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51.
Alexandre Raphael Cabral Orlando Garcia Rocha Filho Richard David Jones 《Journal of Geochemical Exploration》2008,96(1):69-76
Mercury contents in Precambrian banded iron formation-hosted hematite ores are virtually unknown. In an attempt to provide information on the abundance and distribution of Hg in Fe ore, we present analyses for Hg in samples of high-grade soft hematite ore from Gongo Soco, Minas Gerais, Brazil. Bulk samples contain from < 5 to 25 ppb Hg without obvious correlation with major elements. Granulometric fractions of follow-up samples have amounts of Hg from 6 to 48 ppb and display positive linear correlations with total Mn as MnO (r = 0.87), LOI (r = 0.87) and SiO2 (r = 0.76), as well as a negative linear correlation with total Fe as Fe2O3 (r = − 0.87). The correlations suggest that Hg is associated with a hydrated ferruginous groundmass bearing residual Mn, Al and Si, which replaced gangue minerals in itabirite in the process of formation of the Gongo Soco soft hematite ore. 相似文献
52.
The mutual solubility in the system corundum–hematite[-(Al, Fe3+)2O3] was investigated experimentally using bothsynthetic and natural materials. Mixtures of -Al2O3 and -Fe2O3(weight ratios of 8:2 and 10:1) were used as starting materialsfor synthesis experiments in air at 800–1300°C withrun times of 7–34 days. Experiments at 8–40 kbarand 490–1100°C were performed in a piston-cylinderapparatus (run times of 0·8–7·4 days) usinga natural diasporite consisting of 60–70 vol. % diasporeand 20–30 vol. % Ti-hematite. During the diasporite–corunditetransformation, the FeTiO3 component (12–18 mol %) ofTi-hematite only slightly increased, implying that oxygen fugacitywas maintained at high values. Run products were studied byelectron microprobe and X-ray diffraction (Rietveld) techniques.An essentially linear volume of mixing exists in the solid solutionwith a slight positive deviation at the hematite side. Up to1000°C, corundum contains <4 mol % Fe2O3 and hematite<10 mol % Al2O3; at 1200°C these amounts increase to9·3 and 17·0 mol %, respectively. At 1300°Chematite was no longer stable and coexists with the orthorhombic phase . The present results agree with corundum (solvus) compositions obtained inprevious studies but indicate a larger solubility of Al in hematite.The miscibility gap in the solution can be modelled with anasymmetric Margules equation with interaction parameters (2uncertainties): ; ; ; . Application of the corundum–hematite solution as a solvus geothermometer is limited because of thescarcity of suitable rock compositions. KEY WORDS: corundum; hematite; corundum–hematite miscibility gap; experimental study; Margules model; metabauxite 相似文献
53.
本文分别以3种不同的可溶性三价铁盐作为Fe~(3+)源物质的强迫水解法和以针铁矿和四方纤铁矿为起始物质的溶液转化法,在90～315℃范围内合成赤铁矿,测定了赤铁矿与水之间的氧同位素分馏。矿物合成实验和氧同位素分析结果显示,在90～225℃范围内,实验获得的赤铁矿与水之间氧同位素分馏为亚稳态分馏,并且不同合成实验方法得到不同的分馏关系,前者相对于后者富集(18)O约为2‰,即:10~31nα_(赤铁矿-水)=1.17±0.02×10~6/T~2-9.14±0.20(强迫水解法);10~31nα_(赤铁矿-水)=1.46±0.18×10~6/T~2-14.52±0.03(溶液转化法)。但温度在315℃以下,无论强迫水解法还是溶液转化法,在实验误差范围内实验测定的分馏值几乎不可区分,并且与增量方法的理论预测相近,表明该温度下获得的赤铁矿与水之间氧同位素分馏代表了赤铁矿-水体系氧同位素平衡分馏。此外,两种不同方法获得了不同的分馏关系,显示低温下赤铁矿-水体系氧同位素分馏不仅依赖于赤铁矿形成的温度,而且取决于赤铁矿的成因机制,因此对应于不同形成环境下的动力学亚稳态平衡,这对解释低温环境中赤铁矿的氧同位素数据具有重要意义。 相似文献
54.
