太湖流域降雨和湖水酸根阴离子长期变化及其环境意义     

赵健  代丹  王瑞  郝晨林  何成达  于涛 《湖泊科学》2019,31(1):88-98

为揭示太湖流域降雨和湖水酸根阴离子长期变化特征及环境意义,通过历史数据收集和采样分析,对太湖流域降雨和湖水中的SO₄^2-、NO₃^-变化特征和来源进行了研究.结果表明：自1990s以来太湖流域降雨中SO₄^2-呈显著下降趋势,年平均下降率为0.28 mg/（L·a）;NO₃^-浓度却呈显著上升趋势,年平均增长率为0.05 mg/（L·a）,降雨中氮污染呈现加重的趋势.与之相反,湖水中SO₄^2-呈显著上升趋势,年平均增长率为1.24 mg/（L·a）;NO₃^-浓度却呈显著下降趋势,年平均下降率为0.02 mg/（L·a）.30年以来,太湖水体SO₄^2-/NO₃^-比值不断升高,远高于降水SO₄^2-/NO₃^-比值.研究认为：流域SO₂排放引起的酸沉降是湖水SO₄^2-浓度增长的最重要原因,但氮氧化物排放并未引起湖水NO₃^-浓度升高,说明太湖流域对大气沉降的氮氧化物有滞留作用,而太湖水体是流域大气沉降硫酸盐的重要汇.综合治理太湖流域酸性物质排放对防止太湖水体酸化和治理富营养化都具有重要意义.  相似文献   

Geochemical correlations between effusive and explosive silicic volcanics in the Saraykent region (Yozgat), central Anatolia,Turkey     

Gonca Genaliolu‐Kucu  Peter A. Floyd 《Geological Journal》2002,37(2):143-165

Two main volcanic events are distinguished between Saraykent and Akçakışla in the Yozgat province of central Anatolia: (1) early Late Cretaceous–Palaeocene effusive activity, that produced a sequence of intermediate to felsic ‘basal lavas’; and (2) marginally later Palaeocene explosive activity that formed a series of covering ignimbrite flows. Due to their close temporal and spatial relation, geochemical comparisons were made between the silicic members of the lavas and ignimbrites, to identify chemical groups and their relative petrogenesis. The basal lavas range from calc‐alkaline basaltic andesites to dominant rhyolites. Based on trace element correlations three main geochemical groups were identified: the Akçakışla rhyolites (present as domes); Akçakışla rhyodacites‐dacites (lava flows); and Ozan‐Saraykent rhyolites (lava flows). Large‐ion lithophile elements have been mobile in all the groups, but mainly in the Akçakışla rhyolites. Rare earth element (REE) patterns show marked similarity between the Ozan and Saraykent basal lavas. The Akçakışla dome rhyolites are more fractionated with lower La_N/Yb_N ratios (c.10), whereas the Akçakışla basal lavas have much higher La_N/Yb_N ratios (c.30). The chemical coherence and petrographic similarities between the Saraykent and Ozan lavas suggest a single suite related via fractionation. Three geochemical groups were also established for the ignimbrites: Saraykent ignimbrite; Bağlıca ignimbrite‐Toklu‐Kızıldağ crystal tuffs; and Keklikpınar ignimbrite. The ignimbrites, like the basal lavas, display a pronounced depletion in Ba on ORG‐normalized plots. Relative to the basal lavas, chondrite‐normalized patterns for the ignimbrites are different in displaying negative Eu anomalies that indicate feldspar fractionation. The lack of geochemical overlap or coherence between any of the lava and ignimbrite groups suggests that they represent distinct eruptive events and are not related in any simple volcanic development and cogenetic sense. Two geochemical features are common to all the volcanic rock groups: (1) the presence of a Nb‐Ta anomaly, which is generally accepted as a crustal signature; and (2) the relatively low Y abundances which appear characteristic for the region as a whole. These fundamental features of the local silicic volcanism largely reflect source composition and effects. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

