苯酰胺类化合物防污活性基团的初步探索     

荀靖懿  郑纪勇  程旭东  马力  张宏泉  蔺存国 《海洋科学》2022,46(5):104-114

开发绿色环保防污剂是海洋船舶防污涂料研究的重要方向,查明防污活性化合物分子结构中的防污活性基团,是设计开发新型防污剂的关键。本文合成了三种结构相似的苯酰胺类化合物HNOB、DOLPA和DHNOB,通过FTIR,1H NMR,13C NMR测试表征三种化合物的分子结构,利用典型污损生物硅藻和贻贝作为目标生物,测试其对硅藻和贻贝附着的影响,并将分子结构与防污活性进行对比,初步探讨影响防污性能的活性基团。硅藻和贻贝附着实验均表明,HNOB的防污性能较好,半数抑制浓度远低于DOLPA和DHNOB。通过结构对比分析发现,极性和非极性结构的协同作用比单一的极性基团或非极性长碳链基团能更好地赋予苯酰胺类物质良好的防污性能。该研究初步探讨了苯酰胺类化合物的构效关系,有助于新型防污活性化合物的设计开发和结构优化,并对探究该类化合物防除污损生物附着的机理和快速筛选有潜力的防污化合物具有重要意义。  相似文献   

中国城市网络关联格局的影响因素分析——基于电子信息企业网络的视角   总被引：3，自引：6，他引：3  

盛科荣  张红霞  赵超越 《地理研究》2019,38(5):1030-1044

城市网络关联格局影响因素的测度及其作用机理的解析是建立城市网络理论模型的关键环节。基于2017年中国电子信息100强企业网络视角构建城市网络,采用指数随机图模型定量测度了中国城市网络的影响因素,解析了城市网络生长发育的微观过程,并探索性的提出了理解中国城市网络发育机理的概念框架。研究发现：偏好依附效应和接收者（GDP）效应构成了中国城市网络中心性格局的微观基础,中国城市网络生长发育表现为择优选择的地理过程;互惠性链接深刻影响着城市间的关系格局,网络闭合机制逐步成为城市间链接关系的重要影响因素;空间距离对基于电子信息企业网络的城市网络约束作用并不明显,城市网络表现出在“流动空间”中生长发育的特征。  相似文献   

施工人员的成人依恋与事故倾向性的关联性研究     

刘威 《城市地质》2015,(Z2):17-21

本文通过调查问卷方式,应用事故倾向性量表(APS-CW)、亲密关系经历量表(ECR)和一般自我效能感量表(GSES),以方差分析、相关分析、回归分析为主要的统计方法,探讨施工人员的成人依恋、事故倾向性及两者的关系,表明施工人员的依恋维度高低对事故倾向性具有一定的影响。  相似文献   

Understanding Place Attachment to the County in the American Great Plains          下载免费PDF全文

Jeffrey S. Smith  Jordan M. McAlister 《Geographical review》2015,105(2):178-198

The American Great Plains is a region dominated by a flat, treeless, semiarid environment that has challenged population settlement for over 140 years. As railroad companies successfully attracted pioneers to settle the land, state governments established hundreds of counties. Following Jeffersonian ideals, many of the counties were small in area so they could better serve the local agricultural‐based population. When states established these counties, they envisioned that the population would continue to grow and the Great Plains would become the breadbasket of North America. Unfortunately that did not materialize. A succession of hardships combined with serious environmental constraints has discouraged large‐scale settlement in the region. Many counties reached their maximum population in the early 1900s and their totals have decreased ever since (in some counties by as much as 60 percent to 80 percent). This has led a number of government officials to consider consolidating counties much like school districts have been combined. Using Logan and Gove counties in western Kansas as a case study, our purpose is to understand how attached people are to the county in which they live. Employing multiple methods, we gathered information about how different segments of the population regard their local county. We learned that changing computer technology and the Internet has the biggest impact on peoples' attachment to the county seat.  相似文献   

校园网中IP盗用监控管理系统的研究与实现   总被引：1，自引：0，他引：1  

王坤  尹志本 《成都信息工程学院学报》2002,17(2):88-92

IP地址盗用是校园网管理中一个迄待解决的问题，它严重影响了合法用户的权益，影响了网络正常的运行秩序。针对IP盗用的原理，在现有的防落IP盗用方法的基础上，设计出了一有效地防落IP盗用的管理系统，它结合了网络设备的管理功能和路由隔离中的静态路由技术，通过MAC地址的端口绑定和IP－MAC地址绑定实现了对IP地址盗用的有效管理，很好解决了这一困扰网络管理员的管理问题。  相似文献   

Using grounded theory to study the difference of place attachment between festival ＆ special event venue and convention ＆ exhibition complex： Cases of venue of International Horticultural Exposition 2011 Xi＇an China and China Import and Export Fair Complex     

《地理研究》2012,31(9)