Olga N. Karasyova Lyudmila I. Ivanova Leonid Z. Lakshtanov Lars Lövgren Staffan Sjöberg 《Aquatic Geochemistry》1998,4(2):215-231
The acid/base properties of the hematite/water interface and surfacecomplexation with gold has been studied by potentiometric titrations in thefour component system H+ – FeOH –AuCl
4
-
– Cl-. Equilibrium measurementswere performed in NaCl media at 298.2 K. In the evaluation of equilibriummodel from experimental data the constant capacitance model was applied. Theacid/base properties were investigated in 0.1 M NaCl in the range 2.6 pH 7.4. The resulting intrinsic constants for protonation anddeprotonation of hydroxyl groups at the surface were log
1,1,0,0(int)
s
= 7.10 ± 0.06 andlog
-1,1,0,0(int)
s
= - 7.80 ±0.06. The density of proton active surface sites was 2.85nm-2 and the specific capacitance 2.5 C V-1 m-2. In the investigation of surface complexation of gold, thepotentiometric titrations were performed in the range 2.0 pH 10.2.Titration data was supplemented with analysis of Au in the aqueous phase byatomic absorbance spectrometry. The equilibrium model proposed consists ofthe following monodentate surface complexes: FeOHAuCl3(log
0,1,1,-1
s
= 1.45 ± 0.03),FeOHAuCl2OH (log
-1,1,1,-2
s
= -3.89 ± 0.02), FeOHAu(OH)3 (log
-3,1,1,-4
s
= -21.94 ± 0.05). Aslightly better fit could be obtained by assuming formation of a bidentatecomplex with the composition(FeO)2Au(OH)H2O. However, based onstructural arguments this complex was rejected. 相似文献
55.
The Oxia mineralized granite is the product of differentiation in the external parts of the Florina magmatic mass. Acidic
hydrothermal solutions either of magmatic or of meteoric origin reacted with the upper tectonically fractured parts of the
Florina granite and became enriched in iron, thorium, uranium, zircon and rare-earth elements. The most abundant alteration
minerals are sericite and quartz, while the minerals of the mineralization bands include magnetite, hematite, thorite, monazite
and zircon. The outer parts of the Oxia granite made it easy the percolation of hydrothermal solutions from the deeper heater
to the upper cooler parts of the granite which acted as a hot spot. 相似文献
56.
The paper features data on thermomagnetic characteristics of the red-bed sediments of the Lower Cretaceous of the Tadjik depression which turned out to be somewhat anomalous. The thermomagnetic characteristics of monolithic samples are stable under long-term heating (2–3 hours) at high temperature (600°–700°C). At the same time, the thermomagnetic characteristics of the powders, obtained from heated monolithic samples, display instability under even lesser temperatures.
During heating at 600°–700°C, part of the hematite, dispersed in the rock, turns into stable maghemite. Disintegration of the monoliths changes the properties of the secondary maghemite - it becomes unstable to heating and at temperatures of 550°-600°C irreversibly changes into hematite. 相似文献
57.
The iron ores of the Gushan mine occur in the contact zone of a Mesozoic diorite intrusion and are composed primarily of hematite microcrystallites and chalcedony,The hematite microcrystallites have undergone post-mineralization recrystallization and coarsening with resultant formation of lath-shaped hematite porphyroblasts.Microscopic investigation reveals that recrystallization and coarsening of the hematite ores of the Gushan mine took place without the formation of new nuclei,due to the coalescence of the microcrystallites.The whole process could have begun with the mutual approach of the microcrystallites,followed by grain rotation to realize paralleism and ending by the welding of these grains to form optically homogeneous porphyroblastic hematite. 相似文献
58.
新近纪大洋红层是一种在氧化条件下形成的红色-粉色-棕色海洋沉积物。白垩纪大洋红层研究成果众多,然而新近纪大洋红层研究缺乏系统的分析和总结。本文以新近纪大洋红层为研究对象,通过对全球大洋钻探井位资料的分析,发现39个钻井含有新近纪大洋红层。通过对不同大洋区域、不同钻井内93个红层离散样品的主量元素CaO,Al2O3和SiO2含量进行三元图投点分析,将新近纪大洋红层分为铝质和钙质大洋红层,其中绝大多数为铝质大洋红层。进一步分析了部分钻井中离散样品的磁化率变化、反射光谱一阶导数曲线、热退磁曲线和交变磁场退磁曲线变化,结果表明新近纪大洋红层的致色矿物以赤铁矿为主。12个钻井中新近纪大洋红层离散样品的低总有机碳含量和低CaCO3含量指示较低的生物生产力,此外19个钻井中红层的沉积速率平均为4 mm/ka,而非红层的沉积速率平均为85.3 mm/ka,指示红层的沉积速率相对较低。总结和分析新近纪大洋红层的以上特征,本文认为较低的有机质堆积速率为铁氧化物(赤铁矿)的形成提供了有利的氧化条件,使得沉积物中的铁氧化物在成岩阶段得以保存,最终形成全球分布的新近纪大洋红层。 相似文献
59.
