三元体系K^＋，Mg^2＋／B4O7^2- -H2O25℃相关系研究   总被引：3，自引：0，他引：3       下载免费PDF全文

靳治良  孙柏李刚　李武 《盐湖研究》2004,12(2):19-22

对三元体系K+,Mg2+/B4O2-7-H2O 25℃的溶解度进行了研究,该体系属简单共饱型,两段溶解度曲线对应于体系的两种原始组分K2B4O7·4H2O、MgB4O7·9H2O的结晶区,共饱点组成为K2B4O7 13.96%,MgB4O7 0.53%.  相似文献   

Na~ /Cl~-,B_4O_7~(2-)-H_2O体系在28℃与35℃时介稳相平衡研究   总被引：2，自引：0，他引：2       下载免费PDF全文

孟令宗  邓天龙  孙柏 《盐湖研究》2007,15(1):34-38

采用等温蒸发法研究了Na+/Cl-,B4O2-7-H2O体系28 ℃与35 ℃介稳相平衡及溶液的物化性质(密度、折光率),绘制了相应的介稳相图.该介稳体系属简单共饱和型,相图由两条溶解度曲线构成,分别对应于Na2B4O7·10H2O和NaCl相区.用经验公式计算了该体系在相应温度下的密度、折光率,与实验测定结果吻合较好.  相似文献   

Boron Isotopic Composition of Freshwater Lakes from Central Europe and Possible Contamination Sources     

A. Vengosh  S. Barth  K. G. Heumann  S. Eisenhut 《洁净——土壤、空气、水》1999,27(6):416-421

The boron isotopic compositions of common synthetic boron products, municipal wastewaters from Switzerland, and three Swiss freshwater lakes were investigated. The δ11B values (δ11B values are normalized to the standard NIST SRM-951) of synthetic Na-borates (–0.4 to 7.6‰) and Ca-Na-borates (–13.4 to –4.9‰) overlap with those of natural borate minerals and hence suggest that the isotopic signal of anthropogenic boron is not modified during the manufacturing process. As a result it is possible to predict the isotopic composition of synthetic boron products and their potential impact upon contamination of water resources. The δ11B values of municipal wastewaters from two locations in northern Switzerland (–7.7 to –4.5‰) reflect utilization of Na/Ca- and/or Ca-borates depleted in 11B. Freshwater lakes from Switzerland (Lake Zürich, Greifensee, Lake Lugano) yielded a δ11B range of –1.7 to 7.1‰ and boron concentrations of 17 to 102 mg L–1. The boron isotopic ratios decrease with increasing boron concentrations, indicating mixing between anthropogenic boron with a low δ11B signature and meteoric boron with a heavier isotopic signal. We suggest that the isotopic composition of meteoric boron over central Europe has δ11B values in the range of ca. 10 to 20‰, whereas in coastal areas the marine component is larger with a higher 11B/10B ratio (δ11B ∼ 30‰).  相似文献   

干旱区粉尘对古里雅冰帽中化学记录的影响   总被引：8，自引：0，他引：8  

李月芳  姚檀栋  盛文坤  皇翠兰 《海洋地质与第四纪地质》1999,19(2):103-108

从雪冰样品中的阳离子（Ｃａ２＋、Ｎａ＋、Ｍｇ２＋和Ｋ＋）、阴离子（Ｃｌ－、ＳＯ４２－和ＮＯ３－）、ｐＨ值、电导率等几个方面分析了干旱区粉尘对古里雅冰帽中化学记录的影响特点。研究表明,干旱区粉尘对该冰帽的影响使得离子的浓度高于极地冰川中相应离子的浓度,离子之间的浓度大小顺序明显地不同于极地冰川。钻取样品中离子存在明显的空间变化趋势,反映了近源粉尘对冰帽中化学记录的影响;最新一次降水中离子没有明显的空间变化趋势,反映了远源粉尘对冰帽整体的均匀影响。８５％的样品的ｐＨ值大于７,部分样品的ｐＨ值大于９,归因于来自干旱区的尘埃中的易溶性弱酸盐的水解作用,电导率的主要贡献者是粉尘中的易溶盐  相似文献   

2007-2008年南京江北工业区大气降水化学特征   总被引：1，自引：0，他引：1  

高俊  郑有飞  陈书涛 《南京气象学院学报》2012,(6):697-701

2007年3月-2008年9月在南京市江北地区南京信息工程大学采集有效降水样品共48个,测量了降水的pH值和电导率,用离子色谱仪分析检测了降水样品的阴、阳离子的质量浓度。结果表明：2007年的酸雨频率为44．5％,2008年酸雨频率为59．3％,南京江北工业区降水的酸性及酸化频率都有所增高;2007-2008年大气降水与2005-2006年所测数据相比较,NO3-的质量浓度略有增长,NH4＋的质量浓度有了较大幅度的增长;研究区域SO4／NO。的实验数据表明,硫污染特征有所减弱,氮氧化物污染逐渐突出,表现出燃煤污染与汽车尾气污染并存的过渡型大气污染特征。  相似文献   

Feldspar dissolution in the presence of organic acid anions under diagenetic conditions: an experimental study     

D.A.C. Manning  K. Gestsdttir  E.I.C. Rae 《Organic Geochemistry》1992,19(4-6)

