作用以及养殖活动对表层沉积物中颗粒磷赋存形式的影响,对东海生态环境的可持续发展有着重要的意义。长江口以北和浙江近岸泥质区各存在一个缺氧中心,杭州湾属于强潮区,而象山港遍布养殖场。2018年8—9月在上述4个海域分别采集表层沉积物,采用SEDEX方法进行了颗粒磷的形态划分和含量测定。研究结果表明：在长江口外北部缺氧区和浙江近岸泥质区的南部缺氧区,由于沉积物-水界面的还原环境可以活化铁结合态磷,使之转变为生物可以直接利用的弱吸附态无机磷,因此表现出沉积物中铁结合态磷的低值和弱吸附态无机磷的高值;前者的缺氧程度高于后者,因此其铁结合态磷的含量相应更低。杭州湾和象山港海域均受潮汐作用影响,两者沉积物中磷的分布比较均匀。象山港表层沉积物中铁结合态磷含量均较低,这可能是因为养殖活动造成的水体缺氧通过潮汐活动扩散到整个港底。象山港废弃养殖场沉积物中的碎屑磷和残余有机磷含量显著低于非养殖区,可能是由于养殖活动累积的生物沉积稀释了陆源输入的碎屑颗粒。  相似文献   

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation     

Pasquale Crea  Concetta De Stefano  Demetrio Milea  Silvio Sammartano   《Marine Chemistry》2008,112(3-4):142-148

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).  相似文献   

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常志巧  郝金明  张成军  崔建勇 《大地测量与地球动力学》2008,28(3):83-86

???GPS?????λ??????????????????????????????????????????????M??????????????μ??????????????????????????????????????????????е????????????????????????÷??????п???????????????????????????  相似文献   

旅游地快速交通优势度与旅游流强度的空间耦合分析   总被引：6，自引：2，他引：4  

郭向阳  穆学青  明庆忠  丁正山  胡美娟 《地理研究》2019,38(5):1119-1135

以典型旅游地—云南省为研究案例,以高德交通大数据、统计数据等多源数据为基础,依据“路网及站点密度+通行规模+通行功能+区位优势度+换乘便捷度”的思路,构建快速交通优势度模型;基于旅游流“规模→消费→效益→效应”的历时性维度构建旅游流强度模型;采用加权TOPSIS法对二者评价值进行测算,并运用耦合四象限模型对两者耦合类型进行划分。结果发现：① 快速交通与旅游流耦合存在显著空间差异性。昆明、红河和丽江呈现良性耦合协调,耦合类型表现为“高旅游流-高快速交通优势”,而旅游化水平低、远离交通枢纽和主要交通干线的边缘地区,旅游流与快速交通耦合效应则表现为“低旅游流-低快速交通优势”。② 快速交通优势度与旅游流强度呈正相关关系,不同快速交通方式与旅游流强度的拟合优度表现为“航空运输>高速公路>高速铁路”的特征。③ 云南省快速交通优势度与旅游流强度耦合水平总体偏低,快速交通发展的主导模式为协调互补模式,且缘于快速交通的“时间-空间收敛”效应和“组织-空间协同”效应,快速交通组合类型多样化与旅游流强度存在正相关关系。不同快速交通发展模式对旅游流强度的贡献效应表现出“多元共生模式>协调互补模式>单类孤立模式>低速交通维持模式”的特征。  相似文献   

春季季风间期赤道东印度洋浮游植物光合生理特征     

袁超  徐宗军  张学雷  韦钦胜  王辉武  王宗灵 《海洋学报(英文版)》2019,38(6):83-91

Phytoplankton physiologies are dynamic and have sensitive responses to the ambient environment. In this paper,we examine photosynthetic physiologies of phytoplankton communities with Phyto-PAM in the eastern equatorial Indian Ocean during the spring inter-monsoon. Environmental parameters were measured to investigate the coupling between phytoplankton photosynthetic physiologies and their habitats. During the cruise, the water column was highly stratified. The mixed layer extended to about 75 m and was characterized by high temperature(28°C) and low nutrient level. The F_v/F_m values and chlorophyll a(Chl a) concentrations were lower at the surface, as consequences of nutrient depletion and photo-inhibition. Subsurface Chl a maximum(SCM) occurred between 75 and 100 m, and had the highest F_v/F_m values. The formation of SCM was a balance between nutrient availability and light limitation. The SCM may contribute significantly to pelagic food web and primary production in the water column. Phytoplankton in different layers encountered different light, trophic and hydrographic dynamics and evolved distinct photosynthetic characteristics. Despite of co-limitation of nutrient limitation and photo-inhibition, phytoplankton in the surface layer showed their acclimation to high irradiance, had lower light utilization efficiencies(α: 0.061±0.032) and could exploit a wide range of light irradiance. Whereas, phytoplankton in the SCM layers presented the highest light utilization efficiencies(α:0.146±0.48), which guaranteed higher photosynthetic capacities under low light level. These results provide insights into phytoplankton photo-adaption strategies in this less explored region.  相似文献   

Migration and speciation transformation mechanisms of mercury in undercurrent zones of the Tongguan gold mining area,Shaanxi Loess Plateau and impact on the environment     

Rui-ping Liu  You-ning Xu  Hui-chao Rui  El-Wardany RM  Ying Dong 《China Geology》2021,4(2):311-328

In order to study the migration and transformation mechanism of Hg content and occurrence form in subsurface flow zone of gold mining area in Loess Plateau and its influence on water environment, the field in-situ infiltration test and laboratory test were carried out in three typical sections of river-side loess, alluvial and proluvial strata in Tongguan gold mining area of Shaanxi Province, and the following results were obtained: (1) The source of Hg in subsurface flow zone is mainly caused by mineral processing activities; (2) the subsurface flow zone in the study area is in alkaline environment, and the residual state, iron and manganese oxidation state, strong organic state and humic acid state of mercury in loess are equally divided in dry and oxidizing environment; mercury in river alluvial or diluvial strata is mainly concentrated in silt, tailings and clayey silt soil layer, and mercury has certain stability, and the form of mercury in loess is easier to transform than the other two media; (3) under the flooding condition, most of mercury is trapped in the silt layer in the undercurrent zone where the sand and silt layers alternate with each other and the river water and groundwater are disjointed, and the migration capacity of mercury is far less than that of loess layer and alluvial layer with close hydraulic connection; (4) infiltration at the flood level accelerates the migration of pollutants to the ground; (5) the soil in the undercurrent zone is overloaded and has seriously exceeded the standard. Although the groundwater monitoring results are safe this time, relevant enterprises or departments should continue to pay attention to improving the gold extraction process, especially vigorously rectify the small workshops for illegal gold extraction and the substandard discharge of the three wastes, and intensify efforts to solve the geological environmental problems of mines left over from history. At present, the occurrence form of mercury in the undercurrent zone is relatively stable, but the water and soil layers have been polluted. The risk of disjointed groundwater pollution can not be ignored while giving priority to the treatment of loess and river alluvial landform areas with close hydraulic links. The research results will provide a scientific basis for water conservancy departments to groundwater prevention and control in water-deficient areas of the Loess Plateau.  相似文献