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11.
Initial coagulation rates of colloidal hematite (-Fe2O3) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 104 in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G
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) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10–7 to 10–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10–3 to 10–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems. 相似文献
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利用漫反射光谱鉴定红粘土中针铁矿和赤铁矿 总被引：5，自引：0，他引：5
针铁矿(Gt)和赤铁矿(Hm)是广泛存在于土壤和沉积物中的重要铁矿物。这两种矿物在土壤和沉积物中含量很低,常规的测试手段很难有效地测定其含量。利用反射光谱联合加热处理的方法,可对土壤及沉积物样品中针铁矿和赤铁矿进行定性或半定量测定。实验结果显示,样品加热到300℃后,针铁矿的反射光谱的一阶导数特征峰发生了变化,赤铁矿的一阶导数特征峰却没有明显的变化。因此加热前后样品反射光谱一阶导数的变化取决于针铁矿和赤铁矿的含量。利用这种方法估计黄土高原第三纪红粘土样品中的赤铁矿含量约为0.3%～0.4%,针铁矿含量约为0.5%～1%。 相似文献
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黄土剖面中赤铁矿和针铁矿的定量分析与气候干湿变化研究 总被引：2，自引：6，他引：2
为了了解黄土剖面中赤铁矿和针铁矿的分布特征,文章采用对铁氧化物矿物灵敏的漫反射光谱法(DRS),开展了赤铁矿和针铁矿的鉴定和测定研究,提出了定量分析赤铁矿和针铁矿含量的DRS新方法.选择天然典型黄土和古土壤样品,首先采用柠檬酸盐-重碳酸盐-连二亚硫酸盐(CBD)方法去除其中成壤成因的铁氧化物矿物,以其为基体配制含不同赤铁矿和针铁矿的系列标样,然后进行DRS测试和多元逐步回归分析,分别建立测定赤铁矿和针铁矿含量的校准方程并加以检验.利用DRS方法,分析了多个黄土剖面的赤铁矿和针铁矿含量,发现黄土-古土壤剖面的赤铁矿/针铁矿比值可作为东亚季风干/湿变化的敏感指标.该比值较高时反映了干燥土壤环境,而较低时指示了潮湿土壤环境.对灵台和洛川剖面中赤铁矿/针铁矿比值的分析,初步揭示了2.6Ma年以来黄土高原东亚季风阶段性变强的特征. 相似文献
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To further evaluate the potential of magnetic anisotropy techniques for determining the origin of the natural remanent magnetization (NRM) in sedimentary rocks, several new remanence anisotropy measurement techniques were explored. An accurate separation of the remanence anisotropy of magnetite and hematite in the same sedimentary rock sample was the goal.In one technique, Tertiary red and grey sedimentary rock samples from the Orera section (Spain) were exposed to 13 T fields in 9 different orientations. In each orientation, alternating field (af) demagnetization was used to separate the magnetite and hematite contributions of the high field isothermal remanent magnetization (IRM). Tensor subtraction was used to calculate the magnetite and hematite anisotropy tensors. Geologically interpretable fabrics did not result, probably because of the presence of goethite which contributes to the IRM. In the second technique, also applied to samples from Orera, an anisotropy of anhysteretic remanence (AAR) was applied in af fields up to 240 mT to directly measure the fabric of the magnetite in the sample. IRMs applied in 2 T fields followed by 240 mT af demagnetization, and thermal demagnetization at 90°C to remove the goethite contribution, were used to independently measure the hematite fabric in the same samples. This approach gave geologically interpretable results with minimum principal axes perpendicular to bedding, suggesting that the hematite and magnetite grains in the Orera samples both carry a depositional remanent magnetization (DRM). In a third experiment, IRMs applied in 13 T fields were used to measure the magnetic fabric of samples from the Dome de Barrot area (France). These samples had been demonstrated to have hematite as their only magnetic mineral. The fabrics that resulted were geologically interpretable, showing a strong NW-SE horizontal lineation consistent with AMS fabrics measured in the same samples. These fabrics suggest that the rock's remanence may have been affected by strain and could have originated as a DRM or a CRM.Our work shows that it is important to account for the presence of goethite when using high field IRMs to measure the remanence anisotropy of hematite-bearing sedimentary rocks. It also shows that very high magnetic fields (>10 T) may be used to measure the magnetic fabric of sedimentary rocks with highly coercive magnetic minerals without complete demagnetization between each position, provided that the field magnetically saturates the rock. 相似文献
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冀西北长城纪宣龙式铁矿层中微体植物化石的发现及其意义 总被引：10，自引：0，他引：10