Previous experiments to determine the aqueous solubility of lead-rich orthoclase in the presence of the ethanoic acid anion (acetate) at 150°C and 50 MPa have shown that the observed fluid compositions are essentially controlled by the presence of secondary mineral precipitates, which buffer dissolved species apart from lead. Data for lead suggest that dissolution increased with increasing fluid ethanoic acid anion content, but the ethanoic acid anion was unstable under the experimental conditions. Additional experiment have now been carried out using pure natural albite and ethanoic acid anion solutions at 150°C and 50 MPa, in which the ethanoic acid anion remains stable. The results for albite again demonstrate the influence on fluid composition of secondary mineral precipitates, but data for silica allow the rates of dissolution to be estimated. Values obtained for the dissolution rate constant increase from 1.8 × 10⁻⁷ to 5.3 × 10⁻⁷ s⁻¹ with increasing fluid ethanoic acid anion content (0.1–2.5 molal) and approximate to values for quartz and orthoclase dissolution rates for similar PT conditions, reflecting similarity in the mechanisms of dissolution of the minerals' three dimensional (alumino)silicate frameworks. However, these experiments provide no other evidence that the ethanoic acid anion enhances equilibrium solubilities of feldspars or quartz. In contrast to the results for the ethanoic acid anion, data for albite dissolution experiments in the presence of the ethanedioic acid anion (oxalate) at 150°C and 50 MPa show an inhibitionn of solubility (apart from aluminium), while data for the 2-hydroxy-1,2,3-propanetricarboxylic acid trivalent anion (citrate) show considerable enhancement of solubility for aluminium and silicon, and titanium derived from the reaction vessel. The 2-hydroxy-1,2,3-propanetricarboxylic acid trivalent anion is unstable, decaying according to first order kinetics (half life = 1.5 days). In their application to problems of diagenesis in the presence of organic acid anions, these results suggest that the ethanoic acid anion may influence feldspar dissolution by accelerating diagenetic reactions, while geologically short-lived species such as the 2-hydroxy-1,2,3-propanetricarboxylic acid trivalent anion and its decay products may dramatically enhance aluminosilicate solubility.  相似文献   

硼氧酸盐水溶液化学   总被引：1，自引：0，他引：1  

李武  李军 《盐湖研究》1996,4(2):18-30

本文从硼氧酸盐水溶液中硼氧配阴离子的存在形式，盐卤硼氧酸盐化学和现代谱学方法对硼氧酸盐的研究等方面进行了综述。  相似文献   

表生作用条件下硼酸盐矿床的形成问题          下载免费PDF全文

孙大鹏  高章洪  马育华  蔡克勤  帅开业  高建华 《盐湖研究》2002,10(1):45-60

沉积硼酸盐矿床在自然界分布相当广泛 ,主要见于南、北美和我国青藏高原的盐湖中、美国和土耳其某些第三纪沉积盆地中 ,以及欧洲某些古代海相盐矿床中。为了研究其形成问题 ,从 70年代开始 ,我们利用青藏高原盐湖卤水和泉水进行了许多模拟实验工作。从 40～ 5 0个样品中获得了大量钠硼酸盐、纳钙硼酸盐、镁硼酸盐和含氯化镁的镁硼酸盐复盐。这对于阐明表生作用条件下硼酸盐矿床的形成是非常重要的。实验和研究结果证明 :1)与地热和火山活动有关的水体是硼酸盐矿床形成的物质来源 ;2 )硼酸盐矿床可形成于Ｎａ、Ｋ、Ｍｇ//Ｃｌ、ＳＯ4 ·Ｈ2 Ｏ和Ｎａ、Ｋ//Ｃｌ、ＳＯ4 、ＨＣＯ3、ＣＯ3·Ｈ2 Ｏ不同水盐平衡体系的不同富硼水体中 (盐度 :1 2 7～ 41 4% ,Ｂ2 Ｏ3含量 :0 0 5～ 2 97% ) ;3 )硼酸盐矿床通常形成于稳定平衡条件下 ,而不是介稳平衡条件下 (蒸发过程中 ) ;4)低温条件有利于硼酸盐自水体中析出 ;5 )硼酸盐矿床的形成与水体的化学类型、ｐＨ值和硼含量有密切关系 ;6)我们实验中所获的硼酸盐反映了天然硼酸盐矿床形成的原始条件。不仅揭示了大陆盐湖硼酸盐矿床的形成 ,也揭示了古代海相盐矿床硼酸盐的成因。  相似文献   

Synthesis and optical characterization of Gd-neso-borate single crystals     

《Chemie der Erde / Geochemistry》2015,75(3):317-322

  相似文献   

Combined Separation of Cu,Fe and Zn from Rock Matrices and Improved Analytical Protocols for Stable Isotope Determination   总被引：3，自引：0，他引：3       下载免费PDF全文

Paolo A. Sossi  Galen P. Halverson  Oliver Nebel  Stephen M. Eggins 《Geostandards and Geoanalytical Research》2015,39(2):129-149

Isotope ratios of heavy elements vary on the 1/10000 level in high temperature materials, providing a fingerprint of the processes behind their origin. Ensuring that the measured isotope ratio is precise and accurate depends on employing an efficient chemical purification technique and optimised analytical protocols. Exploiting the disparate speciation of Cu, Fe and Zn in HCl and HNO₃, an anion exchange chromatography procedure using AG1‐×8 (200–400 mesh) and 0.4 × 7 cm Teflon columns was developed to separate them from each other and matrix elements in felsic rocks, basalts, peridotites and meteorites. It required only one pass through the resin to produce a quantitative and pure isolate, minimising preparation time, reagent consumption and total analytical blanks. A ThermoFinnigan Neptune Plus MC‐ICP‐MS with calibrator‐sample bracketing and an external element spike was used to correct for mass bias. Nickel was the external element in Cu and Fe measurements, while Cu corrected Zn isotopes. These corrections were made assuming that the mass bias for the spike and analyte element was identical, and it is shown that this did not introduce any artificial bias. Measurement reproducibilities were ± 0.03‰, ± 0.04‰ and ± 0.06‰ (2s) for δ⁵⁷Fe, δ⁶⁵Cu and δ⁶⁶Zn, respectively.  相似文献