通过两个典型案例的对比,以2011西安世界园艺博览会园区和广州琶洲国际会展中心为研究区域,采用深度访谈和参与观察等手段获取研究资料,运用扎根理论分别对节事场所和会展场所的场所依赖的维度进行挖掘和提炼,归纳出个体、社会、场所和事件四个主要范畴,在此基础上比较研究节事场所和会展场馆场所依赖的差异。研究发现：观众在节事场所当中把个人视为“游憩者”,节事场所被看作是一个“游憩空间”,具有“根基性场所”的特点,观众在与节事场所的互动中倾向于情感性的依赖;观众在会展场馆当中把个人视为“消费者”,会展场馆被看作是一个“消费空间”,具有“工具性场所”的特点,观众在与会展场所的互动中倾向于功能性的依赖。  相似文献   

基于扎根理论的节事场所依赖维度探索性研究——以2011西安世界园艺博览会为例   总被引：2，自引：0，他引：2  

戴光全  梁春鼎 《地理科学》2012,(7):777-783

场所依赖(place attachment)探讨的是个人对充满意义的特定场所产生的某种认知或感情的联系。作为一项探索性研究,以2011西安世界园艺博览会为案例,采用质性研究方法,通过参与观察和深度访谈等手段获取研究资料,运用扎根理论深入分析游客的活动特征和情感态度,研究游客的节事场所依赖特征。在此基础上挖掘和提炼节事场所依赖的维度,最终构建一个由个体、社会、场所和节事4个维度构成的节事场所依赖PSPE概念模型,为节事场所依赖的定量研究打下基础。  相似文献   

Corona processes and lightning attachment: The effect of wind during thunderstorms   总被引：1，自引：0，他引：1  

E.M. Bazelyan  Yu.P. Raizer  N.L. Aleksandrov  F. D'Alessandro   《Atmospheric Research》2009,94(3):436-447

A simple model of a glow corona occurring near the tip of a grounded electrode in a thundercloud electric field that can be enhanced by an approaching downward leader has been studied analytically and numerically with regard to the effect of wind. We obtained an approximate expression for corona current taking into account the (i) removal of space charge from the coronating point due to ion drift and wind and (ii) image of the charge in the ground. As the wind velocity decreases to zero, the expression tends to that obtained previously in the absence of wind. It was shown analytically and numerically that, in a thundercloud electric field, even moderate wind velocities lead to hundreds of percent increase in the corona current. This current decreases with time only slightly in a steady thundercloud electric field, as opposed to the current behavior in the absence of wind. However, even strong wind is not sufficient to affect the properties of a corona intensified in the electric field of an approaching downward leader. The occurrence of wind does not affect the conditions for initiation of an upward connecting leader from grounded objects and consequently the efficiency of lightning rods of ordinary height.  相似文献   

独立书店消费者的休闲涉入和地方依恋研究     

陈婉茹  李爽  伍艳慈 《世界地理研究》2021,30(2):422-432

以广州1200bookshop为例,采用涉入量表和地方依恋量表,运用结构方程模型和文本分析探讨独立书店文化消费者的休闲涉入和地方依恋的关系。研究表明：（1）休闲涉入只有中心性对地方依恋的每个维度均有显著的正向关系,且对地方依赖的影响大于地方认同;（2）吸引力对地方依赖有显著正向影响,而自我表现对地方认同有显著的正向影响;（3）地方依赖对地方认同有显著的正向影响;（4）文化消费者对1200bookshop的地方依恋特征主要是功能性依赖和精神性认同。研究将“休闲涉入-地方依恋”模型迁移到城市日常休闲活动空间,验证并修正了该模型,拓展了该模型的适用范围,同时也为独立书店的经营和发展模式提供实践支持。  相似文献   

My neighbourhood,my country or my planet? The influence of multiple place attachments and climate change concern on social acceptance of energy infrastructure     

《Global Environmental Change》2017

Research on place attachments and identities has made an important contribution to understanding social acceptance of low carbon infrastructure, which are often objected to by local communities. However, a focus on local attachments predominates in studies to date, neglecting the potential role of national and global attachments and identities on energy beliefs and attitudes, despite the fact that large energy infrastructures are not only local in significance or function. To investigate this, survey data was collected from a representative sample of UK adults (N = 1519), capturing place attachments at local, national and global levels, climate change concern, beliefs about power lines and support for energy system change. Findings show significant differences in infrastructure beliefs and attitudes depending upon relative strength of attachments at different levels, controlling for personal characteristics. Analyses of variance revealed that individuals with stronger national than local or global attachments were less likely to support European grid integration; those with relatively stronger global attachment were most likely to support decentralised energy and those with relatively stronger local attachment were most likely to protest against a nearby power line. In addition, those with strong attachments at local, national and global levels were most willing to reduce energy demand, and those with weak attachments were least likely to trust grid companies. Relatively stronger global than national attachment was positively associated with support for decentralised energy, with this effect partially mediated by climate change concern. Explanations for the findings and implications for future research are discussed.  相似文献