Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

Preparation and Measurement of Cassiterite for Sn Isotope Analysis          下载免费PDF全文

Ryan Mathur  Wayne Powell  Andrea Mason  Linda Godfrey  Junming Yao  Mark E. Baker 《Geostandards and Geoanalytical Research》2017,41(4):701-707

Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO₂, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis.  相似文献   

特超稠油油藏水平井蒸汽驱油物理模拟实验     

郑贺梅  刘鹏程  郑舰 《现代地质》2015,29(6):1467-1474

以胜利油田A区块特超稠油油藏为目标区块,自主研发了高温高压二维比例物理模型,研究了不同开发阶段水平井蒸汽驱油机理,开展了油藏压力、井底干 度、注汽强度对水平井蒸汽驱的效果影响的研究。物模实验结果显示,蒸汽驱整个过程分为三个阶段：存水回采期、汽驱受效期、蒸汽突破期。存水回采期蒸汽腔向水平方向扩展,以水平驱替方式为主 ;汽驱受效期蒸汽腔向垂向和水平方向扩展,以水平驱替方式为主,纵向泄油为辅;后期蒸汽突破,蒸汽腔继续向上方扩展,以纵向泄油为主,实现油层整体动用。5 MPa时转蒸汽驱的采出程度高于7 MPa时转蒸汽驱的采出程度;蒸汽驱的井底蒸汽干度应不低于0.4,蒸汽干度越高,水平井蒸汽驱的开发效果越好;注汽强度为1.9 t/(d·ha·m)时温度场最为发育。同时,在高压下提高干度可实现水 平井蒸汽驱的有效开发。以上的实验结果较好地指导了胜利油田A区块特超稠油油藏水平井蒸汽驱开发,取得了明显的开发效果,该研究对于类似稠油和超稠油油藏水平井蒸汽驱开发具有重要的指导意义 。  相似文献   

海水中溶解态铵盐氮同位素分析的预处理方法     

刘丽丽  于海燕  俞志明  宋秀贤  曹西华  袁涌铨 《海洋科学》2013,37(12):28-33

以蒸馏法为基础, 研究了适合海水中铵盐稳定氮同位素分析的预处理方法。对蒸馏法预处理过程中的最佳蒸馏时间、沸石的选取、铵盐最适浓度范围等分别进行改进和优化, 获得稳定、高效的海水中铵盐氮稳定同位素分析预处理方法。结果表明: 最佳蒸馏时间为50 min, 铵盐的回收率为(97±5.8)%。测定了不同沸石对不同浓度氨氮的吸附率, 筛选出酸性条件下铵氮吸附效率较高且稳定的康华科技沸石; 确定铵盐的最佳适用浓度范围为2～10 μmol/L, 在该浓度范围内氮回收率94%～99%,氮分馏系数为0.1‰～0.8‰。将此方法应用于长江口海域水样分析, 结果表明, 这一方法可以应用于河口中铵盐的氮同位素分析, 能够为河口中溶解态氮的来源及循环机理等研究提供有效信息。  相似文献   

重庆地区岩溶地下河水溶解无机碳及其稳定同位素特征   总被引：6，自引：3，他引：3  

蒲俊兵 《中国岩溶》2013,32(2):123-132

稳定碳同位素是指示岩溶动力系统碳来源及转化的重要指标。为揭示重庆地区岩溶地下水中溶解无机碳基本特征和碳来源,本文对该地区63条岩溶地下河水样进行了水化学和碳同位素分析。研究结果表明,重庆地区地下河水溶解无机碳主要表现形式为HCO3-,雨季由于稀释作用其浓度低于旱季。重庆岩溶地下河水δ13C-DIC（V-PDB）旱季变化范围为-15.34 ‰～-5.89 ‰,雨季变化范围为-17.40 ‰～-4.23 ‰。根据δ13C同位素质量平衡方法,计算得到重庆地下河旱季碳酸盐岩溶蚀对DIC贡献为45.1 % ～79.7 %,雨季平均为34.6 %～82.1 % 。计算结果表明,在人类活动不断增强的情况下,岩溶水体DIC通量中碳酸盐岩溶解来源的DIC和其参与岩溶地下水δ13C值的形成并不一定是岩溶作用理论方程中所计算的50 %,而是有一定的变化范围。因此在计算岩溶作用碳汇时,建议通过δ13C值扣除碳酸盐岩溶蚀形成DIC的通量后再来推算岩溶作用形成的碳汇量。   相似文献   

Heat calculation and numerical simulation in steam mining of permafrost gas hydrate     