本文研究的是笔者等在冀西北长城系串岭沟组宣龙式铁矿层中发现的微体植物化石,这些化石都保存在铁质叠层石(肾状赤铁矿)和铁质核形石(鲕状赤铁矿)的基本层中。微化石以丝状体为主,部分为球状体。归属于原核生物蓝藻门颤藻科的两个属和色球藻科的一个属。化石层同位素年龄约在1800—1757Ma。这些化石与北美冈弗林特组微化石比较,既有些相似,又有些区别。该化石的发现为研究铁矿的成因,指示沉积环境及层位对比都很有意义。 相似文献
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长江三角洲全新世地层中潮滩沉积磁性特征及其古环境意义 总被引：3，自引：1，他引：2
对长江三角洲北翼江苏南通地区NT钻孔（长60.9 m）进行了系统的环境磁学分析,并结合岩性特征、粒度、漫反射光谱（DRS）等手段,探讨了全新世早、晚期潮滩沉积的磁性特征及其古环境意义。NT孔自下而上可分为6层（U1~U6层）,其中U2层下部（49.9~44.8 m）和U6层（7.5~0.3 m）为潮滩沉积,具有较低的退磁参数S比值及较高的硬剩磁（HIRM）和SIRM/χ,表明反铁磁性矿物如赤铁矿、针铁矿等含量和比例较高。结合漫反射光谱（DRS）分析,发现U6层上部盐沼（1.5~0.3 m）赤铁矿和针铁矿富集,U2层下部的盐沼仅富集赤铁矿。这一差异与U2层和U6层形成的时期和沉积环境有关。U2层形成于晚更新世晚期至早全新世,且曾长期暴露地表,有利于赤铁矿的形成,其后随着海平面的持续上升,盐沼不断垂向加积,始终处于水下环境,不利于针铁矿的形成;U6层形成于晚全新世三角洲海岸的进积过程中,氧化还原相互交替的环境有利于针铁矿的形成,后期成陆后的成土作用生成了较多的磁赤铁矿和赤铁矿。研究表明,全新世三角洲发育过程中,不同时期形成的盐沼具有不同的磁性特征,磁性特征的研究可以提供潮滩沉积环境演变的信息,对三角洲古环境重建研究具有重要意义。 相似文献
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中新世是新生代古气候变化的关键时期。本文以柴达木盆地东北部瑙格剖面18.4～6.9Ma沉积物为研究对象,通过对沉积物颜色指标的测定与分析,获得该时段沉积物高分辨率颜色指标变化序列。发现色度值变化与氧化—还原作用有关,红度值与赤铁矿相对含量呈正相关。结合其它资料分析表明,柴达木盆地东北部地区中新世气候变化为18.4～14.2Ma相对暖湿阶段、14.2～7.7Ma相对冷湿阶段、7.7～6.9Ma相对干冷阶段,其变化可能受到全球温度变化的影响,气候转型主要导致了该区沉积相和沉积物色度的变化。 相似文献
19.
贵州三都县巴言一带石炭系下统祥摆组及断裂带中可见鲕状赤铁矿。区域成矿条件对比研究发现,祥摆组无沉积赤铁矿的条件;钻孔显示赤铁矿呈脉状赋存于祥摆组至上司组断裂带中,而祥摆组正常层位无赤铁矿;沿断裂带走向追索,赤铁矿化蚀变明显,远离断裂带,祥摆组岩性为黑色炭质泥岩夹石英砂岩,岩相条件不适宜赤铁矿沉积;矿体仅分布于断裂带附近地层及破碎带中,不符合沉积矿床的一般特征。排除通过风化作用充填的可能,结合矿体的展布特征及围岩蚀变特征,推断巴言赤铁矿为构造热液成因。对巴言构造热液成因的赤铁矿"鲕粒"特征研究发现,其与正常沉积的赤铁矿"鲕粒"具有相似的特征,这将为"鲕粒"成因的深入研究提供新的线索。 相似文献
20.
James R. Hein David A. Clague Randolph A. Koski Robert W. Embley Rachel E. Dunham 《Marine Georesources & Geotechnology》2013,31(4):317-339
A Tiburon ROV dive within the East Blanco Depression (EBD) increased the mapped extent of a known hydrothermal field by an order of magnitude. In addition, a unique opal-CT (cristobalite-tridymite)-hematite mound was discovered, and mineralized sediments and rock were collected and analyzed. Silica-hematite mounds have not previously been found on the deep ocean floor. The light-weight rock of the porous mound consists predominantly of opal-CT and hematite filaments, rods, and strands, and averages 77.8% SiO2 and 11.8% Fe2O3. The hematite and opal-CT precipitated from a low-temperature (≥ 115° C), strongly oxidized, silica- and iron-rich, sulfur-poor hydrothermal fluid; a bacterial mat provided the framework for precipitation. Samples collected from a volcaniclastic rock outcrop consist primarily of quartz with lesser plagioclase, smectite, pyroxene, and sulfides; SiO2 content averages 72.5%. Formation of these quartz-rich samples is best explained by cooling in an up-flow zone of silica-rich hydrothermal fluids within a low permeability system. Opal-A, opal-CT, and quartz mineralization found in different places within the EBD hydrothermal field likely reflects decreasing silica saturation and increasing temperature of the mineralizing fluid with increasing silica crystallinity. Six push cores recovered gravel, coarse sand, and mud mineralized variously by Fe or Mn oxides, silica, and sulfides. Total rare-earth element concentrations are low for both the rock and push core samples. Ce and Eu anomalies reflect high and low temperature hydrothermal components and detrital phases. A remarkable variety of types of mineralization occur within the EBD field, yet a consistent suite of elements is enriched (relative to basalt and unmineralized cores) in all samples analyzed: Ag, Au, S, Mo, Hg, As, Sb, Sr, and U; most samples are also enriched in Cu, Pb, Cd, and Zn. On the basis of these element enrichments, the EBD hydrothermal field might best be described as a base- and precious-metal-bearing, silica-Fe-oxide-barite deposit. Such deposits are commonly spatially and temporally associated with volcanogenic massive sulfide (VMS) ores. A plot of data for pathfinder elements shows a large hot spot at the northwestern margin of the field, which may mark a region where moderate to high temperature sulfide deposits are forming at depth; further exploration of the hydrothermal field to the northwest is warranted. 相似文献