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71.
An ion chromatographic method with a valve switching facility was developed to determine trace nitrate concentrations in seawater using two pumps, two different suppressors, and two columns. A carbohydrate membrane desalter was used to reduce the high concentrations of sodium salts in samples. In this method, trace nitrate was eluted from the concentrator column to the analytical columns, while the matrix flowed to waste. Neither chemical pre-treatment nor sample dilution was required. In the optimized separation conditions, the method showed good linearity (R〉0,99) in the 0.05 and 50 mg/L concentration range, and satisfactory repeatability (RSD〈5%, n=6). The limit of detection for nitrate was 0.02 mg/L. Results showed that the valve switching system was suitable and practical for the determination of trace nitrate in seawater. 相似文献
72.
A pyrethroid insecticide-degrading bacterium, strain HS-24, was isolated from an offshore seawater environment. The strain, which can degrade cypermethrin(CYP) and deltamethrin(DEL), was identified as Methylophaga sp. The optimal culture and degradation conditions for CYP and DEL by strain HS-24 is pH 7 at 28°C. Under optimum culture conditions, strain HS-24 exhibited a broad degradation concentration range of 100, 200, 400, 600, and 800 mg/L for CYP and DEL. The metabolic intermediates were analyzed by NMR, which provided strong evidence that CYP and DEL removal occurred mainly because of a biological process. The toxicity of the degradation products of strain HS-24 was studied simultaneously by measuring the light output of the luminescence bacterium. This demonstrated that the biodegradation ability of strain HS-24 significantly decreased the toxicity of CYP- and DEL-contaminated aquaculture seawater. Finally, the findings of this paper indicate that strain HS-24 is thus revealed as a biological agent for the remediation of marine aquatic environments. 相似文献
73.
基于指标规范值的海水水质评价的SVR模型 总被引:1,自引:0,他引:1
为了建立具有普适通用的海水水质评价的支持向量机模型,在设置各指标参照值和指标规范变换式,并对指标进行规范变换的基础上,应用免疫进化优化算法,建立基于指标规范值的海水水质评价的回归支持向量机模型。将优化好的模型用于珠江口海水水质的评价,其评价结果与BP神经网络的评价结果基本一致,从而表明基于指标规范值的支持向量机模型用于海水水质评价是可行的,且该模型较传统的支持向量机评价模型具有较好的普适性和通用性。 相似文献
74.
Water sensitivity phenomenon occurs during saline aquifer freshening process in seawater intrusion area, and clay particles released in the phenomenon can damage the infiltration capacity of the aquifer. In order to find out the factors and mechanisms for clay particle release, laboratory column infiltration experiments simulating saline aquifer freshening process were designed to measure the critical conditions(critical flow velocity, critical salt concentration and critical ionic strength) and force analysis for clay particle according to DLVO electric double layer theory was employed to illustrate the mechanisms for particle release. The research results showed that critical flow velocity for clay particle release is influenced by salt concentration of injecting solution. When salt concentration of injecting solution is very high, clay particles are not released, indicating that there does not exist a critical flow velocity in this situation. As salt concentration of injecting solution decreases, particles start to be released. The critical salt concentration for clay particle release is 0.052 mol L-1 in our work, which was determined by a constant-flux experiment for stepwise displacement of high concentration Na Cl solution. The critical ionic strength for clay particle release decreases as Ca2+ molar content percentage of the mixed solution of Na Cl and Ca Cl2 increases following the first-order exponential decay equation y = 0.0391e-0.266 x + 0.0015. 相似文献
75.
Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%. 相似文献
76.
针对均匀水体假设的海水透明度经验计算公式不具有普适性的缺点,将海水在垂直方向上分为若干光学性质相近的均匀层,推导出非均匀水体中目标对比度传输方程,在此基础上,建立了海水透明度的计算模型。利用BROKE_WEST_ACS实测的海水固有光学性质数据和透明度盘观测数据,对计算模型进行了数值试验和效果分析。结果表明:模型计算值与透明度盘实测值平均相对误差为9.1%;该模型既克服了透明度盘测量易受天气状况和人眼差异影响较大的缺点,又突破了均匀水体透明度计算方法的局限性。 相似文献
77.
Philippe Besson Jefferson Degboe Benjamin Berge Valérie Chavagnac Sébastien Fabre Gilles Berger 《Geostandards and Geoanalytical Research》2014,38(3):355-362
We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q® water. We obtained an average reference value rK (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg?1)/(g kg?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to rNa, rCa and rMg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids. 相似文献
78.
79.
This study is aimed to understand the hydraulic mechanism of coastal aquifer systems that include highly permeable layers (HPLs). These hydrologic conditions can be found in many volcanic islands that are composed of a series of lava flows discharged into sea or other standing body of water. In the first part, we developed a numerical model based on the geologic and hydrologic data obtained from the eastern Jeju Island, Korea, of which the aquifer contains clinker and hyaloclastite layers. The simulation results reproduced spatial location of fresh‐saline water interface, especially the abrupt decline of interface at the inland part and the thickness variation of transition zone along the cross‐section observed at the eastern Jeju coastal aquifer. We were able to find out that these phenomena are strongly related to the presence of the HPL. In the second part, quantitative analyses were conducted with the use of hypothetical models in order to understand the dynamic characteristics of coastal system that includes HPLs. A series of sensitivity studies were conducted to assess the effect of the horizontal length and vertical depth of HPL on the spatial location of the interface toe and the configuration of transition zone. Various case studies have shown that the seawater intruded into the inland more as the horizontal length of HPL was increased and its vertical depth was decreased. In other simulations including two HPLs, the vertical distance between these two HPLs primarily controlled the flow regime, flux variations, and the configuration of the transition zone. Finally, we performed simulations to evaluate the effect of a rising sea‐level. This study provides more understanding of how the presence of HPL controls the seawater intrusion processes, and the spatial configurations of fresh‐saline water interface at coastal aquifers. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
80.