纳米比亚西北部Kunene（库内内）省新元古界铁矿层分布广泛。经普查,在EPL4432及EPL4533矿权区铁矿规模均构成大型矿床。铁矿床赋存于新元古界Damara(达马拉)层序的Chuos（朝斯）组上段与下段层位中（分别简称为“上矿层”和“下矿层”）。EPL4432下层矿中主要矿物为磁铁矿,EPL4533下层矿主要矿物为赤铁矿,同一层位出现不同的矿物类型,据分析这主要是赤铁矿受热液改造成磁铁矿造成的。经综合分析,纳米比亚西北部Chuos组铁矿的成矿类型为沉积-热液改造型,Chuos组下矿层分布地段为有利的成矿地段 相似文献
60.
Enrichment iron ore of the Hamersley Province, currently estimated at a resource of over 40 billion tonnes (Gt), mainly consists of BIF (banded iron-formation)-hosted bedded iron deposits (BID) and channel iron deposits (CID), with only minor detrital iron deposits (DID). The Hamersley BID comprises two major ore types: the dominant supergene martite–goethite (M-G) ores (Mesozoic–Paleocene) and the premium martite–microplaty hematite ores (M-mplH; ca 2.0 Ga) with their various subtypes. The supergene M-G ores are not common outside Australia, whereas the M-mplH ores are the principal worldwide resource. There are two current dominant genetic models for the Hamersley BID. In the earlier 1980–1985 model, supergene M-G ores formed in the Paleoproterozoic well below normal atmospheric access, driven by seasonal oxidising electrochemical reactions in the vadose zone of the parent BIF (cathode) linked through conducting magnetite horizons to the deep reacting zone (anode). Proterozoic regional metamorphism/diagenesis at ～80–100°C of these M-G ores formed mplH from the matrix goethite in the local hydrothermal environment of its own exhaled water to produce M-mplH ores with residual goethite. Following general exposure by erosion in the Cretaceous–Paleocene when a major second phase of M-G ores formed, ground water leaching of residual goethite from the metamorphosed Proterozoic ores resulted in the mainly goethite-free M-mplH ores of Mt Whaleback and Mt Tom Price. Residual goethite is common in the Paraburdoo M-mplH-goethite ores where erratic remnants of Paleoproterozoic cover indicate more recent exposure. Deep unweathered BIF alteration residuals in two small areas of the Mt Tom Price M-mplH deposits have been used since 1999 for new hypogene–supergene modelling of the M-mplH ores. These models involve a major Paleoproterozoic hydrothermal stage in which alkaline solutions from the underlying Wittenoom Formation dolomite traversed the Southern Batter Fault to leach matrix silica from the BIF, adding siderite and apatite to produce a magnetite–siderite–apatite ‘protore.’ A later heated meteoric solution stage oxidised siderite to mplH + ankerite and magnetite to martite. Weathering finally removed residual carbonates and apatite leaving the high-grade porous M-mplH ore. Further concepts for the Mt Tom Price North and the Southern Ridge Deposits involving acid solutions followed, but these have been modified to return essentially to the earlier hypogene–supergene model. Textural data from erratic ‘metasomatic BIF’ zones associated with the above deposits are unlike those of the typical martite–microplaty hematite ore bodies. The destiny of the massive volumes of dissolved silica gangue and the absence of massive silica aureoles has not been explained. Petrographic and other evidence indicate the Mt Tom Price metasomatism is a localised post-ore phenomenon. Exothermic oxidation reactions in the associated pyrite-rich black shales during post-ore removal by groundwater of remnant goethite in the ores may have resulted in this very localised and erratic hydrothermal alteration of BIF and its immediately associated pre-existing ore. 相似文献