富硫型水库沉积物AVS和SEM空间分布特征及重金属风险评价     

关昊鹏  谢筱婷  陈思睿  邓莎  陈小强  金业  林琳  汪天祥  许士国 《湖泊科学》2024,36(2):452-466

随着湖库外源性污染的有效控制,沉积物污染特征成为影响湖库水环境质量的关键因素。本文以富硫型水库——汤河水库为研究对象,分析探讨水库沉积物的理化性质、重金属总量、酸可挥发性硫化物(acid volatile sulfide,AVS)和同步提取重金属(simultaneously extracted metals,SEM)的空间分布特征,采用沉积物基准法(sediment quality guidelines, SQGs)和AVS与SEM关系法对重金属可能诱发的生态风险和毒性效应进行评估。结果表明:汤河水库沉积物中AVS含量在0.03~51.75 μmol/g之间,并呈现坝前深水区>东支流库区>西支流库区的空间分布特征。根据Pearson相关性分析可知,汤河水库沉积物AVS含量与间隙水中SO₄^2-浓度、沉积物烧失量(LOI)含量呈显著正相关,与沉积物间隙水中NO₃^-浓度和沉积物pH呈现显著负相关。间隙水中SO₄^2-浓度和沉积物LOI含量是控制AVS产量的重要因素。水库沉积物中ΣSEM变化范围为0.52~2.75 μmol/g,呈现出东支流库区>坝前深水区>西支流库区的分布规律。水库沉积物中ΣSEM/AVS和ΣSEM-AVS的变化范围分别为0.06~22.73和-49.18~2.44 μmol/g,显示出水库坝前深水区表层0~10 cm沉积物不具有生态风险,而东、西支流库区沉积物中的SEM因为不能完全被AVS所固定而存在潜在生态风险。就单一重金属而言,汤河水库坝前深水区和东西支流中部区域沉积物Ni、Cu、Pb和Zn含量均介于临界效应含量(threshold effects level, TEL)值和可能效应含量(probable effect level, PEL)值之间,可产生低级风险毒性效应,但Ni的毒性效应风险接近中级,今后应予以重点关注。富硫型水库沉积物中容易出现高含量AVS,沉积物间隙水中SO₄^2-和NO₃^-的浓度是决定沉积物AVS净产量的重要因素。流域内重金属土壤背景值以及工业、采矿产业排放的废水类型直接影响着诱发生态风险的重金属种类。  相似文献   

西藏中冈底斯扎布耶茶卡北部晚侏罗世则弄群火山岩的锆石U-Pb年代学及其成因意义   总被引：1，自引：0，他引：1       下载免费PDF全文

叶春林  黄柏鑫  王燚  侯云岭  贾小川  杨学俊  王国光  吕志伟 《高校地质学报》2018,24(4):525

冈底斯带晚中生代构造演化模式一直存在争议。此次研究了中冈底斯带扎布耶茶卡北部区域则弄群火山岩的野外特 征和锆石U-Pb年龄。锆石U-Pb定年结果表明,扎布耶茶卡北部则弄群火山岩主要喷发于154.2~142.1 Ma。研究首次获得 晚侏罗世的则弄群火山岩年龄为154 Ma,比前人提出的则弄群火山岩浆活动起始时间（130 Ma） 提前了24 Ma,据此将则 弄群的时代定为晚侏罗世至早白垩世。根据研究获得的最新年代学数据,结合冈底斯带火山岩的前人研究资料,显示冈底 斯带中生代弧火山岩具有从南向北逐渐年轻的趋势。因此,最早期南冈底斯弧中生代火山岩可能与新特提斯洋板片北向俯 冲有关,晚侏罗世至早白垩世的中冈底斯带弧火山岩受到了新特提斯洋板片北向俯冲和班公湖-怒江洋板片南向俯冲的双 重影响,早白垩世中期的北冈底斯带弧火山岩则与班公湖-怒江洋板片的南向俯冲密切相关。研究成果为冈底斯带晚中生 代构造演化模式提供了火山岩方面的新证据。  相似文献   