LI Bing  SUN Youhong  GUO Wei  LI Kuan 《世界地质(英文版)》2012,15(2):135-139

Steam mining method was injecting hot steam into the borehole to heat the hydrate strata at the same time of depressurization mining,which could promote further decomposition and expand mining areas of gas hydrate. Steam heat calculation would provide the basis for the design of heating device and the choice of the field test parameters. There were piping heat loss in the process of mining. The heat transfer of steam flowing in the pipe was steady,so the heat loss could be obtained easily by formula calculation. The power of stratum heating should be determined by numerical simulation for the process of heating was dynamic and the equations were usually nonlinear. The selected mining conditions were 500-millimeter mining radius,10 centigrade mining temperature and 180 centigrade steam temperature. Heat loss and best heating power,obtained by formula calculation and numerical simulation,were 21. 35 W/m and 20 kW.  相似文献   

基于循环注蒸气和烟气激励的海上稠油开采技术   总被引：1，自引：1，他引：0  

杨海林  钟立国 《东北石油大学学报》2013,(1):78-84,96,9,10

通过实验和油藏数值模拟,研究循环注蒸气和烟气激励的加热降黏、气体溶解降黏、气体扩大加热腔与减少热损失、蒸气与气体协同增产效应等开采机理,优化注入蒸气和烟气温度、烟气蒸气体积比、周期蒸气和气体注入量等参数,建议注入蒸气与烟气的温度高于300℃,在大气压下烟气蒸气体积比为0.4～0.6.在渤海稠油油田开展4口井循环注蒸气和烟气激励开采的现场试验.结果表明,循环注蒸气和烟气激励开采后稠油井平均日产油量达到冷采的3倍以上,最高日产油量超过100m3,周期产油量达到1.0×104 m3左右.基于循环注蒸气和烟气激励的海上开采稠油技术可以提高海上稠油开采速度和采收率,有潜力成为未来海上稠油油田的主要热采开发方式.  相似文献   

膜蒸馏处理乳化油废水的实验研究     

王斯佳  蔡蕊  孙求实  袁文真  吕颖 《世界地质》2009,28(2):261-264

采用自制的中空纤维膜蒸馏组件对模拟的乳化油废水进行膜蒸馏处理研究, 分析了料液的浓度、流速、温度和处理时间等因素对膜通量及去除率的影响。实验结果表明: 在料液温度为50℃、流速为14 mL /min、乳化油浓度为500 mg/L 的条件下, 运行1 h后乳化油膜通量为21.20 g/m2 ·h, 去除率> 70%; 运行5 h后膜通量下降为5.141 g/m2 ·h, 去除率> 90%。  相似文献   

膜蒸馏处理糠醛废水的实验研究   总被引：2，自引：1，他引：1  

张凤君  李卿  马玖彤  于广菊 《吉林大学学报(地球科学版)》2006,36(2):270-273

采用中空纤维膜蒸馏技术研究了糠醛废水的膜蒸馏处理效果,考察了料液相的温度、醋酸浓度、流速、吸收液浓度等因素对处理效果的影响。结果表明：在温差为15℃、料液的浓度为0.306 mol/mL时,速度为8 mL/min;吸收液的质量浓度为25 g/L时,速度为3 mL/min。运行12 h后,料液的pH值由开始的1.9升高为5.1,醋酸的去除率为76.3％,糠醛的去除率为40.1％。此过程可降低料液中糠醛和醋酸的含量,减小了低分子量有机酸对微生物危害的影响,为后续生物处理奠定了基础。  相似文献   

HD-1注汽井新型防砂材料的研究与应用     

沈朝霞  梁富春  高成元  刁俊西  孙理达 《海洋地质译丛》2010,(3):61-63

孤岛油田属稠油疏松砂岩油藏,生产过程中油井出砂严重,现有的涂敷砂人工井壁防砂注蒸汽后强度较低,造成防砂成功率低,注汽后高强度采液生产周期较短。为此,通过室内试验,优选出耐高温树脂、高强度骨架颗粒、偶联剂、固化剂,进行室内配方优化试验,评价固结体耐高温性能,测定其渗透率,研制出一种适用于疏松砂岩油藏注蒸汽热采井的HD-1注汽井新型防砂材料。在孤岛油田稠油注蒸汽热采区共试验72口井,成功率为91.0%,截止目前,累计产油为121 572 t,单井平均有效期为233 d。现场应用表明：HD-1注汽井新型防砂材料耐高温、强度高,防砂成功率高,有效期长,能够有效改善注蒸汽热采井的防砂效果。  相似文献