三塘湖盆地航磁异常特征及油气远景预测     

舒晴  朱晓颖  高维  李瑞  尹航 《吉林大学学报(地球科学版)》2018,48(2):451-460

三塘湖盆地是我国西部典型的火山岩油气盆地。本文基于1：5万高精度航磁资料,结合区域地质、区域重力、地面踏勘和物性资料,对三塘湖盆地进行了航磁综合解释;详细分析了磁场和重力场特征及其与区域构造的对应关系,圈定了盆地火山岩分布范围,采用欧拉反褶积方法计算了磁性体埋深,初步揭示了盆地磁性基底起伏情况;结合盆地火山岩油气成藏模式,开展了航磁油气远景预测。结果表明,三塘湖盆地中央坳陷内有隐伏火山岩存在的次级凹陷中心具有寻找火山岩油藏的良好前景：汉水泉凹陷区中的2个次级凹陷中心、条湖凹陷区北段次级凹陷中心应作为油气勘探重点区域;石头梅凸起和岔哈泉凸起区可作为重要油气勘探方向;方方梁凸起及其以南区域可作为下一步油气勘探工作的预研区。研究结果可为盆地油气资源后续勘探开发提供指导。  相似文献   

Evidences for Incipient Hydrothermal Event(s) in the Central Indian Basin: A Review     

Sridhar D. IYER 《《地质学报》英文版》2005,79(1):77-86

1 IntroductionMetalliferous sediments and mounds occur in all majortectonic settings in the oceans (e.g., the Galapagos Rift,East Pacific Rise (EPR), Bauer Deep and Central Basin ofthe Pacific; Heath and Dymond, 1977). Further, massivesulphide deposits and high-temperature vents have beenreported along the mid-ocean ridges (MOR). In the IndianOcean, an inactive hydrothermal field and a hydrothermalplume site have been discovered along the Central IndianRidge (CIR). The SONNE Hydro…  相似文献   

Geochemical distribution and removal of As,Fe, Mn and Al in a surface water system affected by acid mine drainage at a coalfield in Southwestern China   总被引：5，自引：0，他引：5  

Pan Wu  Changyuan Tang  Congqiang Liu  Lijun Zhu  TingQuan Pei  Lijuan Feng 《Environmental Geology》2009,57(7):1457-1467

The chemical characteristics, formation and natural attenuation of pollutants in the coal acid mine drainage (AMD) at Xingren coalfield, Southwest China, are discussed in this paper based on the results of a geochemical investigation as well as geological and hydrogeological background information. The chemical composition of the AMD is controlled by the dissolution of sulfide minerals in the coal seam, the initial composition of the groundwater and the water–rock interaction. The AMD is characterized by high sulfate concentrations, high levels of dissolved metals (Fe, Al, Mn, etc.) and low pH values. Ca²⁺ and SO₄ ²⁻ are the dominant cation and anion in the AMD, respectively, while Ca²⁺ and HCO₃ ⁻ are present at significant levels in background water and surface water after the drainage leaves the mine site. The pH and alkalinity increase asymptotically with the distance along the flow path, while concentrations of sulfate, ferrous iron, aluminum and manganese are typically controlled by the deposition of secondary minerals. Low concentrations of As and other pollutants in the surface waters of the Xingren coalfield could be due to relatively low quantities being released from coal seams, to adsorption and coprecipitation on secondary minerals in stream sediments, and to dilution by unpolluted surface recharge. Although As is not the most serious water quality problem in the Xingren region at present, it is still a potential environmental problem. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Geochemical characterization of karst groundwater in the cradle of humankind world heritage site,South Africa   总被引：1，自引：0，他引：1  

M. Holland  K. T. Witthüser 《Environmental Geology》2009,57(3):513-524

The karst of the Cradle of Humankind World Heritage Site plays a major role in the assimilation or carrying of acid mine drainage, sewage effluent return flow and agricultural run-off. Infiltration of contaminated water has altered the chemical composition of the natural waters of the karst system. A multivariate statistical method in combination with conventional geochemical and spatial analysis was applied on groundwater and surface water quality samples to determine the spatial extent of hydrochemical impacts from different anthropogenic sources. The application of hierarchical cluster analysis of the major ions (148 samples) recognised three distinct hydrochemical regimes. Cluster 1 is moderately mineralized, especially with regard to chloride, nitrate and sulphate, cluster 2 has a low mineralization with all elements well within the recommended drinking water limits of South Africa and cluster 3 represents highly mineralized samples taken in the vicinity of decanting mineshafts. The cluster solution is confirmed by a simple mixing model, indicating varying contributions of three identified end members (acid mine drainage, treated sewage effluents and pristine dolomitic groundwater) to the groundwater quality in the catchment. The combination of statistical, geochemical and spatial methods in conjunction with end-member mixing analysis provides a reliable method to understand the processes responsible for the groundwater quality variations and to assist in the identification of anthropogenic impacts.  相似文献   

基于脂肪酸标记的长江口海区浮游动物常见种食性分析   总被引：5，自引：0，他引：5  

金鑫  李超伦  孙松  刘梦坛 《海洋与湖沼》2012,43(6):1083-1090

脂肪酸不仅是浮游动物的重要组分,也被作为生物标记来指示动物的食物组成及其之间的营养关系。本文运用脂肪酸标记法对长江口附近海区6个浮游动物常见种的食性进行了分析。研究结果表明,中华哲水蚤(Calanus sinicus)雌体和桡足幼体都表现出明显的植食性。但雌体中16:1ω7的含量要明显高于18:4ω3,表明雌体对硅藻的摄食较多;桡足幼体的18:4ω3要高于雌体,说明桡足幼体对甲藻的摄食较多。磷虾(Euphausia spp.)的多不饱和脂肪酸(PUFA)和ω3系列脂肪酸的含量很高,说明其作为饵料可以给摄食者提供较多的脂类营养物质。中华哲水蚤和磷虾较低的22:6ω3/20:5ω3比值说明他们的营养地位较低。箭虫(Sagitta spp.)的20:1和22:1脂肪酸含量很高,指示了其对植食性桡足类的摄食。蝶水母(Ocyropsis crystallina)、瓜水母(Bero cucumis)和四叶小舌水母(Liriopetetraphylla)的20:1+22:1脂肪酸所占比例较高,指示了其对植食性桡足类的摄食,但是水母类的总脂肪酸含量都很低。几种水母和箭虫的22:6ω3的含量要明显高于20:5ω3的含量,说明它们在浮游食物网中具有较高的营养地位。  相似文献   

Landscape-scale patterns of sediment sulfur accumulation in Swedish lakes     

Richard Bindler  Maria Wik-Persson  Ingemar Renberg 《Journal of Paleolimnology》2008,39(1):61-70

Sulfur has played a central role in the acidification of many lakes in Scandinavia and other regions. As part of the research into sulfur cycling, numerous studies have analyzed the sediment record in order to develop insights into past in-lake cycling of sulfur, particularly in the context of reconstructing past deposition rates. Although many of these studies have shown that it is not easy to interpret the sediment record in terms of past sulfur deposition rates, analyses of sulfur in sediment still provide valuable information on the response of lakes to anthropogenic sulfur deposition. Here, we have analyzed sulfur in top and bottom samples from short surface cores (25–35 cm, representing ≥250 years) as well as bulk cores from ∼110 lakes located throughout Sweden, which were collected during 1986, as well as in more-detailed profiles from six lakes. The lakes with the highest surface sediment concentrations (9–24 mg S g⁻¹ dry mass) and the highest calculated inventories of ‘excess’ sulfur (20–180 g S m⁻²) are found in southern Sweden and around one industrial area along the northeastern coast where sulfur deposition rates and lake-water concentrations have been highest. For many lakes in the central and northern inland region it is common that the sediment cores exhibit either no enrichment or even a decline in sulfur concentrations in near-surface sediments, which we suggest was the pre-pollution norm for lakes. Although interpreting sulfur sediment profiles is problematic for reconstructing deposition, a more-comprehensive spatial sampling approach shows that there is a good geographic agreement between sulfur deposition, lake-water chemistry and sediment sulfur accumulation.  相似文献